Citation: Yue Jun Zhu, Ye Bang Tan, Xu Du, Ji Cheng Piao, Qi Feng Zhou. Synthesis and characteristic of double hydrophilic block copolymer with amine pendant chains[J]. Chinese Chemical Letters, ;2008, 19(3): 355-358. doi: 10.1016/j.cclet.2008.01.008 shu

Synthesis and characteristic of double hydrophilic block copolymer with amine pendant chains

a School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China;
b Key Laboratory of Colloid and Interface Chemistry, Shandong University, Ministry of Education, Jinan 250100, China

Received Date: 8 October 2007

Fund Project: The work is financially supported by the National Natural Science Foundation of China (No. 20674045), Shandong Provincial Natural Science Foundation (No.Y2007B34) and the Scientific Research Founation of Key Laboratory of Colloid and Interface Chemistry, Shandong University, Ministry of Education.

Novel double hydrophilic block copolymers with amine pendant chains were synthesized by polymerization of 4-vinyl benzylamine hydrochloric salt using 4, 4'-azo-bis[4-cyanopentanoate poly (ethylene glycol) ester] as macroazoinitiator. The structures of the copolymers were characterized by ¹H NMR, FTIR spectra and acid-base titration, GPC-MALS techniques.
- Polyamine,
- Macroazoinitiator,
- Double hydrophilic block copolymer
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