MOF衍生的ZnO/PANI S型异质结用于高效光催化苯酚矿化耦合H<sub>2</sub>O<sub>2</sub>生产

引用本文: 刘博文, 张建军, 李瀚, 程蓓, 别传彪. MOF衍生的ZnO/PANI S型异质结用于高效光催化苯酚矿化耦合H₂O₂生产[J]. 物理化学学报, 2025, 41(10): 100121. doi: 10.1016/j.actphy.2025.100121 shu

Citation: Bowen Liu, Jianjun Zhang, Han Li, Bei Cheng, Chuanbiao Bie. MOF-derived ZnO/PANI S-scheme heterojunction for efficient photocatalytic phenol mineralization coupled with H₂O₂ generation[J]. Acta Physico-Chimica Sinica, 2025, 41(10): 100121. doi: 10.1016/j.actphy.2025.100121 shu

MOF衍生的ZnO/PANI S型异质结用于高效光催化苯酚矿化耦合H₂O₂生产

刘博文 ^1, ,
张建军 ^2, ,
李瀚 ^3, ,
程蓓 ^1, ,
别传彪 ^{2,
,}

1.
武汉理工大学材料复合新技术全国重点实验室, 湖北武汉 430070
2.
中国地质大学(武汉)材料与化学学院, 太阳燃料实验室, 湖北武汉 430078
3.
湖北汽车工业学院汽车材料学院, 湖北十堰 442020

通讯作者: 别传彪, biechuanbiao@cug.edu.cn

基金项目:
国家重点研发计划项目 2022YFB3803600

国家自然科学基金 22202187

国家自然科学基金 U24A2071

国家自然科学基金 22278324

国家自然科学基金 22361142704

国家自然科学基金 U23A20102

湖北省自然科学基金 2025AFB492

湖北省自然科学基金 2022CFA001

湖北省重点研发计划项目 2023BAB113

摘要: 持久性有机污染物在废水中的完全矿化仍是一项艰巨挑战。本研究报道了一种通过原位氧化聚合法合成的ZIF-8衍生ZnO/聚苯胺(PANI)S型异质结的理性设计。先进表征技术证实了ZnO/PANI异质结内S型电荷转移机制。优化后的复合材料在模拟太阳光照射下，60 min内实现苯酚完全矿化，同时以0.75 mmol∙L⁻¹·h^–1的速率生成H₂O₂。机理研究表明，S型异质结保留了强氧化还原电势，驱动活性氧物种的形成，从而实现H₂O₂合成与苯酚降解。该工作为MOF衍生的无机/有机S型异质结建立了普适性设计范式，有效耦合了太阳能驱动的能源转化与环境修复。

关键词:

English

MOF-derived ZnO/PANI S-scheme heterojunction for efficient photocatalytic phenol mineralization coupled with H₂O₂ generation

1.
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, Hubei Province, China
2.
Laboratory of Solar Fuel, Faculty of Materials Science and Chemistry, China University of Geosciences, Wuhan 430078, Hubei Province, China
3.
School of Automotive Materials, Hubei University of Automotive Technology, Shiyan 442020, Hubei Province, China

Corresponding author: Chuanbiao Bie, Email: biechuanbiao@cug.edu.cn

Received Date: 03 June 2025
Accepted Date: 15 June 2025
Revised Date: 13 June 2025
Available Online: 15 October 2025
Fund Project:
the National Key Research and Development Program of China

the National Natural Science Foundation of China

the National Natural Science Foundation of China

the National Natural Science Foundation of China

the National Natural Science Foundation of China

the National Natural Science Foundation of China

Hubei Provincial Natural Science Foundation

Hubei Provincial Natural Science Foundation

the Key R&D Program Projects in Hubei Province

Abstract: Complete mineralization of persistent organic pollutants in wastewater remains a formidable challenge. Here, we report the rational design of a ZIF-8-derived ZnO/polyaniline (PANI) S-scheme heterojunction synthesized via in situ oxidative polymerization. Advanced characterizations confirm the S-scheme charge transfer mechanism within the ZnO/PANI heterojunction. The optimized composite achieves complete phenol mineralization within 60 min while concurrently generating H₂O₂ at a rate of 0.75 mmol∙L⁻¹·h^–1 under simulated solar irradiation. Mechanistic studies verify that the S-scheme heterojunction retains strong redox potentials, driving the formation of reactive oxygen species for H₂O₂ production and phenol degradation. This work establishes a universal design paradigm for MOF-derived inorganic/organic S-scheme heterojunctions, effectively coupling solar-driven energy conversion with environmental remediation.

Key words:

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沈阳化工大学材料科学与工程学院沈阳 110142

MOF衍生的ZnO/PANI S型异质结用于高效光催化苯酚矿化耦合H₂O₂生产

通讯作者: 别传彪, biechuanbiao@cug.edu.cn

English

MOF-derived ZnO/PANI S-scheme heterojunction for efficient photocatalytic phenol mineralization coupled with H₂O₂ generation

Corresponding author: Chuanbiao Bie, Email: biechuanbiao@cug.edu.cn

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通讯作者: 别传彪, biechuanbiao@cug.edu.cn

English

MOF-derived ZnO/PANI S-scheme heterojunction for efficient photocatalytic phenol mineralization coupled with H2O2 generation

Corresponding author: Chuanbiao Bie, Email: biechuanbiao@cug.edu.cn

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

MOF衍生的ZnO/PANI S型异质结用于高效光催化苯酚矿化耦合H₂O₂生产

MOF-derived ZnO/PANI S-scheme heterojunction for efficient photocatalytic phenol mineralization coupled with H₂O₂ generation

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs