Citation: Shu Quan Sun, Qi Jun Song, He Fang Yuan, Yu Qiang Ding. Solid-state electrochemiluminescence of a novel iridium(Ⅲ) complex[J]. Chinese Chemical Letters, ;2008, 19(12): 1509-1512. doi: 10.1016/j.cclet.2008.09.031 shu

Solid-state electrochemiluminescence of a novel iridium(Ⅲ) complex

School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, China

Received Date: 2 June 2008

Fund Project: This work was supported by the National Natural Science Foundation of China (No. 20571033).

The sofid-state ECL behavior of a water-insoluble bis-cyclometalated (pq)₂Ir(N-phMA) complex is presented, in which pq is a 2-phenylquinoline anion and N-phMA is N-phenyl methacrylamide, a monoanionic bidentate ligand. The MWNTs/(pq)₂Ir(N-phMA) film, MWNTs/Ru(bpy)₃²⁺ film and (pq)₂Ir(N-phMA) directly modified glassy carbon electrode were fabricated; only the MWNTs/(pq)₂Ir(N-phMA) film can produce steady ECL in the presence of tri-n-propylamine as a coreactant.
- Solid-state electrochemiluminescence,
- Iridium(Ⅲ)complex,
- Multi-wall carbon nanotubes
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