Citation: Jian Xue, Lu Ling Wu, Xian Huang. The facile insertion of β-keto sulfones to arynes:The direct preparation of polysubstituted ortho-keto benzyl sulfones[J]. Chinese Chemical Letters, ;2008, 19(6): 631-633. doi: 10.1016/j.cclet.2008.04.006 shu

The facile insertion of β-keto sulfones to arynes:The direct preparation of polysubstituted ortho-keto benzyl sulfones

Jian Xue ^a, ,
Lu Ling Wu ^a ,
Xian Huang ^a,b

a Department of Chemistry, Zhejiang University Campus Xixi, Hangzhou 310028, PR China;
b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, PR China

Received Date: 10 September 2007

Fund Project: We are grateful to the National Natural Science Foundation of China (Nos. 20332060 and 2472072)

One novel carbon-carbon bond insertion reaction of arynes has been developed. By this reaction β-keto sulfones can insert the triple bond of arynes to prepare polysubstituted ortho-keto benzyl sulfones.
- Arynes,
- Insertion reaction,
- C-C bonds,
- β-Keto sulfones
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