Citation: Bowen Liu, Jianjun Zhang, Han Li, Bei Cheng, Chuanbiao Bie. MOF-derived ZnO/PANI S-scheme heterojunction for efficient photocatalytic phenol mineralization coupled with H₂O₂ generation[J]. Acta Physico-Chimica Sinica, ;2025, 41(10): 100121. doi: 10.1016/j.actphy.2025.100121 shu

MOF-derived ZnO/PANI S-scheme heterojunction for efficient photocatalytic phenol mineralization coupled with H₂O₂ generation

1.
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, Hubei Province, China
2.
Laboratory of Solar Fuel, Faculty of Materials Science and Chemistry, China University of Geosciences, Wuhan 430078, Hubei Province, China
3.
School of Automotive Materials, Hubei University of Automotive Technology, Shiyan 442020, Hubei Province, China

Corresponding author: Chuanbiao Bie, biechuanbiao@cug.edu.cn
Received Date: 3 June 2025
Revised Date: 13 June 2025
Accepted Date: 15 June 2025

Fund Project: the National Key Research and Development Program of China 2022YFB3803600the National Natural Science Foundation of China 22202187the National Natural Science Foundation of China U24A2071the National Natural Science Foundation of China 22278324the National Natural Science Foundation of China 22361142704the National Natural Science Foundation of China U23A20102Hubei Provincial Natural Science Foundation 2025AFB492Hubei Provincial Natural Science Foundation 2022CFA001the Key R&D Program Projects in Hubei Province 2023BAB113

Complete mineralization of persistent organic pollutants in wastewater remains a formidable challenge. Here, we report the rational design of a ZIF-8-derived ZnO/polyaniline (PANI) S-scheme heterojunction synthesized via in situ oxidative polymerization. Advanced characterizations confirm the S-scheme charge transfer mechanism within the ZnO/PANI heterojunction. The optimized composite achieves complete phenol mineralization within 60 min while concurrently generating H₂O₂ at a rate of 0.75 mmol∙L⁻¹·h^–1 under simulated solar irradiation. Mechanistic studies verify that the S-scheme heterojunction retains strong redox potentials, driving the formation of reactive oxygen species for H₂O₂ production and phenol degradation. This work establishes a universal design paradigm for MOF-derived inorganic/organic S-scheme heterojunctions, effectively coupling solar-driven energy conversion with environmental remediation.
- Photocatalysis,
- S-scheme heterojunction,
- H₂O₂ production,
- Phenol degradation,
- ZnO
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

MOF-derived ZnO/PANI S-scheme heterojunction for efficient photocatalytic phenol mineralization coupled with H2O2 generation

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通讯作者: 陈斌, bchen63@163.com

MOF-derived ZnO/PANI S-scheme heterojunction for efficient photocatalytic phenol mineralization coupled with H₂O₂ generation