Citation: Ziyang Long, Quanzheng Li, Chengliang Zhang, Haifeng Shi. BiVO₄/WO_3-x S-scheme heterojunctions with amplified internal electric field for boosting photothermal-catalytic activity[J]. Acta Physico-Chimica Sinica, ;2025, 41(10): 100122. doi: 10.1016/j.actphy.2025.100122 shu

BiVO₄/WO_3-x S-scheme heterojunctions with amplified internal electric field for boosting photothermal-catalytic activity

1.
School of Science, Jiangnan University, Wuxi 214122, Jiangsu Province, China
2.
Microelectronics Research Institute, Hangzhou Dianzi University, Hangzhou 310018, Zhejiang Province, China
3.
National Laboratory of Solid State Microstructures, Nanjing University, Nanjing 210093, Jiangsu Province, China

Corresponding author: Haifeng Shi, hfshi@jiangnan.edu.cn
Received Date: 13 May 2025
Revised Date: 13 June 2025
Accepted Date: 15 June 2025

Fund Project: the National Natural Science Foundation of China 52271175National Laboratory of Solid State Microstructures, Nanjing University M34047

Modulating the internal electric field (IEF) remains a critical challenge for S-scheme heterojunction photocatalysts. The BiVO₄/WO_3-x S-scheme heterojunctions were successfully prepared to purify the wastewater environment where tetracycline (TC) and Cr(Ⅵ) coexist under visible light illumination. The BiVO₄/WO_3-x with 10% (wt) WO_3-x (BVO/WO_3-x-10) demonstrated superior photocatalytic efficiency, which could degrade 78.5% of TC and reduce 85.3% of Cr(Ⅵ) in 60 min. The photocatalytic activity of BVO/WO_3-x-10 displayed enhanced removal efficiency in the mixed system. The removal ability of TC and Cr(Ⅵ) was increased by 1.29 and 1.32 times, respectively. Based on infrared thermography (IR) thermography measurements, the elevated reaction system temperatures were ascribed to the photothermal effect of WO_3-x. Oxygen vacancies (OVs) could amplify the energy band difference between WO_3-x and BiVO₄, which strengthens the IEF and accelerates the separation of carriers. A detailed degradation pathway and intermediate toxicity were carried out using the mung bean experiment and the results of the Liquid Chromatograph Mass Spectrometer (LC-MS). In general, this work provided new insights for regulating IEF to enhance the degradation efficiency in mixed wastewater and the carriers separation in the S-scheme heterojunction of the photothermal-catalytic system.
- S-scheme heterojunction,
- Internal electric field,
- Photothermal effect,
- Tetracycline,
- Cr(Ⅵ)
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

BiVO4/WO3-x S-scheme heterojunctions with amplified internal electric field for boosting photothermal-catalytic activity

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通讯作者: 陈斌, bchen63@163.com

BiVO₄/WO_3-x S-scheme heterojunctions with amplified internal electric field for boosting photothermal-catalytic activity