Citation: Jing Zhang, Yan Xia Wang, Feng Kang, Ying Ya Shao, Zong Jie Li, Xin Lin Yang. Synthesis of novel fullerene α-amino acid conjugates[J]. Chinese Chemical Letters, ;2008, 19(10): 1159-1162. doi: 10.1016/j.cclet.2008.06.035
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Aspartie acid and glutamic acid with protected α-amino and α-carboxyl groups had been used to react with the activated hydroxyl group of N-substituted 3,4-fuUero pyrrolidine.The products were deprotected,affording two monofullerene α-amino acids,monofullerene aspartic acid(mFas) and monofullerene glutamic acid(mFgu).Then a bifullerene glutamic acid conjugate (bFguC)was synthesized by reaction of mFgu containing protected amino group with N-subsfimted 3,4-fullero pyrrolidine.
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