Citation: Lan Ying Yang, Min Min Shi, Mang Wang, Hong Zheng Chen. Self-assembled helical nanostructures from an asymmetrical perylene diimide[J]. Chinese Chemical Letters, ;2008, 19(10): 1260-1263. doi: 10.1016/j.cclet.2008.07.008 shu

Self-assembled helical nanostructures from an asymmetrical perylene diimide

Lan Ying Yang ^a,b, ,
Min Min Shi ^a,b ,
Mang Wang ^a,b ,
Hong Zheng Chen ^a,b

a Department of Polymer Science and Engineering, State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou 310027, China;
b Key Laboratory of Macromolecule Synthesis and Functionalization, Zhejiang University, Ministry of Education, Hangzhou 310027, China

Received Date: 26 February 2008

Fund Project: This work was supported by National Natural Science Foundation of China (Nos. 50433020, 50403022 and 50520150165) and by the developing program of Changjiang Scholar and Innovation Team from Education Department of China under Grant No. IRT0651.

An asymmetrical perylene diimide 3,N-(4-methoxyphenyl)-N'-(4-nitrophenyl)-perylene-3,4,9,10-tetracarboxylic diimide,was synthesized,and its self-assembly and dissociation behaviors in chloroform was studied in detail bv UV-vis and fluorescence spectroscopies.The resulting unique helical nanostructures from 3 were proposed to be self-assembled via the cooperative actions of π-π stacking,steric hindrance and electrophile-nucleophile type pairing.
- Perylene diimide,
- Helical nanostructures,
- Self-assembly
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