Citation: Guo Xian Zhu, Yong Da Li, Hong Zhou Lian, Jing Hui Yan, Xing Quan Wang. Synthesis and fluorescence properties of cerium-KMgF₃ through a solvothermal process[J]. Chinese Chemical Letters, ;2009, 20(1): 106-110. doi: 10.1016/j.cclet.2008.09.032 shu

Synthesis and fluorescence properties of cerium-KMgF₃ through a solvothermal process

a College of Science, Changchun University of Science and Technology, Changchun 130022, China;
b School of Chemistry Science and Technology, Zhanjiang Normal University, Zhanjiang 524048, China;
c Key Laboratory of Rare Earth Chemistry and Physics, Chinese Academy of Science, Changchun 130022, China

Received Date: 2 June 2008

Fund Project: This work was supported by the National Natural Science Foundation of China (No. 50702057).

Phosphor of KMgF₃:Ce³⁺ is synthesized through solvothermal method at 180℃ and characterized by means of X-ray powder diffraction (XRD) and environment scanning electron microscopy (ESEM). X-ray photoelectron spectroscopy (XPS) is applied to the study of the energy band structure of KMgF₃:Ce³⁺ and confirms the oxygen content of the product is very low. The fluorescence spectra of the rare-earth ion-doped KMgF₃ is investigated by the fluorescence spectrophotometer. In the emission spectra, there is a broadband emission with a maximum center located at 306 nm arising from d-f transition of Ce³⁺ in the host. This will be useful for ultraviolet tunable lasers.
- Solvothermal synthesis,
- Ce³⁺ions,
- KMgF₃,
- Luminescence,
- X-ray photoelectron spectroscopy(XPS)
1. [1]
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13. [13]
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16. [16]
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17. [17]
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18. [18]
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19. [19]
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20. [20]
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