Citation: Hong She Wang, Jun E. Zeng. Iodine catalyzed efficient synthesis of symmetrical diaryl sulfoxides from arenes and thionyl chloride under solvent-free conditions[J]. Chinese Chemical Letters, ;2007, 18(12): 1447-1450. doi: 10.1016/j.cclet.2007.10.024 shu

Iodine catalyzed efficient synthesis of symmetrical diaryl sulfoxides from arenes and thionyl chloride under solvent-free conditions

Shaanxi Key Laboratory for Phytochemistry, Baoji University of Arts and Sciences, Baoji 721007, China

Received Date: 9 July 2007

Fund Project: This work was financially supported by the Science Research Foundation of Baoji University of Arts and Sciences (Zk064) and the Special Scientific Research Project of Shaanxi Education Commission (No.04JK147, No.05JS43).

Synthesis of symmetrical diaryl sulfoxides from arenes and thionyl chloride in the presence of a catalytic amount of iodine at room temperature under solvent-free conditions is described. Mild reaction conditions, easy workup, high yield, and easily available catalyst are important features of this method.
- Iodine,
- Aryl sulfoxides,
- Arenes,
- Thionyl chloride
1. [1]
  Lin Ding , Jinpeng Zhang , Junfeng Li , Daying Liu . Color Catcher: A Marvelous Encounter of Starch and Iodine. University Chemistry, 2024, 39(6): 334-341. doi: 10.3866/PKU.DXHX202311064
2. [2]
  Hongting Yan , Aili Feng , Rongxiu Zhu , Lei Liu , Dongju Zhang . Reexamination of the Iodine-Catalyzed Chlorination Reaction of Chlorobenzene Using Computational Chemistry Methods. University Chemistry, 2025, 40(3): 16-22. doi: 10.12461/PKU.DXHX202403010
3. [3]
  Pengcheng Su , Shizheng Chen , Zhihong Yang , Ningning Zhong , Chenzi Jiang , Wanbin Li . Vapor-phase postsynthetic amination of hypercrosslinked polymers for efficient iodine capture. Chinese Chemical Letters, 2024, 35(9): 109357-. doi: 10.1016/j.cclet.2023.109357
4. [4]
  Yu-Jie Long , Xiao-Ni Han , Ying Han , Chuan-Feng Chen . Recent advances in supramolecular luminescent materials based on macrocyclic arenes. Chinese Chemical Letters, 2025, 36(6): 110600-. doi: 10.1016/j.cclet.2024.110600
5. [5]
  Jia Peng , Guo-Ping Luo , Chao Wu , Congyang Wang . Visible light-induced deuteration of arenes via thianthrenation. Chinese Chemical Letters, 2025, 36(8): 111255-. doi: 10.1016/j.cclet.2025.111255
6. [6]
  Yajun Hou , Chuanzheng Zhu , Qiang Wang , Xiaomeng Zhao , Kun Luo , Zongshuai Gong , Zhihao Yuan . ~2.5 nm pores in carbon-based cathode promise better zinc-iodine batteries. Chinese Chemical Letters, 2024, 35(5): 108697-. doi: 10.1016/j.cclet.2023.108697
7. [7]
  Xinyi Cao , Yucheng Jin , Hailong Wang , Xu Ding , Xiaolin Liu , Baoqiu Yu , Xiaoning Zhan , Jianzhuang Jiang . A tetraaldehyde-derived porous organic cage and covalent organic frameworks: Syntheses, structures, and iodine vapor capture. Chinese Chemical Letters, 2024, 35(9): 109201-. doi: 10.1016/j.cclet.2023.109201
8. [8]
  Dongying Fu , Lin Pan , Yanli Ma , Yue Zhang . Bilayered Dion–Jacobson lead-iodine hybrid perovskite with aromatic spacer for broadband photodetection. Chinese Chemical Letters, 2025, 36(2): 109621-. doi: 10.1016/j.cclet.2024.109621
9. [9]
  Muhammad Riaz , Rakesh Kumar Gupta , Di Sun , Mohammad Azam , Ping Cui . Selective adsorption of organic dyes and iodine by a two-dimensional cobalt(II) metal-organic framework. Chinese Journal of Structural Chemistry, 2024, 43(12): 100427-100427. doi: 10.1016/j.cjsc.2024.100427
10. [10]
  Xiang Li , Beibei Zhang , Zhixiang Wang , Xiangyu Chen . Organocatalyzed iodine-mediated reversible-deactivation radical polymerization via photoinduced charge transfer complex catalysis. Chinese Chemical Letters, 2025, 36(6): 110383-. doi: 10.1016/j.cclet.2024.110383
11. [11]
  Jie Yang , Xin-Yue Lou , Dihua Dai , Jingwei Shi , Ying-Wei Yang . Desymmetrized pillar[8]arenes: High-yield synthesis, functionalization, and host-guest chemistry. Chinese Chemical Letters, 2025, 36(1): 109818-. doi: 10.1016/j.cclet.2024.109818
12. [12]
  Xixian Sun , Shengke Li , Ruibing Wang , Leyong Wang . Functional macrocyclic arenes with active binding sites inside cavity for biomimetic molecular recognition. Chinese Chemical Letters, 2025, 36(4): 110806-. doi: 10.1016/j.cclet.2024.110806
13. [13]
  Xueru Zhao , Aopu Wang , Shimin Wang , Zhijie Song , Li Ma , Li Shao . Adsorption and visual detection of nitro explosives by pillar[n]arenes-based host–guest interactions. Chinese Chemical Letters, 2025, 36(4): 110205-. doi: 10.1016/j.cclet.2024.110205
14. [14]
  Kun Zhang , Xin-Yue Lou , Yan Wang , Weiwei Huan , Ying-Wei Yang . Emission enhancement induced by the supramolecular assembly of leggero pillar[5]arenes for the detection and separation of silver ions. Chinese Chemical Letters, 2025, 36(6): 110464-. doi: 10.1016/j.cclet.2024.110464
15. [15]
  Xintian Qu , Zeen Liu , Zhifan Wang , Dongyan Yu , Xueqiu Huang , Jie Yang , Jiecheng Ji , Xueqin Wei , Cheng Yang . Achieving strong and tunable circularly polarized luminescence through pillar[5]arenes insertion in BINOL-Py-based chromophore. Chinese Chemical Letters, 2025, 36(11): 111024-. doi: 10.1016/j.cclet.2025.111024
16. [16]
  Yan-E Zhang , Yingtao Jiang , Yun Zhang , Hu Wang , Zitong Wu , Rui Li , Yumiao Ma , Tao Tu . Enantioselective synthesis of bulky planar-chiral pillar[n]arenes through dynamic kinetic resolution. Chinese Chemical Letters, 2025, 36(12): 111201-. doi: 10.1016/j.cclet.2025.111201
17. [17]
  Yu Tian , Yijun Lin , Siyu Deng , Yinghe Tan , Xuanyi Bie , Zhaoyang Chen , Pangkuan Chen . Metal-Coordinate Complexes (M = 3d, 4f) with Enhanced Circularly Polarized Luminescence in Planar Chiral Pillar[5]arenes. Chinese Journal of Structural Chemistry, 2025, 44(8): 100626-100626. doi: 10.1016/j.cjsc.2025.100626
18. [18]
  Xinyu Hu , Bo Song , Shukai Song , Qinghui Ling , Bangkun Yue , Lianrui Hu , Feifei Wang , Li He , Lin Xu . Development of luminescent metallohelicate as a selective chloride transporter. Chinese Chemical Letters, 2025, 36(12): 110918-. doi: 10.1016/j.cclet.2025.110918
19. [19]
  Laiyang ZHU , Xuze PAN , Xiaoying ZHANG , Xinyu XU , Shiheng LI , Fajin CAI , Yifan WANG , Qingxia YAO , Yi QIU , Jie SU . Synthesis of stable and porous bimetallic Ti-MOF for photocatalytic oxidation of aromatic sulfides to sulfoxides. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2115-2126. doi: 10.11862/CJIC.20250139
20. [20]
  Kailong Zhang , Chao Zhang , Luanhui Wu , Qidong Yang , Jiadong Zhang , Guang Hu , Liang Song , Gaoran Li , Wenlong Cai . Chloride molten salt derived attapulgite with ground-breaking electrochemical performance. Chinese Chemical Letters, 2024, 35(10): 109618-. doi: 10.1016/j.cclet.2024.109618

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(1259)
HTML views(39)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return