Citation: Lian Peng Tong, Jing Nan Cui, Wei Min Ren, Xing Yong Wang, Xu Hong Qian. Asymmetric bioreduction of substituted acenaphthenequinones using plant enzymatic systems: A novel strategy for the preparation of (+)-and(-)-mono hydroxyacenaphthenones[J]. Chinese Chemical Letters, ;2008, 19(10): 1179-1182. doi: 10.1016/j.cclet.2008.06.037 shu

Asymmetric bioreduction of substituted acenaphthenequinones using plant enzymatic systems: A novel strategy for the preparation of (+)-and(-)-mono hydroxyacenaphthenones

a State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012, China;
b Shanghai Key Laboratory of Chemical Biology, East China University of Science and Technology, Shanghai 200237, China

Received Date: 1 April 2008

Fund Project: We are grateful to the Program for Changjiang Scholars, the Innovative Research Team in University (No. IRT0711) and the Technology Foundation of Shanghai (No. 04DZ05605) for financial support of the research.

Regio- and enantioselective reduction of substituted acenaphthenequinones were conducted under mild reaction conditions using plant enzymatic systems.A screening of 15 plants allowed the selection of two suitable plants fulfilling enantiocomplementarity.The (+)-and(-)-mono hydroxyacenaphthenones were achieved with high conversion and good enantiomeric purity using peach(Prunus persica(L.)Batseh.,conversion 98%,71% ee)and carrot(Daucus carota L.,conversion 95%,81% ee),respectively.
- Bioreduction,
- Plant enzymes,
- Acenaphthenequinone,
- Chiral hydroxyacenaphthenone
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