Citation: La Mei Yu, Wen Yan Hao, Ming Zhong Cai. A one-pot stereoselective synthesis of 1,4-dienyl selenides by hydrostannylation-Stille tandem reaction of acetylenic selenides with Bu₃SnH and allylic bromides[J]. Chinese Chemical Letters, ;2008, 19(9): 1047-1050. doi: 10.1016/j.cclet.2008.06.029 shu

A one-pot stereoselective synthesis of 1,4-dienyl selenides by hydrostannylation-Stille tandem reaction of acetylenic selenides with Bu₃SnH and allylic bromides

Department of Chemistry, Jiangxi Normal University, Nanchang 330022, China

Received Date: 19 March 2008

Fund Project: We thank the National Natural Science Foundation of China (No. 20462002) and Natural Science Foundation of Jiangxi Province (No. 2007GZW0172) for financial support.

1,4-Dienyl selenides can be stereoselectively synthesized in one pot under mild conditions in good yields by the palladium-catalyzed hydrostannylation of acetylenic selenides, followed by Stille coupling with allylic bromides.
- Acetylenic selenide,
- Hydrostannylation,
- Stille coupling,
- 1,4-Dienyl selenide,
- Stereoselective synthesis
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