Citation: Hai Yan Wang, Da Xiong Han. A new method of immobilizing ionic liquids into layered zirconium phosphates[J]. Chinese Chemical Letters, ;2007, 18(6): 764-767. doi: 10.1016/j.cclet.2007.04.021 shu

A new method of immobilizing ionic liquids into layered zirconium phosphates

Hai Yan Wang ^a, ,
Da Xiong Han ^b

a The Key Laboratory of Global Change and Marine-Atmopheric Chemistry, Third Institute of Oceanography of State Oceanic Administration, Xiamen 361005, China;
b Department of Pharmacy, Medical College of Xiamen University, Xiamen 361005, China

Received Date: 13 November 2006

Fund Project: This work has been supported by the Grant for Youth from Third Institute of Oceanography of State Oceanic Administration of China (No. HF05005), the Natural Science Foundation of Fujian Province (No. 2006J0184) and the Grand Research Foundation of Fujian Province (No. 2005YZ1014).

In this work, a new method of a series of ion liquids (ILs) l-alkyl-3-methylimidazolium chloride[C_nmim]Cl (n=2, 4, 6, 8) intercalation into layered zirconium phosphates was investigated.It was found that the α-ZrP-2BA (i.e.pre-intercalated BA was arranged in a bilayer mode in the galleries ofα-ZrP) was a suitable host for intercalation ILs:ILs was inserted through exchanging pre-intercalated BA.And the intercalation orientation was investigated by use of X-ray diffraction (XRD) experiments and molecular modeling calculation.
- Ionic liquids,
- Zirconium phosphates,
- Intercalation
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