Citation: Bowen Liu, Jianjun Zhang, Han Li, Bei Cheng, Chuanbiao Bie. MOF-derived ZnO/PANI S-scheme heterojunction for efficient photocatalytic phenol mineralization coupled with H₂O₂ generation[J]. Acta Physico-Chimica Sinica, ;2025, 41(10): 100121. doi: 10.1016/j.actphy.2025.100121 shu

MOF-derived ZnO/PANI S-scheme heterojunction for efficient photocatalytic phenol mineralization coupled with H₂O₂ generation

1.
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, Hubei Province, China
2.
Laboratory of Solar Fuel, Faculty of Materials Science and Chemistry, China University of Geosciences, Wuhan 430078, Hubei Province, China
3.
School of Automotive Materials, Hubei University of Automotive Technology, Shiyan 442020, Hubei Province, China

Corresponding author: Chuanbiao Bie, biechuanbiao@cug.edu.cn
Received Date: 3 June 2025
Revised Date: 13 June 2025
Accepted Date: 15 June 2025

Fund Project: the National Key Research and Development Program of China 2022YFB3803600the National Natural Science Foundation of China 22202187the National Natural Science Foundation of China U24A2071the National Natural Science Foundation of China 22278324the National Natural Science Foundation of China 22361142704the National Natural Science Foundation of China U23A20102Hubei Provincial Natural Science Foundation 2025AFB492Hubei Provincial Natural Science Foundation 2022CFA001the Key R&D Program Projects in Hubei Province 2023BAB113

Complete mineralization of persistent organic pollutants in wastewater remains a formidable challenge. Here, we report the rational design of a ZIF-8-derived ZnO/polyaniline (PANI) S-scheme heterojunction synthesized via in situ oxidative polymerization. Advanced characterizations confirm the S-scheme charge transfer mechanism within the ZnO/PANI heterojunction. The optimized composite achieves complete phenol mineralization within 60 min while concurrently generating H₂O₂ at a rate of 0.75 mmol∙L⁻¹·h^–1 under simulated solar irradiation. Mechanistic studies verify that the S-scheme heterojunction retains strong redox potentials, driving the formation of reactive oxygen species for H₂O₂ production and phenol degradation. This work establishes a universal design paradigm for MOF-derived inorganic/organic S-scheme heterojunctions, effectively coupling solar-driven energy conversion with environmental remediation.
- Photocatalysis,
- S-scheme heterojunction,
- H₂O₂ production,
- Phenol degradation,
- ZnO
1. [1]
  Z. H. Jabbar, B. H. Graimed, J. Water Process. Eng. 47 (2022) 102671, https://doi.org/10.1016/j.jwpe.2022.102671 doi: 10.1016/j.jwpe.2022.102671
2. [2]
  A. Bibi, S. Bibi, M. Abu-Dieyeh, M. A. Al-Ghouti, J. Cleaner Prod. 417 (2023) 137810, https://doi.org/10.1016/j.jclepro.2023.137810 doi: 10.1016/j.jclepro.2023.137810
3. [3]
  L. K. Rathore, A. Bera, ACS Appl. Mater. Interfaces 16 (2024) 43670, https://doi.org/10.1021/acsami.4c10367 doi: 10.1021/acsami.4c10367
4. [4]
  S. Yadav, S. Kumar, A. K. Haritash, J. Environ. Manage. 342 (2023) 118254, https://doi.org/10.1016/j.jenvman.2023.118254 doi: 10.1016/j.jenvman.2023.118254
5. [5]
  Y. Lin, L. Gan, X. Zhao, G. Che, S. Wang, Q. Pan, Chem. Synth. 5 (2024) 4, https://doi.org/10.20517/cs.2024.17 doi: 10.20517/cs.2024.17
6. [6]
  Y. Dai, L. Yin, S. Wang, Y. Song, J. Hazard. Mater. 392 (2020) 122314, https://doi.org/10.1016/j.jhazmat.2020.122314 doi: 10.1016/j.jhazmat.2020.122314
7. [7]
  N. Goyal, P. Gao, Z. Wang, S. Cheng, Y. Ok, G. Li, L. Liu, J. Hazard. Mater. 392 (2020) 122494, https://doi.org/10.1016/j.jhazmat.2020.122494 doi: 10.1016/j.jhazmat.2020.122494
8. [8]
  H. Wu, Z. Hu, R. Liang, O. V. Nkwachukwu, O. A. Arotiba, M. Zhou, Appl. Catal. B 321 (2023) 122053, https://doi.org/10.1016/j.apcatb.2022.122053 doi: 10.1016/j.apcatb.2022.122053
9. [9]
  Z. Li, S. Li, Y. Tang, X. Li, J. Wang, L. Li, Chem. Eng. J. 391 (2020) 123533, https://doi.org/10.1016/j.cej.2019.123533 doi: 10.1016/j.cej.2019.123533
10. [10]
  L. Guo, L. Lu, M. Yin, R. Yang, Z. Zhang, W. Zhao, Chem. Eng. J. 397 (2020) 125420, https://doi.org/10.1016/j.cej.2020.125420 doi: 10.1016/j.cej.2020.125420
11. [11]
  A. E. Gahrouei, S. Vakili, A. Zandifar, S. Pourebrahimi, Environ. Res. 252 (2024) 119029, https://doi.org/10.1016/j.envres.2024.119029 doi: 10.1016/j.envres.2024.119029
12. [12]
  M. Gar Alalm, D. C. Boffito, Chem. Eng. J. 450 (2022) 138352, https://doi.org/10.1016/j.cej.2022.138352 doi: 10.1016/j.cej.2022.138352
13. [13]
  Y. Zhao, Y. Zhang, H. Tan, C. Ai, J. Zhang, J. Materiomics 11 (2025) 100970, https://doi.org/10.1016/j.jmat.2024.100970 doi: 10.1016/j.jmat.2024.100970
14. [14]
  S. Li, Y. Wu, H. Zheng, H. Li, Y. Zheng, J. Nan, J. Ma, D. Nagarajan, J. Chang, Chemosphere 311 (2023) 136977, https://doi.org/10.1016/j.chemosphere.2022.136977 doi: 10.1016/j.chemosphere.2022.136977
15. [15]
  B. Zhang, C. Fang, J. Ning, R. Dai, Y. Liu, Q. Wu, F. Zhang, W. Zhang, S. Dou, X. Liu, Carbon Neutralization 2 (2023) 646, https://doi.org/10.1002/cnl2.96 doi: 10.1002/cnl2.96
16. [16]
  J. Yang, H. Yin, A. Du, M. Tebyetekerwa, C. Bie, Z. Wang, Z. Sun, Z. Zhang, X. Zeng, X. Zhang, Appl. Catal. B 361 (2025) 124586, https://doi.org/10.1016/j.apcatb.2024.124586 doi: 10.1016/j.apcatb.2024.124586
17. [17]
  Y. Zhang, J. Qiu, B. Zhu, G. Sun, B. Cheng, L. Wang, Chin. J. Catal. 57 (2024) 143, https://doi.org/10.1016/S1872-2067(23)64580-2 doi: 10.1016/S1872-2067(23)64580-2
18. [18]
  Y. Zhang, Y. Wang, Y. Liu, S. Zhang, Y. Zhao, J. Zhang, J. Materiomics 11 (2025) 100985, https://doi.org/10.1016/j.jmat.2024.100985 doi: 10.1016/j.jmat.2024.100985
19. [19]
  C. Jiang, C. Yuan, K. Xu, X. Zhou, C. Bie, J. Mater. Sci. Technol. 231 (2025) 36, https://doi.org/10.1016/j.jmst.2024.12.071 doi: 10.1016/j.jmst.2024.12.071
20. [20]
  M. Gu, Y. Yang, B. Cheng, L. Zhang, P. Xiao, T. Chen, Chin. J. Catal. 59 (2024) 185, https://doi.org/10.1016/s1872-2067(23)64610-8 doi: 10.1016/s1872-2067(23)64610-8
21. [21]
  Y. Ma, S. Wang, Y. Zhang, B. Cheng, L. Zhang, J. Materiomics 11 (2025) 100978, https://doi.org/10.1016/j.jmat.2024.100978 doi: 10.1016/j.jmat.2024.100978
22. [22]
  W. Zhong, D. Zheng, Y. Ou, A. Meng, Y. Su, Acta Phys. -Chim. Sin. 40 (2024) 2406005, https://doi.org/10.3866/PKU.WHXB202406005 doi: 10.3866/PKU.WHXB202406005
23. [23]
  A. Meng, X. Ma, D. Wen, W. Zhong, S. Zhou, Y. Su, Chin. J. Catal. 60 (2024) 231, https://doi.org/10.1016/S1872-2067(24)60008-2 doi: 10.1016/S1872-2067(24)60008-2
24. [24]
  X. Zhang, H. Su, P. Cui, Y. Cao, Z. Teng, Q. Zhang, Y. Wang, Y. Feng, R. Feng, J. Hou, X. Zhou, P. Ma, H. Hu, K. Wang, C. Wang, L. Gan, Y. Zhao, Q. Liu, T. Zhang, K. Zheng, Nat. Commun. 14 (2023) 7115, https://doi.org/10.1038/s41467-023-42887-y doi: 10.1038/s41467-023-42887-y
25. [25]
  C. Bie, J. Yang, X. Zeng, Z. Wang, X. Sun, Z. Yang, J. Yu, X. Zhang, Small 21 (2025) 2411184, https://doi.org/10.1002/smll.202411184 doi: 10.1002/smll.202411184
26. [26]
  Y. Wu, Y. Yang, M. Gu, C. Bie, H. Tan, B. Cheng, J. Xu, Chin. J. Catal. 53 (2023) 123, https://doi.org/10.1016/s1872-2067(23)64514-0 doi: 10.1016/s1872-2067(23)64514-0
27. [27]
  Z. Jiang, B. Cheng, L. Zhang, Z. Zhang, C. Bie, Chin. J. Catal. 52 (2023) 32, https://doi.org/10.1016/s1872-2067(23)64502-4 doi: 10.1016/s1872-2067(23)64502-4
28. [28]
  Y. Wang, H. Sun, Z. Yang, Y. Zhu, Y. Xia, Carbon Neutralization 3 (2024) 737, https://doi.org/10.1002/cnl2.153 doi: 10.1002/cnl2.153
29. [29]
  Y. Ouyang, S. Zheng, G. Guan, Q. Yang, ACS Appl. Energy Mater. 5 (2022) 14455, https://doi.org/10.1021/acsaem.2c02993 doi: 10.1021/acsaem.2c02993
30. [30]
  J. Zhu, Q. Bi, Y. Tao, W. Guo, J. Fan, Y. Min, G. Li, Adv. Funct. Mater. 33 (2023) 2213131, https://doi.org/10.1002/adfm.202213131 doi: 10.1002/adfm.202213131
31. [31]
  S. Wan, W. Wang, B. Cheng, G. Luo, Q. Shen, J. Yu, J. Zhang, S. Cao, L. Zhang, Nat. Commun. 15 (2024) 9612, https://doi.org/10.1038/s41467-024-53951-6 doi: 10.1038/s41467-024-53951-6
32. [32]
  L. Zhang, J. Zhang, J. Yu, H. García, Nat. Rev. Chem. 9 (2025) 328, https://doi.org/10.1038/s41570-025-00698-3 doi: 10.1038/s41570-025-00698-3
33. [33]
  J. Yan, L. Wei, Acta Phys. -Chim. Sin. 40 (2024) 2312024, https://doi.org/10.3866/PKU.WHXB202312024 doi: 10.3866/PKU.WHXB202312024
34. [34]
  Y. Shiraishi, S. Kanazawa, Y. Sugano, D. Tsukamoto, H. Sakamoto, S. Ichikawa, T. Hirai, ACS Catal. 4 (2014) 774, https://doi.org/10.1021/cs401208c doi: 10.1021/cs401208c
35. [35]
  B. Zhu, C. Jiang, J. Xu, Z. Zhang, J. Fu, J. Yu, Mater. Today 82 (2025) 251, https://doi.org/10.1016/j.mattod.2024.11.012 doi: 10.1016/j.mattod.2024.11.012
36. [36]
  Q. Xia, C. Wang, N. Xu, J. Yang, G. Gao, J. Ding, Adv. Funct. Mater. 33 (2023) 2214769, https://doi.org/10.1002/adfm.202214769 doi: 10.1002/adfm.202214769
37. [37]
  Z. Cui, R. Yuan, H. Chen, B. Zhou, B. Zhu, C. Zhang, J. Water Process. Eng. 59 (2024) 104900, https://doi.org/10.1016/j.jwpe.2024.104900 doi: 10.1016/j.jwpe.2024.104900
38. [38]
  Y. Zhang, Y. Gao, R. Deng, Z. Qin, F. Shi, J. Zeng, C. Zhao, Y. Pu, T. Duan, Sep. Purif. Technol. 354 (2025) 129331, https://doi.org/10.1016/j.seppur.2024.129331 doi: 10.1016/j.seppur.2024.129331
39. [39]
  B. Liu, C. Bie, Y. Zhang, L. Wang, Y. Li, J. Yu, Langmuir 37 (2021) 14114, https://doi.org/10.1021/acs.langmuir.1c02360 doi: 10.1021/acs.langmuir.1c02360
40. [40]
  B. Zhou, S. Ding, K. Yang, J. Zhang, G. Huang, A. Pan, W. Hu, K. Li, W. Huang, Adv. Funct. Mater. 31 (2020) 2009230, https://doi.org/10.1002/adfm.202009230 doi: 10.1002/adfm.202009230
41. [41]
  S. Liu, H. Fu, F. Wang, Y. Wei, B. Meng, P. Wang, C. Zhao, W. Liu, C. Wang, Appl. Catal. B 346 (2024) 123753, https://doi.org/10.1016/j.apcatb.2024.123753 doi: 10.1016/j.apcatb.2024.123753
42. [42]
  T. Zou, C. Wang, R. Tan, W. Song, Y. Cheng, J. Hazard. Mater. 338 (2017) 276, https://doi.org/10.1016/j.jhazmat.2017.05.042 doi: 10.1016/j.jhazmat.2017.05.042
43. [43]
  B. A. Tahoun, E. M. Farag, M. A. Tony, S. A. Mansour, Appl. Water Sci. 13 (2023) 225, https://doi.org/10.1007/s13201-023-02020-2 doi: 10.1007/s13201-023-02020-2
44. [44]
  X. Wu, S. Liu, Y. Li, M. Yan, H. Lin, J. Chen, S. Liu, S. Wang, X. Duan, Angew. Chem. Int. Ed. 62 (2023) e202305639, https://doi.org/10.1002/anie.202305639 doi: 10.1002/anie.202305639
45. [45]
  A. Wang, J. Ni, W. Wang, X. Wang, D. Liu, Q. Zhu, J. Hazard. Mater. 426 (2022) 128106, https://doi.org/10.1016/j.jhazmat.2021.128106 doi: 10.1016/j.jhazmat.2021.128106
46. [46]
  B. Liu, K. Meng, B. Cheng, L. Wang, G. Liang, C. Bie, J. Mater. Sci. Technol. 231 (2025) 286, https://doi.org/10.1016/j.jmst.2025.02.013 doi: 10.1016/j.jmst.2025.02.013
47. [47]
  J. S. Algethami, M. S. Hassan, T. Amna, L. S. Alqarni, M. A. M. Alhamami, A. F. Seliem, Materials 16 (2023) 3314, https://doi.org/10.3390/ma16093314 doi: 10.3390/ma16093314
48. [48]
  C. Bie, C. Jiang, J. Yang, X. Sun, X. Zeng, J. Zhang, B. Zhu, J. Mater. Sci. Technol. 229 (2025) 48, https://doi.org/10.1016/j.jmst.2024.12.047 doi: 10.1016/j.jmst.2024.12.047
49. [49]
  Z. Zhou, C. Bie, P. Li, B. Tan, Y. Shen, Chin. J. Catal. 43 (2022) 2699, https://doi.org/10.1016/S1872-2067(22)64118-4 doi: 10.1016/S1872-2067(22)64118-4
50. [50]
  S. Cao, B. Zhong, C. Bie, B. Cheng, F. Xu, Acta Phys. -Chim. Sin. 40 (2024) 2307016, https://doi.org/10.3866/PKU.WHXB202307016 doi: 10.3866/PKU.WHXB202307016
51. [51]
  F. Zhang, X. Li, Q. Zhao, G. Chen, Q. Zhang, Appl. Catal. B 263 (2020) 118278, https://doi.org/10.1016/j.apcatb.2019.118278 doi: 10.1016/j.apcatb.2019.118278
52. [52]
  H. Zuo, C. Wu, H. Du, Z. Guo, Y. Cheng, Q. Yan, Appl. Surf. Sci. 633 (2023) 157600, https://doi.org/10.1016/j.apsusc.2023.157600 doi: 10.1016/j.apsusc.2023.157600
53. [53]
  Y. Zhang, J. Qiu, B. Zhu, M. V. Fedin, B. Cheng, J. Yu, L. Zhang, Chem. Eng. J. 444 (2022) 136584, https://doi.org/10.1016/j.cej.2022.136584 doi: 10.1016/j.cej.2022.136584
54. [54]
  C. Bie, Z. Meng, B. He, B. Cheng, G. Liu, B. Zhu, J. Mater. Sci. Technol. 173 (2024) 11, https://doi.org/10.1016/j.jmst.2023.07.019 doi: 10.1016/j.jmst.2023.07.019
55. [55]
  Z. Meng, J. Zhang, H. Long, H. García, L. Zhang, B. Zhu, J. Yu, Angew. Chem. Int. Ed. 64 (2025) e202505456, https://doi.org/10.1002/anie.202505456 doi: 10.1002/anie.202505456
56. [56]
  B. He, P. Xiao, S. Wan, J. Zhang, T. Chen, L. Zhang, J. Yu, Angew. Chem. Int. Ed. 62 (2023) e202313172, https://doi.org/10.1002/anie.202313172 doi: 10.1002/anie.202313172
57. [57]
  W. Yu, C. Bie, Acta Phys. -Chim. Sin. 40 (2024) 2307022, https://doi.org/10.3866/pku.whxb202307022 doi: 10.3866/pku.whxb202307022
58. [58]
  J. Yang, C. Bie, Chem. Synth. 5 (2024) 12, https://doi.org/10.20517/cs.2024.105 doi: 10.20517/cs.2024.105
59. [59]
  B. Liu, J. Cai, J. Zhang, H. Tan, B. Cheng, J. Xu, Chin. J. Catal. 51 (2023) 204, https://doi.org/10.1016/S1872-2067(23)64466-3 doi: 10.1016/S1872-2067(23)64466-3
60. [60]
  F. Xu, Y. He, J. Zhang, G. Liang, C. Liu, J. Yu, Angew. Chem. Int. Ed. 64 (2025) e202414672, https://doi.org/10.1002/anie.202414672 doi: 10.1002/anie.202414672
61. [61]
  W. Zhong, A. Meng, Y. Su, H. Yu, P. Han, J. Yu, Angew. Chem. Int. Ed. 64 (2025) e202425038, https://doi.org/10.1002/anie.202425038 doi: 10.1002/anie.202425038
62. [62]
  K. Meng, J. Zhang, B. Cheng, X. Ren, Z. Xia, F. Xu, L. Zhang, J. Yu, Adv. Mater. 36 (2024) 2406460, https://doi.org/10.1002/adma.202406460 doi: 10.1002/adma.202406460
63. [63]
  V. Ischenko, S. Polarz, D. Grote, V. Stavarache, K. Fink, M. Driess, Adv. Funct. Mater. 15 (2005) 1945-1954, https://doi.org/10.1002/adfm.200500087 doi: 10.1002/adfm.200500087
64. [64]
  K. Meng, J. Zhang, B. Zhu, C. Jiang, H. García, J. Yu, Adv. Mater. 37 (2025) 2505088, https://doi.org/10.1002/adma.202505088 doi: 10.1002/adma.202505088
65. [65]
  M. Gu, Y. Yang, L. Zhang, B. Zhu, G. Liang, J. Yu, Appl. Catal. B 324 (2023) 122227, https://doi.org/10.1016/j.apcatb.2022.122227 doi: 10.1016/j.apcatb.2022.122227
66. [66]
  M. Liu, M. Gao, L. Pei, Y. Ji, X. Gu, H. Wang, H. Tan, J. Zhao, J. Jia, Z. Zheng, Appl. Catal. B 284 (2021) 119710, https://doi.org/10.1016/j.apcatb.2020.119710 doi: 10.1016/j.apcatb.2020.119710
67. [67]
  Z. Lian, F. Gao, H. Xiao, D. Luo, M. Li, D. Fang, Y. Yang, J. Zi, H. Li, Angew. Chem. Int. Ed. 63 (2024) e202318927, https://doi.org/10.1002/anie.202318927 doi: 10.1002/anie.202318927
68. [68]
  L. Yang, Z. Chen, Q. Cao, H. Liao, J. Gao, L. Zhang, W. Wei, H. Li, J. Lu, Adv. Mater. 36 (2024) 2306758, https://doi.org/10.1002/adma.202306758 doi: 10.1002/adma.202306758
1. [1]
  Qishen Wang , Changzhao Chen , Mengqing Li , Lingmin Wu , Kai Dai . Lignin derived carbon quantum dots and oxygen vacancies coregulated S-scheme LCQDs/Bi₂WO₆ heterojunction for photocatalytic H₂O₂ production. Acta Physico-Chimica Sinica, 2025, 41(11): 100147-0. doi: 10.1016/j.actphy.2025.100147
2. [2]
  Jingping Li , Suding Yan , Jiaxi Wu , Qiang Cheng , Kai Wang . Improving hydrogen peroxide photosynthesis over inorganic/organic S-scheme photocatalyst with LiFePO₄. Acta Physico-Chimica Sinica, 2025, 41(9): 100104-0. doi: 10.1016/j.actphy.2025.100104
3. [3]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
4. [4]
  Chenye An , Sikandaier Abiduweili , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . Hierarchical S-scheme Heterojunction of Red Phosphorus Nanoparticles Embedded Flower-like CeO₂ Triggering Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-0. doi: 10.3866/PKU.WHXB202405019
5. [5]
  Jiayao Wang , Guixu Pan , Ning Wang , Shihan Wang , Yaolin Zhu , Yunfeng Li . Preparation of donor-π-acceptor type graphitic carbon nitride photocatalytic systems via molecular level regulation for high-efficient H₂O₂ production. Acta Physico-Chimica Sinica, 2025, 41(12): 100168-0. doi: 10.1016/j.actphy.2025.100168
6. [6]
  Jiali Lei , Juan Wang , Wenhui Zhang , Guohong Wang , Zihui Liang , Jinmao Li . TiO₂/CdIn₂S₄ S-scheme heterojunction photocatalyst promotes photocatalytic hydrogen evolution coupled vanillyl alcohol oxidation. Acta Physico-Chimica Sinica, 2025, 41(12): 100174-0. doi: 10.1016/j.actphy.2025.100174
7. [7]
  Yang Xia , Kangyan Zhang , Heng Yang , Lijuan Shi , Qun Yi . Improving Photocatalytic H₂O₂ Production over iCOF/Bi₂O₃ S-Scheme Heterojunction in Pure Water via Dual Channel Pathways. Acta Physico-Chimica Sinica, 2024, 40(11): 2407012-0. doi: 10.3866/PKU.WHXB202407012
8. [8]
  Xinyu Yin , Haiyang Shi , Yu Wang , Xuefei Wang , Ping Wang , Huogen Yu . Spontaneously Improved Adsorption of H₂O and Its Intermediates on Electron-Deficient Mn^(3+δ)+ for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312007-0. doi: 10.3866/PKU.WHXB202312007
9. [9]
  Wenlong Wang , Wentao Hao , Lang He , Jia Qiao , Ning Li , Chaoqiu Chen , Yong Qin . Bandgap and adsorption engineering of carbon dots/TiO₂ S-scheme heterojunctions for enhanced photocatalytic CO₂ methanation. Acta Physico-Chimica Sinica, 2025, 41(9): 100116-0. doi: 10.1016/j.actphy.2025.100116
10. [10]
  Yiting Huo , Xin Zhou , Feifan Zhao , Chenbin Ai , Zhen Wu , Zhidong Chang , Bicheng Zhu . Boosting photocatalytic CO₂ methanation through TiO₂/CdS S-scheme heterojunction and fs-TAS mechanism study. Acta Physico-Chimica Sinica, 2025, 41(11): 100148-0. doi: 10.1016/j.actphy.2025.100148
11. [11]
  Menglan Wei , Xiaoxia Ou , Yimeng Wang , Mengyuan Zhang , Fei Teng , Kaixuan Wang . S-scheme heterojunction g-C₃N₄/Bi₂WO₆ highly efficient degradation of levofloxacin: performance, mechanism and degradation pathway. Acta Physico-Chimica Sinica, 2025, 41(9): 100105-0. doi: 10.1016/j.actphy.2025.100105
12. [12]
  Deyun Ma , Fenglan Liang , Qingquan Xue , Yanping Liu , Chunqiang Zhuang , Shijie Li . Interfacial engineering of Cd_0.5Zn_0.5S/BiOBr S-scheme heterojunction with oxygen vacancies for effective photocatalytic antibiotic removal. Acta Physico-Chimica Sinica, 2025, 41(12): 100190-0. doi: 10.1016/j.actphy.2025.100190
13. [13]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-0. doi: 10.3866/PKU.WHXB202408005
14. [14]
  Yuejiao An , Wenxuan Liu , Yanfeng Zhang , Jianjun Zhang , Zhansheng Lu . Revealing Photoinduced Charge Transfer Mechanism of SnO₂/BiOBr S-Scheme Heterostructure for CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(12): 2407021-0. doi: 10.3866/PKU.WHXB202407021
15. [15]
  Yi Yang , Xin Zhou , Miaoli Gu , Bei Cheng , Zhen Wu , Jianjun Zhang . Femtosecond transient absorption spectroscopy investigation on ultrafast electron transfer in S-scheme ZnO/CdIn₂S₄ photocatalyst for H₂O₂ production and benzylamine oxidation. Acta Physico-Chimica Sinica, 2025, 41(6): 100064-0. doi: 10.1016/j.actphy.2025.100064
16. [16]
  Jiajie Cai , Chang Cheng , Bowen Liu , Jianjun Zhang , Chuanjia Jiang , Bei Cheng . CdS/DBTSO-BDTO S-scheme photocatalyst for H₂ production and its charge transfer dynamics. Acta Physico-Chimica Sinica, 2025, 41(8): 100084-0. doi: 10.1016/j.actphy.2025.100084
17. [17]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-0. doi: 10.3866/PKU.WHXB202403005
18. [18]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . Efficient Photocatalytic Production of H₂O₂ over ZnO/D-A Conjugated Polymer S-scheme Heterojunction and Charge Transfer Dynamics Investigation. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-0. doi: 10.3866/PKU.WHXB202406027
19. [19]
  Shuang Cao , Bo Zhong , Chuanbiao Bie , Bei Cheng , Feiyan Xu . Insights into Photocatalytic Mechanism of H₂ Production Integrated with Organic Transformation over WO₃/Zn_0.5Cd_0.5S S-Scheme Heterojunction. Acta Physico-Chimica Sinica, 2024, 40(5): 2307016-0. doi: 10.3866/PKU.WHXB202307016
20. [20]
  Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO₂/Bi₂MoO₆ Microsphere Heterojunction for Efficient Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-0. doi: 10.3866/PKU.WHXB202309031

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(66)
HTML views(16)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

MOF-derived ZnO/PANI S-scheme heterojunction for efficient photocatalytic phenol mineralization coupled with H2O2 generation

Metrics

通讯作者: 陈斌, bchen63@163.com

MOF-derived ZnO/PANI S-scheme heterojunction for efficient photocatalytic phenol mineralization coupled with H₂O₂ generation