Citation: Chengyan Ge, Jiawei Hu, Xingyu Liu, Yuxi Song, Chao Liu, Zhigang Zou. Self-integrated black NiO clusters with ZnIn₂S₄ microspheres for photothermal-assisted hydrogen evolution by S-scheme electron transfer mechanism[J]. Acta Physico-Chimica Sinica, ;2026, 42(1): 100154. doi: 10.1016/j.actphy.2025.100154 shu

Self-integrated black NiO clusters with ZnIn₂S₄ microspheres for photothermal-assisted hydrogen evolution by S-scheme electron transfer mechanism

Chengyan Ge ¹ ,
Jiawei Hu ² ,
Xingyu Liu ² ,
Yuxi Song ² ,
Chao Liu ^2,, ,
Zhigang Zou ³

1.
School of Chemistry and Chemical Engineering, Yancheng Institute of Technology, Yancheng 224051, Jiangsu Province, China;
2.
School of Materials Science and Engineering, Yancheng Institute of Technology, Yancheng 224051, Jiangsu Province, China;
3.
Eco-Materials and Renewable Energy Research Centre (ERERC), Nanjing University, Nanjing 210093, Jiangsu Province, China

Corresponding author: Chao Liu, cliu@ycit.edu.cn
Received Date: 29 June 2025
Revised Date: 4 August 2025

Hydrogen (H₂) production technology utilizing solar energy is an essential strategy for questing carbon-neutral, but designing the optimal heterostructured photocatalysts is one of the great challenges. To date, the self-integration of highly-dispersed black NiO clusters with ZIS microspheres was successfully achieved during the solvothermal process. These constructed NiO/ZIS S-scheme heterostructured composites could provide more active for photocatalytic H₂ evolution (PHE) under visible light. The optimal 2-NiO/ZIS showed the best PHE rate of 2474.0 μmol g⁻¹ h⁻¹, highest apparent quantum yield (AQY) value of 36.67% and excellent structural stability. Furthermore, NiO/ZIS composites also exhibited the high PHE rates in natural seawater. The charge separation behaviors of the catalyst were systematically evaluated using advanced spectroscopic characterization techniques, specifically in situ XPS, time-resolved photoluminescence (TRPL) tested in water and transient absorption spectroscopy (TAS). The experimental analysis and theoretical calculation results elucidated the S-scheme charge transfer mechanism for NiO/ZIS. The promoted PHE activity was ascribed to the combined effect between black NiO clusters and ZIS, which enhanced light harvesting ability, accelerated charge carrier transportation and separation, remained high redox ability, and improved surface reaction kinetics. This study offers the insights into constructing S-scheme heterostructured composites with photothermal effect.
- S-scheme heterojunction,
- NiO clusters,
- ZnIn₂S₄,
- Photothermal effect,
- Hydrogen evolution
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Self-integrated black NiO clusters with ZnIn2S4 microspheres for photothermal-assisted hydrogen evolution by S-scheme electron transfer mechanism

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通讯作者: 陈斌, bchen63@163.com

Self-integrated black NiO clusters with ZnIn₂S₄ microspheres for photothermal-assisted hydrogen evolution by S-scheme electron transfer mechanism