Citation: Jian Bin Zhang, Peng Yan Zhang, Guo Hua Chen, Fang Han, Xiong Hui Wei. Photochemical reaction between magnesium tetraphenyl porphyrin and oxygen[J]. Chinese Chemical Letters, ;2008, 19(10): 1190-1192. doi: 10.1016/j.cclet.2008.07.004 shu

Photochemical reaction between magnesium tetraphenyl porphyrin and oxygen

a Department of Applied Chemistry, College of Chemistry & Molecular Engineering. Peking University, Beijing 100190, China;
b College of Chemical Engineering, Inner Mongolia University of Technology, Huhhot 010051, China

Received Date: 7 April 2008

Fund Project: This project was financed by Jiangxi Boyuan Industry Co. Ltd. (Jiangxi Province, China). Thanks to Professor Wenting Hua and Professor Hongcheng Gao (Peking University, China) for their suggestions on the photochemical interaction mechanism of MgTPP with oxygen.

The photochemical reaction of magnesium tetraphenyl porphyrin(MgTPP) with O₂ was studied in CH₂Cl₂ by steady-state fluorescence,UV-vis absorption,FTlR and MALDI-TOF MS measurements.These spectra indicate that O₂ can react with Mg TPP excited by irradiation.forming the stable 1:1 coordinated adduct of MgTPP-O₂.In the adduct,the oxygen atoms of O₂ may insert in the Mg-N bonds in MgTPP and birid with the nitrogen atoms of MgTPP to form N-O-Mg bonds.
- Magnesium tetraphenyl porphyrin,
- Photochemical reaction,
- Linking oxygen
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