Citation: Xin Cui, Juan Li, Lei Liu, Qing Xiang Guo. 1, 3-Dicarbonyl compounds as phosphine-free ligands for Pd-catalyzed Heck and Suzuki reactions[J]. Chinese Chemical Letters, ;2007, 18(6): 625-628. doi: 10.1016/j.cclet.2007.04.014 shu

1, 3-Dicarbonyl compounds as phosphine-free ligands for Pd-catalyzed Heck and Suzuki reactions

Department of Chemistry, University of Science and Technology of China, Hefei 230026, China

Received Date: 25 December 2006

Fund Project: This research was supported by the NNSFC (No. 20332020, 20472079).

Some 1, 3-dicarbonyl compounds (such as pentane-2, 4-dione and 3-oxo-N-phenylbutanamide) were found to constitute highly efficient, yet low-priced and phosphine-free ligands for the Pd-catalyzed Heck and Suzuki reactions of aryl bromides and iodides with very high turnover numbers (ca.10³-10⁴).
- Palladium catalyst,
- Suzuki reaction,
- Heck reaction,
- Phosphine-free ligand
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