微波合成铜负载的碳掺杂氮化硼光催化材料及其大气浓度下CO<sub>2</sub>还原性能研究

引用本文: 马浩桐, 衡明宇, 许杨, 毕炜, 缪应纯, 肖舒宁. 微波合成铜负载的碳掺杂氮化硼光催化材料及其大气浓度下CO₂还原性能研究[J]. 物理化学学报, 2025, 41(11): 100132. doi: 10.1016/j.actphy.2025.100132 shu

Citation: Haotong Ma, Mingyu Heng, Yang Xu, Wei Bi, Yingchun Miao, Shuning Xiao. Synergistic carbon doping and Cu loading on boron nitride via microwave synthesis for enhanced atmospheric CO₂ photoreduction[J]. Acta Physico-Chimica Sinica, 2025, 41(11): 100132. doi: 10.1016/j.actphy.2025.100132 shu

微波合成铜负载的碳掺杂氮化硼光催化材料及其大气浓度下CO₂还原性能研究

马浩桐 ^1, ,
衡明宇 ^1, ,
许杨 ^1, ,
毕炜 ^1, ,
缪应纯 ^{2,
,} ,
肖舒宁 ^{1,
,}

1.
上海理工大学材料与化学学院, 上海 200093
2.
曲靖师范学院化学与材料工程学院, 云南曲靖 655011

通讯作者: 缪应纯, ; 肖舒宁,

基金项目:
国家自然科学基金 22106105

国家自然科学基金 22406130

国家自然科学基金 22408229

上海市科技创新行动 22YF1430400

上海市科技创新行动 21DZ1206300

云南省高校协同创新中心(曲靖绿色光伏产业协同创新中心)

云南省科技厅科技人才与平台计划(云南省李和兴专家工作站) 202305AF150088

云南省科技厅科技人才与平台计划项目(云南省施正荣院士工作站) 202405AF140016

摘要: 在大气浓度下进行光催化CO₂还原极具挑战性，但对于实现碳中和技术应用却至关重要。本研究通过微波辅助熔盐法合成了一种负载铜(Cu)的碳(C)掺杂氮化硼(Cu/BCN)光催化剂。该方法能够同时将C引入BN晶格并选择性负载Cu纳米颗粒，形成高效的异质结构。C掺杂与Cu负载之间的协同作用调节了能带结构，增强了可见光吸收，促进了电荷分离，并改善了CO₂吸附。优化后的Cu/BCN光催化剂在环境CO₂条件下实现了30.62 μmol·g⁻¹·h⁻¹的CO产率，选择性为95.8%。结合实验和DFT分析证实，Cu/BCN界面促进了电荷转移，并降低了*COOH形成的能垒。这项工作展示了直接从空气中高效利用CO₂的有前景途径，为大气中的碳转化提供了一种可扩展的策略。

关键词:

English

Synergistic carbon doping and Cu loading on boron nitride via microwave synthesis for enhanced atmospheric CO₂ photoreduction

Haotong Ma ^1, ,
Mingyu Heng ^1, ,
Yang Xu ^1, ,
Wei Bi ^1, ,
Yingchun Miao ^{2,
,} ,
Shuning Xiao ^{1,
,}

1.
School of Materials and Chemistry, University of Shanghai for Science and Technology, Shanghai, 200093, China
2.
College of Chemistry and Material Engineering, Qujing Normal University, Qujing, 655011, Yunnan Province, China

Corresponding author: Email: Miaoyingchun1979@126.com (Y.M.); Emails: xiaosn@usst.edu.cn (S.X.)

Received Date: 25 June 2025
Accepted Date: 18 July 2025
Revised Date: 16 July 2025
Available Online: 15 November 2025
Fund Project:
the National Natural Science Foundation of China

the National Natural Science Foundation of China

the National Natural Science Foundation of China

Shanghai Science and Technology Innovation Program

Shanghai Science and Technology Innovation Program

Yunnan Provincial University Collaborative Innovation Center (Qujing Green Photovoltaic Industry Collaborative Innovation Center)

Yunnan Provincial Science and Technology Department Science Talent and Platform Program (Yunnan Province Li Hexing Expert Workstation)

Yunnan Provincial Science and Technology Department Science Talent and Platform Program Project (Yunnan Province Shi Zhengrong Academician Workstation)

Abstract: Photocatalytic CO₂ reduction under atmospheric concentrations remains highly challenging yet critical for practical carbon-neutral applications. In this study, a Cu-loaded, carbon-doped boron nitride (Cu/BCN) photocatalyst was synthesized by a microwave-assisted molten salt method. This approach enables simultaneous carbon incorporation into the BN lattice and selective deposition of Cu nanoparticles, forming an efficient heterostructure. The synergy between C doping and Cu loading modulates the band structure, enhances visible-light absorption, promotes charge separation, and improves CO₂ adsorption. The optimized Cu/BCN photocatalyst achieved a CO production rate of 30.62 μmol·g⁻¹·h⁻¹ with 95.8% selectivity under ambient CO₂ conditions. Combined experimental and DFT analyses confirm that the Cu/BCN interface facilitates charge transfer and lowers the energy barrier for *COOH formation. This work demonstrates a promising route toward efficient CO₂ utilization directly from air, offering a scalable strategy for atmospheric carbon conversion.

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沈阳化工大学材料科学与工程学院沈阳 110142

微波合成铜负载的碳掺杂氮化硼光催化材料及其大气浓度下CO₂还原性能研究

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English

Synergistic carbon doping and Cu loading on boron nitride via microwave synthesis for enhanced atmospheric CO₂ photoreduction

Corresponding author: Email: Miaoyingchun1979@126.com (Y.M.); Emails: xiaosn@usst.edu.cn (S.X.)

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中国化学会秘书处

微波合成铜负载的碳掺杂氮化硼光催化材料及其大气浓度下CO2还原性能研究

通讯作者: 缪应纯, ; 肖舒宁,

English

Synergistic carbon doping and Cu loading on boron nitride via microwave synthesis for enhanced atmospheric CO2 photoreduction

Corresponding author: Email: Miaoyingchun1979@126.com (Y.M.); Emails: xiaosn@usst.edu.cn (S.X.)

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通讯作者: 陈斌, bchen63@163.com

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微波合成铜负载的碳掺杂氮化硼光催化材料及其大气浓度下CO₂还原性能研究

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