Citation: Guo Hui Zhu, Zhi Ming Li, Xiao Hua Chen, Jia Ming Liu, Tian Long Yang, Wen Qian Zhang, Shao Xian Lin, Ping Zhou. Determination of trace arsenic(V) by catalytic solid substrate-room temperature phosphorescence quenching method[J]. Chinese Chemical Letters, ;2007, 18(6): 711-713. doi: 10.1016/j.cclet.2007.04.017 shu

Determination of trace arsenic(V) by catalytic solid substrate-room temperature phosphorescence quenching method

a Department of Food and Biological Engineering, Zhangzhou Institute of Technology, Zhangzhou 363000, China;
b Department of Chemistry and Environmental Science, Zhangzhou Normal College, Zhangzhou 363000, China

Received Date: 21 January 2007

Fund Project: This work was supported by Fujian Province Natural Science Foundation (Nos. C 0510028, D 0510027 and 2006J0386).

In the H₂SO₄ medium and in the presence of dodecylbenzene sulfonic acid sodiumsalt (DBS), dimethyl yellow (R) could emit strong and stable solid substrate room temperature phosphorescence (RTF) on filter paper.And NaIO₄ could oxidize R to cause the RTF quenching.Arsenic (V) could catalyze the reaction of NaIO₄ oxidizing R, which caused the RTF sharply quenching.The reducing value of phosphorescence intensity (△I_p) for the system with DBS is 3.3 times higher than that without DBS.Moreover, the △I_p is proportional to the concentration of As (V).Based on the facts above, a new RTF quenching method for the determination of trace As (V) has been established.
- Arsenic(V),
- Dimethyl yellow,
- Catalytic solid substrate-room temperature phosphorescence quenching method
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