Citation: Li Ming Dong, Gong Xiong Liao, Ming Jing Wang, Xi Gao Jian. Synthesis and characterization of poly(phthalazinone ether nitrile)(PPEN)-polydimethylsiloxane (PDMS)block copolymers[J]. Chinese Chemical Letters, ;2008, 19(2): 230-232. doi: 10.1016/j.cclet.2007.11.006 shu

Synthesis and characterization of poly(phthalazinone ether nitrile)(PPEN)-polydimethylsiloxane (PDMS)block copolymers

a Department of Polymer Science & Materials, Dalian University of Technology, Dalian 116012, China;
b Xi'An Modern Chemistry Research Institute, Xi'An 710065, China

Received Date: 27 August 2007

Fund Project: This project was financially supported by National High Technology and Development Program of China (863 Program No. 2003AA33G030).

Block copolymers with different backbone compositions have been prepared by the condensation of dimethylamino terminated poly (dimethylsiloxane)(PDMS) and hydroquinone terminated poly (phthalazinone ether nitrile)(PPEN) in the presence of chlorobenzene/N-methyl pyrrolidone (NMP) as solvents.The products were characterized by FTIR, ¹H NMR and gel permeation chromatography.Differential scanning calorimetry analysis indicated that the block copolymers showed separated microphase.
- Block copolymers,
- Poly(phthalazinone ether nitrile),
- Polydimethylsiloxane,
- Synthesis
1. [1]
  Lizhuang Zhong , Ming Liu , Shilong Su , Dongxin Zeng , Jing Hu , Zhiqian Guo . Engineering stimuli-responsive block copolymers for multimodal bioimaging. Chinese Chemical Letters, 2026, 37(1): 111512-. doi: 10.1016/j.cclet.2025.111512
2. [2]
  Yulong Shi , Fenbei Chen , Mengyuan Wu , Xin Zhang , Runze Meng , Kun Wang , Yan Wang , Yuheng Mei , Qionglu Duan , Yinghong Li , Rongmei Gao , Yuhuan Li , Hongbin Deng , Jiandong Jiang , Yanxiang Wang , Danqing Song . Chemical construction and anti-HCoV-OC43 evaluation of novel 10,12-disubstituted aloperine derivatives as dual cofactor inhibitors of TMPRSS2 and SR-B1. Chinese Chemical Letters, 2024, 35(5): 108792-. doi: 10.1016/j.cclet.2023.108792
3. [3]
  Huiju Cao , Lei Shi . sp¹-Hybridized linear and cyclic carbon chain. Chinese Chemical Letters, 2025, 36(4): 110466-. doi: 10.1016/j.cclet.2024.110466
4. [4]
  Xinyi Zhang , Kai Ren , Yanning Liu , Zhenyi Gu , Zhixiong Huang , Shuohang Zheng , Xiaotong Wang , Jinzhi Guo , Igor V. Zatovsky , Junming Cao , Xinglong Wu . Progress on Entropy Production Engineering for Electrochemical Catalysis. Acta Physico-Chimica Sinica, 2024, 40(7): 2307057-0. doi: 10.3866/PKU.WHXB202307057
5. [5]
  Lei Feng , Ze-Min Zhu , Ying Yang , Zongbin He , Jiafeng Zou , Man-Bo Li , Yan Zhao , Zhikun Wu . Long-Pursued Structure of Au₂₃(S-Adm)₁₆ and the Unexpected Doping Effects. Acta Physico-Chimica Sinica, 2024, 40(5): 2305029-0. doi: 10.3866/PKU.WHXB202305029
6. [6]
  Ying Chen , Ronghua Yan , Weiyan Yin . Research Progress on the Synthesis of Metal Single-Atom Catalysts and Their Applications in Electrocatalytic Hydrogen Evolution Reactions. University Chemistry, 2025, 40(9): 344-353. doi: 10.12461/PKU.DXHX202503066
7. [7]
  Jiaming Xu , Yu Xiang , Weisheng Lin , Zhiwei Miao . Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies. University Chemistry, 2024, 39(3): 239-257. doi: 10.3866/PKU.DXHX202309093
8. [8]
  Chen Lian , Si-Han Zhao , Hai-Lou Li , Xinhua Cao . A giant Ce-containing poly(tungstobismuthate): Synthesis, structure and catalytic performance for the decontamination of a sulfur mustard simulant. Chinese Chemical Letters, 2024, 35(10): 109343-. doi: 10.1016/j.cclet.2023.109343
9. [9]
  Xiao Liu , Hangqi Liu , Qian Wang , Dandan Zheng , Sibo Wang , Masakazu Anpo , Guigang Zhang . Rational synthesis of poly(heptazine imides) nanorod in ternary LiCl/NaCl/KCl for visible light hydrogen production. Chinese Chemical Letters, 2025, 36(12): 111621-. doi: 10.1016/j.cclet.2025.111621
10. [10]
  Huimin Luan , Qinming Wu , Jianping Wu , Xiangju Meng , Feng-Shou Xiao . Templates for the synthesis of zeolites. Chinese Journal of Structural Chemistry, 2024, 43(4): 100252-100252. doi: 10.1016/j.cjsc.2024.100252
11. [11]
  Hang Wang , Qi Wang , Chuan-De Wu . Continuous synthesis of ammonia. Chinese Journal of Structural Chemistry, 2025, 44(3): 100437-100437. doi: 10.1016/j.cjsc.2024.100437
12. [12]
  Zhaojun Liu , Zerui Mu , Chuanbo Gao . Alloy nanocrystals: Synthesis paradigms and implications. Chinese Journal of Structural Chemistry, 2023, 42(11): 100156-100156. doi: 10.1016/j.cjsc.2023.100156
13. [13]
  Zhenhao Wang , Yuliang Tang , Ruyu Li , Shuai Tian , Yu Tang , Dehai Li . Bioinspired synthesis of cochlearol B and ganocin A. Chinese Chemical Letters, 2024, 35(7): 109247-. doi: 10.1016/j.cclet.2023.109247
14. [14]
  Hui Jin , Qin Cai , Peiwen Liu , Yan Chen , Derong Wang , Weiping Zhu , Yufang Xu , Xuhong Qian . Multistep continuous flow synthesis of Erlotinib. Chinese Chemical Letters, 2024, 35(4): 108721-. doi: 10.1016/j.cclet.2023.108721
15. [15]
  Jingjing Zhang , Xinrui Gu , Gao Li . Robust Metal Nanoclusters for Electrocatalytic Synthesis. Chinese Journal of Structural Chemistry, 2025, 44(8): 100650-100650. doi: 10.1016/j.cjsc.2025.100650
16. [16]
  Xue Zhao , Rui Zhao , Qian Liu , Henghui Chen , Jing Wang , Yongfeng Hu , Yan Li , Qiuming Peng , John S Tse . A p-d block synergistic effect enables robust electrocatalytic oxygen evolution. Chinese Chemical Letters, 2024, 35(11): 109496-. doi: 10.1016/j.cclet.2024.109496
17. [17]
  Yiwen Lin , Yijie Chen , Chunhui Deng , Nianrong Sun . Integration of resol/block-copolymer carbonization and machine learning: A convenient approach for precise monitoring of glycan-associated disorders. Chinese Chemical Letters, 2024, 35(12): 109813-. doi: 10.1016/j.cclet.2024.109813
18. [18]
  Peng Liu . Cyclodextrins as versatile supramolecular building block in nanoscale drug delivery systems for precise tumor chemotherapy. Chinese Chemical Letters, 2025, 36(11): 111406-. doi: 10.1016/j.cclet.2025.111406
19. [19]
  Dong Fang , Xiaofan Yang , Fengxin Gao , Chengliang Xiao . Straightforward and versatile construction of phenanthroline-derived diamide ligands for f-block element extraction. Chinese Chemical Letters, 2026, 37(1): 111252-. doi: 10.1016/j.cclet.2025.111252
20. [20]
  Bowen Xu , Jiahao Chen , Lulu Cui , Xinyue Li , Yuan Xue , Sheng Han . Terpolymers of alkyl methacrylate-trans anethole-1,2,3,6-tetrahydrophthalic anhydride copolymers: A low dosage and high-efficiency cold flow improver for diesel fuel. Chinese Chemical Letters, 2025, 36(5): 110196-. doi: 10.1016/j.cclet.2024.110196

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1376)
HTML views(73)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return