Citation: Qi Wang, Yuqing Liu, Jiefei Wang, Yuan-Yuan Ma, Jing Du, Zhan-Gang Han. Catalysts for electrocatalytic dechlorination of chlorinated aromatic hydrocarbons: synthetic strategies, applications, and challenges[J]. Acta Physico-Chimica Sinica, ;2025, 41(10): 100120. doi: 10.1016/j.actphy.2025.100120 shu

Catalysts for electrocatalytic dechlorination of chlorinated aromatic hydrocarbons: synthetic strategies, applications, and challenges

Qi Wang ^{1, 2} ,
Yuqing Liu ¹ ,
Jiefei Wang ¹ ,
Yuan-Yuan Ma ^1,, ,
Jing Du ^1,, ,
Zhan-Gang Han ^1,,

1.
Hebei Technology Innovation Center for Energy Conversion Materials and Devices, Hebei Engineering Research Center of Thin Film Solar Cell Materials and Devices, National Demonstration Center for Experimental Chemistry Education, Testing and Analysis Center, College of Chemistry and Materials Science, Hebei Normal University, Shijiazhuang 050024, Hebei Province, China
2.
College of Chemistry and Chemical Engineering, Xingtai University, Xingtai 054001, Hebei Province, China

Corresponding author: Yuan-Yuan Ma, mayy334@hebtu.edu.cn Jing Du, duj622@hebtu.edu.cn Zhan-Gang Han, hanzg116@hebtu.edu.cn
Received Date: 16 April 2025
Revised Date: 25 May 2025
Accepted Date: 11 June 2025

Fund Project: the National Natural Science Foundation of China 22471056the National Natural Science Foundation of China 22301058the National Natural Science Foundation of China 22371065the Natural Science Foundation of Hebei Province B2024205033the Natural Science Foundation of Hebei Province B2024205007the Natural Science Foundation of Hebei Province B2022205005the Science and Technology Project of Hebei Education Department QN2023049the China Postdoctoral Science Foundation funded project 2021TQ0095the Project of Science and Technology Department of Hebei Province 22567622Hthe Science Foundation of Hebei Normal University L2023B51

Electrocatalytic hydrodechlorination (EHDC) is a promising technology for degrading chlorinated aromatic hydrocarbons (CAHs), offering high efficiency, minimal secondary pollution, and mild operating conditions. Its effectiveness relies on three critical steps: atomic hydrogen (H*) generation, C―Cl bond cleavage, and adsorption/desorption of CAHs/products. Developing high-performance electrocatalysts is essential to optimize energy efficiency and cost-effectiveness. It is urgent to summarize research progress on design strategies for catalysts and establish fundamental principles. In this review, we first summarize commonly deployed measurement methods and metrics for assessing catalyst activity and stability in EHDC. Then, a series of strategies for enhancing the production of H*, facilitating the cleavage of C―Cl bonds, and optimizing the adsorption and desorption kinetics of CAHs and their intermediates/products on the catalyst surface are summarized. These strategies include the loading of catalysts on carbon-based/transition-based support to enhance the dispersion of Pd; constructing heterostructures or forming alloys to modulate the electronic structure of active metal nanocatalysts and optimize its binding affinities with reactants and intermediates; and modulating the microenvironment to modify the interface hydrophilicity/hydrophobicity of catalyst to increase reaction rates or improve stability of catalysts. Additionally, the applications of electrocatalysts for EHDC in recent years, such as Pd-based supported electrocatalysts, Pd-based heterostructure electrocatalysts, Pd-based alloy electrocatalysts, and noble-metal-free electrocatalysts are discussed, as well as the influence of catalyst composition on performance. It is noted that the EHDC efficiency of CAHs is influenced not only by the catalyst but also significantly correlated with the structure of CAHs. Thus, the effects of CAHs structures on EHDC performance are also discussed. Studies demonstrate that weak adsorption between the electrode and CAHs is more conducive to EHDC reactions. The number and position of chlorine functional groups, steric hindrance, and the properties of other functional groups in the substrate molecule can also influence EHDC performance. Finally, the challenges and future prospects of EHDC are highlighted, including improving the catalytic performance of non-noble catalysts, employing advanced in situ and operando characterization techniques, and optimizing DFT calculations to more closely align with real catalytic conditions, all aiming to inspire new investigations and advancements in the field of EHDC of CAHs.
- Electrocatalytic hydrodechlorination,
- Chlorinated aromatic hydrocarbon,
- Electrocatalyst,
- Construction strategy
1. [1]
  M. Chen, S. Shu, J. X. Li, X. S. Lv, F. Dong, G. M. Jiang, J. Hazard. Mater. 389 (2020) 121876, https://doi.org/10.1016/j.jhazmat.2019.121876. doi: 10.1016/j.jhazmat.2019.121876
2. [2]
  M. Y. Mao, J. Wu, Y. Wang, Y. Long, G. Y. Fan, Appl. Surf. Sci. 600 (2022) 153988, https://doi.org/10.1016/j.apsusc.2022.153988. doi: 10.1016/j.apsusc.2022.153988
3. [3]
  T. Wu, Y. Zuo, H. Chen, Z. Xu, S. Zheng, Appl. Catal. A-Gen. 666 (2023) 119407, https://doi.org/10.1016/j.apcata.2023.119407. doi: 10.1016/j.apcata.2023.119407
4. [4]
  G. M. Jiang, K. F. Wang, J. Y. Li, W. Y. Fu, Z. Y. Zhang, G. Johnson, X. S. Lv, Y. Zhang, S. Zhang, F. Dong, Chem. Eng. J. 348 (2018) 26, https://doi.org/10.1016/j.cej.2018.04.173. doi: 10.1016/j.cej.2018.04.173
5. [5]
  B. Yang, G. Yu, D. M. Shuai, Chemosphere 67 (2007) 1361, https://doi.org/10.1016/j.chemosphere.2006.10.046. doi: 10.1016/j.chemosphere.2006.10.046
6. [6]
  Y. Gao, D. He, L. Wu, Z. P. Wang, Y. Yao, Z. -H. Huang, H. Yang, M. -X. Wang, Chem. Eng. J. 420 (2021) 127411, https://doi.org/10.1016/j.cej.2020.127411. doi: 10.1016/j.cej.2020.127411
7. [7]
  Z. T. Liu, Z. Zhou, W. Xiong, Q. Zhang, Langmuir 34 (2018) 10389, https://doi.org/10.1021/acs.langmuir.8b02156. doi: 10.1021/acs.langmuir.8b02156
8. [8]
  Z. W. Cheng, D. Shou, P. Zhao, J. M. Chen, J. K. Zhao, J. M. Yu, S. H. Zhang, Y. H. Guan, Int. Biodeterior. Biodegrad. 180 (2023) 105585, https://doi.org/10.1016/j.ibiod.2023.105585. doi: 10.1016/j.ibiod.2023.105585
9. [9]
  X. Zhou, H. P. Luo, Q. Y. Chen, X. Cao C. S., Shen, J. Zhou, Chem. Eng. J. 402 (2020) 126175, https://doi.org/10.1016/j.cej.2020.126175. doi: 10.1016/j.cej.2020.126175
10. [10]
  Y. Xue, Z. H. Wang, R. Bush, F. Yang, R. X. Yuan, J. S. Liu, N. Smith, M. H. Huang, R. Dharmarajan, P. Annamalai, Chem. Eng. J. 415 (2021) 129041, https://doi.org/10.1016/j.cej.2021.129041. doi: 10.1016/j.cej.2021.129041
11. [11]
  Q. Wang, Q. Liu, Y. -Y. Ma, H. -X. Bi, J. Du, Z. -G. Han, Inorg. Chem. Front. 11 (2024) 1238, https://doi.org/10.1039/D3QI02130K. doi: 10.1039/D3QI02130K
12. [12]
  J. Liu, D. D. Han, P. J. Chen, L. P. Zhai, Y. J. Wang, W. H. Chen, L. W. Mi, L. P. Yang, Chem. Eng. J. 418 (2021) 129492, https://doi.org/10.1016/j.cej.2021.129492. doi: 10.1016/j.cej.2021.129492
13. [13]
  X. Y. Yu, D. Cabooter, R. Dewil, J. Hazard. Mater. 357 (2018) 81, https://doi.org/10.1016/j.jhazmat.2018.05.049. doi: 10.1016/j.jhazmat.2018.05.049
14. [14]
  Z. Zhang, N. Cissoko, J. J. Wo, X. H. Xu, J. Hazard. Mater. 165 (2009) 78, https://doi.org/10.1016/j.jhazmat.2008.09.080. doi: 10.1016/j.jhazmat.2008.09.080
15. [15]
  J. X. Li, Y. Y. Peng, W. D. Zhang, X. L. Shi, M. Chen, P. Wang, X. M. Zhang, H. L. Fu, X. Lv, F. Dong, Appl. Surf. Sci. 509 (2020) 145369, https://doi.org/10.1016/j.apsusc.2020.145369. doi: 10.1016/j.apsusc.2020.145369
16. [16]
  W. Y. Fu, S. Shu, J. X. Li, X. L. X. S. Shi, Y. X. Lv, Huang, F. Dong, G. M. Jiang, Nanoscale 11 (2019) 15892, https://doi.org/10.1039/C9NR04634H. doi: 10.1039/C9NR04634H
17. [17]
  Y. -H. Xu, H. -X. Ma, Q. -Q. Cai, Y. -H. Zhu, C. -A. Ma, Acta Phys. -Chim. Sin. 29 (2013) 973, https://doi.org/10.3866/PKU.WHXB201302283. doi: 10.3866/PKU.WHXB201302283
18. [18]
  H. X. Ma, T. J. Ge, Q. Q. Cai, Y. H. Xu, C. A. Ma, Acta Phys. -Chim. Sin. 32 (2016) 1715, https://doi.org/10.3866/PKU.WHXB20160412. doi: 10.3866/PKU.WHXB20160412
19. [19]
  Z. C. Mao, L. H. Liu, H. B. Yang, Y. L. Zhang, Z. Q. Yao, H. Wu, Y. Q. Huang, Y. H. Xu, B. Liu, Electrochim. Acta 391 (2021) 138886, https://doi.org/10.1016/j.electacta.2021.138886. doi: 10.1016/j.electacta.2021.138886
20. [20]
  H. Wu, H. X. Chen, C. C. Yu, R. F. Qu, M. Q. Shi, Z. M. Lou, J. Q. Zhu, J. M. Yu, Y. H. Xu, Chem. Eng. J. 463 (2023) 142484, https://doi.org/10.1016/j.cej.2023.142484. doi: 10.1016/j.cej.2023.142484
21. [21]
  H. Wu, Z. C. Mao, B. Q. Liu, D. Y. Chen, M. Q. Shi, B. S. Lv, Y. H. Xu, L. B. Wang, Appl. Catal. B-Environ. 337 (2023) 122978, https://doi.org/10.1016/j.apcatb.2023.122978. doi: 10.1016/j.apcatb.2023.122978
22. [22]
  Y. H. Xu, Z. C. Mao, R. F. Qu, J. S. Wang, J. M. Yu, X. Y. Luo, M. Q. Shi, X. B. Mao, J. Ding, B. Liu, Nat. Water 1 (2023) 95, https://doi.org/10.1038/s44221-022-00002-3. doi: 10.1038/s44221-022-00002-3
23. [23]
  H. Wu, L. Q. Chen, C. Tang, X. Y. Fan, Q. Liu, Y. H. Xu, Sep. Purif. Technol. 331 (2024) 125647, https://doi.org/10.1016/j.seppur.2023.125647. doi: 10.1016/j.seppur.2023.125647
24. [24]
  Y. Y. Peng, M. Y. Cui, Z. Y. Zhang, S. Shu, X. L. Shi, J. T. Brosnahan, C. Liu, Y. L. Zhang, P. Godbold, X. M. Zhang, F. Dong, G. M. Jiang, S. Zhang, ACS Catal. 9 (2019) 10803, https://doi.org/10.1021/acscatal.9b02282. doi: 10.1021/acscatal.9b02282
25. [25]
  Z. M. Lou, J. S. Zhou, M. Sun, J. Xu, K. L. Yang, D. Lv, Y. P. Zhao, X. H. Xu, Chem. Eng. J. 352 (2018) 549, https://doi.org/10.1016/j.cej.2018.07.057. doi: 10.1016/j.cej.2018.07.057
26. [26]
  A. Winkel, G. Proske, Ber. Dtsch. Chem. Ges. 69 (1936) 1917, https://doi.org/10.1002/cber.19360690823. doi: 10.1002/cber.19360690823
27. [27]
  M. Stackelberg, W. Z. Stracke, Elektrochem. Angew. Phys. Chem. 53 (2010) 118, https://doi.org/10.1002/bbpc.19490530308. doi: 10.1002/bbpc.19490530308
28. [28]
  G. M. Jiang, M. N. Lan, Z. Y. Zhang, X. S. Lv, Z. M. Lou, X. H. Xu, F. Dong, S. Zhang, Environ. Sci. Technol. 51 (2017) 7599, https://doi.org/10.1021/acs.est.7b01128. doi: 10.1021/acs.est.7b01128
29. [29]
  Z. M. Lou, Z. N. Wang, J. S. Zhou, C. C. Zhou, J. Xu, X. H. Xu, Environ. Sci-Nano. 7 (2020) 1566, https://doi.org/10.1039/D0EN00182A. doi: 10.1039/D0EN00182A
30. [30]
  Q. Wang, L. X. Zhou, Q. Chen, M. Y. Mao, W. D. Jiang, Y. Long, G. Y. Fan, J. Hazard. Mater. 408 (2021) 124456, https://doi.org/10.1016/j.jhazmat.2020.124456. doi: 10.1016/j.jhazmat.2020.124456
31. [31]
  Z. M. Zhang, R. Cheng, J. Nan, X. Q. Chen, C. Huang, D. Cao, C. H. Bai, J. L. Han, B. Liang, Z. L. Li, A. J. Wang, Chin. Chem. Lett. 33 (2022) 3823, https://doi.org/10.1016/j.cclet.2021.11.068. doi: 10.1016/j.cclet.2021.11.068
32. [32]
  K. F. Wang, S. Shu, M. Chen, J. Li, K. Zhou, J. Pan, X. L. Wang, X. J. Li, J. P. Sheng, F. Dong, Chem. Eng. J. 381 (2020) 122673, https://doi.org/10.1016/j.cej.2019.122673. doi: 10.1016/j.cej.2019.122673
33. [33]
  Q. Wang, J. Du, Y. Y. Ma, X. Y. Yin, Z. Y. Tian, Z. G. Han, Chem. Eng. J. 451 (2023) 139107, https://doi.org/10.1016/j.cej.2022.139107. doi: 10.1016/j.cej.2022.139107
34. [34]
  P. Wang, X. L. Shi, C. H. Fu, X. J. Li, J. X. Li, X. S. Lv, Y. H. Chu, F. Dong, G. M. Jiang, Nanoscale 12 (2020) 843, https://doi.org/10.1039/C9NR07528C. doi: 10.1039/C9NR07528C
35. [35]
  A. A. Isse, B. B. Huang, C. Durante, A. Gennaro, Appl. Catal. B-Environ. 126 (2012) 347, https://doi.org/10.1016/j.apcatb.2012.07.004. doi: 10.1016/j.apcatb.2012.07.004
36. [36]
  F. Wang, Z. Q. Fan, X. H. Wu, M. C. Li, C. A. Ma, Int. J. Electrochem. Sci. 10 (2015) 5101, https://doi.org/10.1016/S1452-3981(23)06690-7. doi: 10.1016/S1452-3981(23)06690-7
37. [37]
  J. Halász, B. Imre, I. Hannus, Appl. Catal. A-Gen. 271 (2004) 47, https://doi.org/10.1016/j.apcata.2004.02.045. doi: 10.1016/j.apcata.2004.02.045
38. [38]
  L. V. Romashov, L. L. Khemchyan, E. G. Gordeev, I. O. Koshevoy, S. P. Tunik, V. P. Ananikov, Organometallics 33 (2014) 6003, https://doi.org/10.1021/om500620u. doi: 10.1021/om500620u
39. [39]
  S. X. Wang, M. D. Yang, C. Y. Cui, Q. Z. Zheng, C. Z. Zhou, Y. J. Xin, Electrochim. Acta. 462 (2023) 142707, https://doi.org/10.1016/j.electacta.2023.142707. doi: 10.1016/j.electacta.2023.142707
40. [40]
  H. H. Qian, Y. T. Su, S. Yan, W. J. Fang, K. Yang, X. L. Weng, Appl. Surf. Sci. 665 (2024) 160245, https://doi.org/10.1016/j.apsusc.2024.160245. doi: 10.1016/j.apsusc.2024.160245
41. [41]
  J. M. Wang, X. F. Wei, P. P. Wang, J. Miao, R. C. Zhang, N. Zhang, X. Q. Zhou, H. Xu, J. Zhang, H. S. Li, S. G. Peng, Fuel 341 (2023) 127689, https://doi.org/10.1016/j.fuel.2023.127689. doi: 10.1016/j.fuel.2023.127689
42. [42]
  J. J. Li, S. M. Ma, Z. Y. Qi, J. Ding, M. H. Yin, B. Zhao, Z. R. Zhang, Y. Wang, H. W. Zhang, L. Wang, D. D. Dionysious, Appl. Catal. B-Environ. 322 (2023) 122076, https://doi.org/10.1016/j.apcatb.2022.122076. doi: 10.1016/j.apcatb.2022.122076
43. [43]
  Y. J. Chen, C. Feng, W. H. Wang, Z. Liu, J. X. Li, C. G. Liu, Y. Pan, Y. Q. Liu, Sep. Purif. Technol. 289 (2022) 120731, https://doi.org/10.1016/j.seppur.2022.120731. doi: 10.1016/j.seppur.2022.120731
44. [44]
  Z. Y. Kong, D. H. Li, R. S. Cai, T. Li, L. P. Diao, X. K. Chen, X. X. Wang, H. J. Zheng, Y. Jia, D. J. Yang, J. Hazard. Mater. 463 (2024) 132964, https://doi.org/10.1016/j.jhazmat.2023.132964. doi: 10.1016/j.jhazmat.2023.132964
45. [45]
  Z. F. Zhao, X. Y. Yao, R. P. Yu, X. Y. Luo, M. H. Chen, X. X. Zhang, Y. H. Xu, Y. Q. Chu, X. B. Mao, H. J. Zheng, Chem. Eng. J. 492 (2024) 152340, https://doi.org/10.1016/j.cej.2024.152340. doi: 10.1016/j.cej.2024.152340
46. [46]
  J. W. Lu, S. N. Zhang, H. Z. Zhou, C. J. Huang, L. Xia, X. F. Liu, H. Luo, H. Wang, Acta Phys. -Chim. Sin. 39 (2023) 2302021, https://doi.org/10.3866/PKU.WHXB202302021. doi: 10.3866/PKU.WHXB202302021
47. [47]
  C. M. Li, K. Chen, X. Y. Wang, N. Xue, H. Q. Yang, Acta Phys. -Chim. Sin. 37 (2021) 2009101, https://doi.org/10.3866/PKU.WHXB202009101. doi: 10.3866/PKU.WHXB202009101
48. [48]
  J. X. Li, Y. J. Chen, R. Y. Bai, C. Chen, W. H. Wang, Y. Pan, Y. Q. Liu, Chem. Eng. J. 435 (2022) 134932, https://doi.org/10.1016/j.cej.2022.134932. doi: 10.1016/j.cej.2022.134932
49. [49]
  P. Peng, A. Anastasopoulou, K. Brooks, H. Furukawa, M. E. Bowden, J. R. Long, T. Autrey, H. Breunig, Nat. Energy. 7 (2022) 448, https://doi.org/10.1038/s41560-022-01013-w. doi: 10.1038/s41560-022-01013-w
50. [50]
  X. S. Lv, K. X. Jiang, H. Wu, L. Ao, L. Hu, X. Y. Li, F. Shen, L. Shi, F. Dong, G. M. Jiang, ACS ES & T. Water. 2 (2022) 1451, https://doi.org/10.1021/acsestwater.2c00205. doi: 10.1021/acsestwater.2c00205
51. [51]
  X. Y. Shu, Q. Yang, F. B. Yao, Y. Zhong, W. C. Ren, F. Chen, J. Sun, Y. H. Ma, Z. Y. Fu, D. B. Wang, X. M. Li, Chem. Eng. J. 358 (2019) 903, https://doi.org/10.1016/j.cej.2018.10.095. doi: 10.1016/j.cej.2018.10.095
52. [52]
  L. -Y. Liu, M. -H. Cui, S. -M. Niu, X. -D. Zhang, X. -H. Li, W. -L. Wang, H. Liu, G. -S. Liu, A. -J. Wang, ACS EST. Engg. 4 (2024) 1275, https://doi.org/10.1021/acsestengg.3c00493. doi: 10.1021/acsestengg.3c00493
53. [53]
  J. J. Li, Y. Wang, B. Zhao, J. Ding, J. Zhang, M. H. Yin, Z. H. Zhang, S. M. Ma, Y. Q. Liu, Z. L. Tan, H. W. Zhang, L. Wang, D. D. Dionysiou, Appl. Catal. B-Environ. 332 (2023) 122754, https://doi.org/10.1016/j.apcatb.2023.122754. doi: 10.1016/j.apcatb.2023.122754
54. [54]
  J. T. Tang, K. N. Liu, X. Y. Li, M. Y. Fu, W. T. Yu, L. X. Jiang, J. X. Ye, S. J. Song, Environ. Chem. Eng. 11 (2023) 109843, https://doi.org/10.1016/j.jece.2023.109843. doi: 10.1016/j.jece.2023.109843
55. [55]
  Z. K. Wang, Y. Y. Wang, N. Zhang, L. X. Ma, J. Sun, C. Yu, S. J. Liu, R. B. Jiang, J. Mater. Chem. A 10 (2022) 10342, https://doi.org/10.1039/D2TA01931K. doi: 10.1039/D2TA01931K
56. [56]
  F. F. Qin, X. D. Tian, Z. Y. Guo, W. Z. Shen, ACS Sustainable Chem. Eng. 6 (2018) 15708, https://doi.org/10.1021/acssuschemeng.8b04227. doi: 10.1021/acssuschemeng.8b04227
57. [57]
  C. X. Fan, Y. D. Tian, S. Y. Bai, C. Y. Zhang, X. L. Wu, J. Energy Storage 44 (2021) 103492, https://doi.org/10.1016/j.est.2021.103492. doi: 10.1016/j.est.2021.103492
58. [58]
  Y. Q. Wang, M. C. Zhang, W. Xu, X. Y. Shen, F. Gao, J. L. Zhu, X. Wan, X. J. Lian, J. G. Xu, Y. Tong, Acta Phys. -Chim. Sin. 38 (2022) 1907076, https://doi.org/10.3866/PKU.WHXB202211025. doi: 10.3866/PKU.WHXB202211025
59. [59]
  Y. Liu, L. Liu, J. Shan, J. D. Zhang, J. Hazard. Mater. 290 (2015) 1, https://doi.org/10.1016/j.jhazmat.2015.02.016. doi: 10.1016/j.jhazmat.2015.02.016
60. [60]
  J. J. Li, H. Wang, L. Wang, C. Ma, C. Luan, B. Zhao, Z. R. Zhang, H. W. Zhang, X. W. Cheng, J. L. Liu, Catalysts 8 (2018) 378, https://doi.org/10.3390/catal8090378. doi: 10.3390/catal8090378
61. [61]
  K. Yang, Q. Sun, F. Xue, D. H. Lin, J. Hazard. Mater. 195 (2011) 124, https://doi.org/10.1016/j.jhazmat.2011.08.020. doi: 10.1016/j.jhazmat.2011.08.020
62. [62]
  K. X. Jiang, X. L. Shi, M. Chen, X. S. Lv, H. F. Gong, Y. Shen, P. Wang, F. Dong, M. Liu, X. M. Zhang, G. M. Jiang, J. Hazard. Mater. 411 (2021) 125119, https://doi.org//10.1016/j.jhazmat.2021.125119. doi: 10.1016/j.jhazmat.2021.125119
63. [63]
  G. L. Li, Y. Liu, Y. Shen, Q. L. Fang, F. Liu, Front. Chem. Eng. 3 (2021) 636439, https://doi.org/10.3389/fceng.2021.636439. doi: 10.3389/fceng.2021.636439
64. [64]
  Y. Shen, Y. W. Tong, J. L. Xu, S. B. Wang, J. Wang, T. Zeng, Z. Q. He, W. Q. Yang, S. Song, Appl. Catal. B-Environ. 264 (2020) 118505, https://doi.org/10.1016/j.apcatb.2019.118505. doi: 10.1016/j.apcatb.2019.118505
65. [65]
  C. C. Chen, L. J. Jin, H. L. Dong, J. Jiang, H. Feng, D. Y. Chen, N. J. Li, Q. F. Xu, J. M. Lu, Sep. Purif. Technol. 324 (2023) 124527, https://doi.org/10.1016/j.seppur.2023.124527. doi: 10.1016/j.seppur.2023.124527
66. [66]
  G. P. Lei, D. K. Chen, Q. B. Li, H. T. Liu, Q. Shi, C. Li, Electrochim. Acta 413 (2022) 140143, https://doi.org/10.1016/j.electacta.2022.140143. doi: 10.1016/j.electacta.2022.140143
67. [67]
  K. Y. Li, D. Guo, J. Y. Kang, B. Wei, X. T. Zhang, Y. J. Chen, ACS Sustainable Chem. Eng. 6 (2018) 14641, https://doi.org/10.1021/acssuschemeng.8b03232. doi: 10.1021/acssuschemeng.8b03232
68. [68]
  C. Hu, C. Lv, S. Liu, Y. Shi, J. F. Song, Z. Zhang, J. G. Cai, A. Watanabe, Catalysis 10 (2020) 188, https://doi.org/10.3390/catal10020188. doi: 10.3390/catal10020188
69. [69]
  H. B. Yu, M. Y. Wang, X. H. Wang, Mater. Res. Bull. 172 (2024) 112655, https://doi.org/10.1016/j.materresbull.2023.112655. doi: 10.1016/j.materresbull.2023.112655
70. [70]
  Z. Qiu, Y. Ma, T. Edvinsson, Nano Energy 66 (2019) 104118, https://doi.org/10.1016/j.nanoen.2019.104118. doi: 10.1016/j.nanoen.2019.104118
71. [71]
  Q. X. Liu, Y. T. Shen, S. Song, Z. Q. He, RSC Adv. 66 (2019) 104118, https://doi.org/10.1039/C9RA01843C. doi: 10.1039/C9RA01843C
72. [72]
  J. Zhao, R. Urrego-Ortiz, N. Liao, F. Calle-Vallejo, J. Luo, Nat. Commun. 15 (2024) 6391, https://doi.org/10.1038/s41467-024-50691-5. doi: 10.1038/s41467-024-50691-5
73. [73]
  F. F. Liu, X. Yang, D. Dang, X. L. Tian, ChemElectroChem 6 (2019) 2208, https://doi.org/10.1002/celc.201900252. doi: 10.1002/celc.201900252
74. [74]
  C. X. Guo, Y. Jiao, Y. Zheng, J. Luo, K. Davey, S. -Z. Qiao, Chem 5 (2019) 2429, https://doi.org/10.1016/j.chempr.2019.06.016. doi: 10.1016/j.chempr.2019.06.016
75. [75]
  M. J. Wang, Y. Xu, C. K. Peng, S. Y. Chen, Y. G. Lin, Z. W. Hu, L. Sun, S. Y. Ding, C. W. Pao, Q. Shao, X. Q. Huang, J. Am. Chem. Soc. 143 (2021) 16512, https://doi.org/10.1021/jacs.1c06006. doi: 10.1021/jacs.1c06006
76. [76]
  Z. M. Lou, C. C. Yu, X. F. Wen, Y. H. Xu, J. M. Yu, X. H. Xu, Appl. Catal. B-Environ. 317 (2022) 121730, https://doi.org/10.1016/j.apcatb.2022.121730. doi: 10.1016/j.apcatb.2022.121730
77. [77]
  F. Gao, Y. P. Zhang, P. P. Song, J. Wang, C. Q. Wang, J. Guo, Y. K. Du, J. Power Sources 418 (2019) 186, https://doi.org/10.1016/j.jpowsour.2019.02.031. doi: 10.1016/j.jpowsour.2019.02.031
78. [78]
  Y. P. Zhang, F. Gao, P. P. Song, J. Wang, J. Guo, Y. Shiraishi, Y. K. Du, ACS Sustainable Chem. Eng. 7 (2019) 3176, https://doi.org/10.1021/acssuschemeng.8b05020. doi: 10.1021/acssuschemeng.8b05020
79. [79]
  Z. Y. Xu, X. Tan, C. Chen, X. D. Wang, R. Sui, Z. B. Zhuang, C. Zhang, C. Chen, Natl. Sci. Rev. 11 (2024) nwae315, https://doi.org/10.1093/nsr/nwae315. doi: 10.1093/nsr/nwae315
80. [80]
  G. M. Jiang, X. L. Shi, M. Y. Cui, W. L. Wang, P. Wang, G. Johnson, Y. D. Nie, X. S. Lv, X. M. Zhang, F. Dong, S. Zhang, ACS Appl. Mater. Interfaces 13 (2021) 4072, https://doi.org/10.1021/acsami.0c20994. doi: 10.1021/acsami.0c20994
81. [81]
  Z. M. Fan, H. C. Zhao, K. F. Wang, W. Ran, J. F. Sun, J. F. Liu, R. Liu, Environ. Sci. Technol. 57 (2023) 1499, https://doi.org/10.1021/acs.est.2c07462. doi: 10.1021/acs.est.2c07462
82. [82]
  X. F. Cheng, Q. Cao, Q. Liu, H. Y. Zhang, Q. F. Xu, J. M. Lu, Chin. J. Chem. 42 (2024) 2445, https://doi.org/10.1002/cjoc.202400293. doi: 10.1002/cjoc.202400293
83. [83]
  J. J. Li, K. Z. Kong, Y. T. Chong, J. Ding, L. Wang, Z. C. Ba, J. Zhang, Sep. Purif. Technol. 323 (2023) 124452, https://doi.org/10.1016/j.seppur.2023.124452. doi: 10.1016/j.seppur.2023.124452
84. [84]
  Q. H. Zhao, C. C. Chen, J. H. Fu, Y. P. Zhang, J. Y. Huo, H. B. Zeng, Q. F. Xu, J. M. Lu, Sep. Purif. Technol. 351 (2024) 128040, https://doi.org/10.1016/j.seppur.2024.128040. doi: 10.1016/j.seppur.2024.128040
85. [85]
  W. T. Yu, H. Jiang, J. H. Fang, S. Song, Environ. Sci. Technol. 55 (2021) 10087, https://doi.org/10.1021/acs.est.1c01922. doi: 10.1021/acs.est.1c01922
86. [86]
  T. Li, Z. Y. Kong, M. M. Liu, Y. Y. Sun, L. P. Diao, P. Lu, D. H. Li, D. J. Yang, Appl. Catal. B-Environ. 351 (2024) 123968, https://doi.org/10.1016/j.apcatb.2024.123968. doi: 10.1016/j.apcatb.2024.123968
87. [87]
  Z. M. Lou, Y. Z. Li, J. S. Zhou, K. L. Yang, Y. L. Liu, S. A. Baig, X. H. Xu, J. Hazard. Mater. 362 (2019) 148, https://doi.org/10.1016/j.jhazmat.2018.08.066. doi: 10.1016/j.jhazmat.2018.08.066
88. [88]
  S. Shu, X. Y. Tang, C. C. Huang, Y. N. Liu, J. J. Li, Ind. Eng. Chem. Res. 63 (2024), 7114, https://doi.org/10.1021/acs.iecr.3c04493. doi: 10.1021/acs.iecr.3c04493
89. [89]
  J. Li, C. Feng, C. Chen, Y. Pan, Y. J. Liu, Environ. Sci. 149 (2025) 288, https://doi.org/10.1016/j.jes.2024.01.053. doi: 10.1016/j.jes.2024.01.053
90. [90]
  Y. F. Wu, L. Gan, S. P. Zhang, H. O. Song, C. Lu, W. T. Li, Z. Wang, B. C. Jiang, A. J. Li, J. Hazard. Mater. 356 (2018) 17, https://doi.org/10.1016/j.jhazmat.2018.05.034. doi: 10.1016/j.jhazmat.2018.05.034
91. [91]
  Y. L. Chen, L. Xiong, X. N. Song, W. K. Wang, Y. X. Huang, H. Q. Yu, Chemosphere 125 (2015) 57, https://doi.org/10.1016/j.chemosphere.2015.01.052. doi: 10.1016/j.chemosphere.2015.01.052
92. [92]
  L. Y. Liu, M. H. Cui, J. J. Ambuchi, S. M. Niu, X. H. Li, W. L. Wang, H. Liu, G. S. Liu, A. J. Wang, Environ. Res. 252 (2024) 118859, https://doi.org/10.1016/j.envres.2024.118859. doi: 10.1016/j.envres.2024.118859
93. [93]
  X. Z. Song, Q. Shi, H. Wang, S. L. Liu, C. Tai, Z. Y. Bian, Appl. Catal. B-Environ. 20 (2017) 442, https://doi.org/10.1016/j.apcatb.2016.10.036. doi: 10.1016/j.apcatb.2016.10.036
94. [94]
  N. Li, X. Song, L. Wang, X. Geng, H. Wang, H. Tang, Z. Y. Bian, ACS Appl. Mater. Interfaces 12 (2020) 24019, https://doi.org/10.1021/acsami.0c05159. doi: 10.1021/acsami.0c05159
95. [95]
  J. L. Xie, Y. X. Li, X. Yan, Z. H. Yu, H. Chen, F. Jiang, Appl. Mater. Interfaces 16 (2024) 44817, https://doi.org/10.1021/acsami.4c08043. doi: 10.1021/acsami.4c08043
96. [96]
  P. Rugira, S. Pan, Z. M. Liang, R. Boutaleb, W. Q. Huang, N. B. Ullah, X. Zhao, C. Wang, Sep. Purif. Technol. 361 (2025) 131573, https://doi.org/10.1016/j.seppur.2025.131573. doi: 10.1016/j.seppur.2025.131573
97. [97]
  Y. Pan, C. Zhang, Y. Lin, Z. Liu, M. M. Wang, C. Chen, Sci. China Mater. 63 (2020) 921, https://doi.org/10.1007/s40843-019-1242-1. doi: 10.1007/s40843-019-1242-1
98. [98]
  X. Zhao, D. Luo, Y. Wang, Z. -H. Liu, Nano Res. 12 (2019) 2872, https://doi.org/10.1007/s12274-019-2529-y. doi: 10.1007/s12274-019-2529-y
99. [99]
  J. J. Li, K. Z. Kong, S. M. Ma, J. Ding, L. Wang, J. Crittenden, Appl. Catal. B-Environ. 356 (2024) 124245, https://doi.org/10.1016/j.apcatb.2024.124245. doi: 10.1016/j.apcatb.2024.124245
100. [100]
  J. J. Li, H. Yu, Y. J. Ding, L. J. Wang, Environ. Chem. Eng. 13 (2025) 115548, https://doi.org/10.1016/j.jece.2025.115548. doi: 10.1016/j.jece.2025.115548
101. [101]
  J. Wang, C. Y. Cui, Y. J. Xin, Q. Z. Zheng, X. Zhang, Electrochim. Acta 296 (2019) 874, https://doi.org/10.1016/j.electacta.2018.11.115. doi: 10.1016/j.electacta.2018.11.115
102. [102]
  S. L. Xu, W. Wang, H. T. Li, Y. X. Gao, Y. Min, P. Liu, X. Zheng, D. -F. Liu, J. J. Chen, H. Q. Yu, X. Zhou, Y. Wu, Adv. Mater. 37 (2025) 2500371, https://doi.org/10.1002/adma.202500371. doi: 10.1002/adma.202500371
103. [103]
  B. Yang, G. Yu, J. Huang, Environ. Sci. Technol. 41 (2007) 7503, https://doi.org/10.1021/es071168o. doi: 10.1021/es071168o
104. [104]
  J. Han, R. L. Deming, F. -M. Tao, J. Phys. Chem. A 108 (2004) 7736, https://doi.org/10.1021/jp047923r. doi: 10.1021/jp047923r
105. [105]
  W. Y. He, S. Y. Yang, K. J. Ye, S. Y. Bai, S. Xu, A. Amrane, M. Zhang, H. Wang, H. Q. Wang, Q. Yuan, X. L. Shi, Chem. Eng. J. 487 (2024) 150460, https://doi.org/10.1016/j.cej.2024.150460. doi: 10.1016/j.cej.2024.150460
106. [106]
  Z. J. Liu, E. A. Betterton, R. G. Arnold, Environ. Sci. Technol. 34 (2000) 804, https://doi.org/10.1021/es991049b. doi: 10.1021/es991049b
107. [107]
  C. Durante, V. Perazzolo, A. A. Isse, M. Favaro, G. Granozzi, A. Gennaro, ChemElectroChem 1 (2014) 1370, https://doi.org/10.1002/celc.201402032. doi: 10.1002/celc.201402032
108. [108]
  X. F. Wei, J. M. Wang, J. Miao, R. C. Zhang, W. W. Lu, N. Zhang, X. Q. Zhou, H. Xu, J. Zhang, S. G. Peng, Colloids Surf. A Physicochem. Eng. Asp. 648 (2022) 129320, https://doi.org/10.1016/j.colsurfa.2022.129320. doi: 10.1016/j.colsurfa.2022.129320
109. [109]
  Z. R. Sun, X. F. Wei, Y. B. Han, S. Tong, X. Hu, J. Hazard. Mater. 244-245 (2013) 287, https://doi.org/10.1016/j.jhazmat.2012.11.017. doi: 10.1016/j.jhazmat.2012.11.017
110. [110]
  S. Shu, W. Y. Fu, P. Wang, W. L. Cen, Y. H. Chu, F. S. Wei, X. M. Zhang, F. Dong, G. M. Jiang, Appl. Catal. A Gen. 583 (2019) 117146, https://doi.org/10.1016/j.apcata.2019.117146. doi: 10.1016/j.apcata.2019.117146
111. [111]
  A. L. Tang, L. M. Wang, R. H. Zhou, Comput. Theor. Chem. 960 (2010) 31, https://doi.org/10.1016/j.theochem.2010.08.021. doi: 10.1016/j.theochem.2010.08.021
1. [1]
  Huafeng SHI . Construction of MnCoNi layered double hydroxide@Co-Ni-S amorphous hollow polyhedron composite with excellent electrocatalytic oxygen evolution performance. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1380-1386. doi: 10.11862/CJIC.20240378
2. [2]
  Bizhu Shao , Huijun Dong , Yunnan Gong , Jianhua Mei , Fengshi Cai , Jinbiao Liu , Dichang Zhong , Tongbu Lu . Metal-Organic Framework-Derived Nickel Nanoparticles for Efficient CO₂ Electroreduction in Wide Potential Windows. Acta Physico-Chimica Sinica, 2024, 40(4): 2305026-0. doi: 10.3866/PKU.WHXB202305026
3. [3]
  Ruige ZHANG , Zhe ZHANG , He ZHENG , Zhan SHI . Recent advances of metal-organic frameworks for alkaline electrocatalytic oxygen evolution reaction. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2011-2028. doi: 10.11862/CJIC.20250185
4. [4]
  Haodong JIN , Qingqing LIU , Chaoyang SHI , Danyang WEI , Jie YU , Xuhui XU , Mingli XU . NiCu/ZnO heterostructure photothermal electrocatalyst for efficient hydrogen evolution reaction. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1068-1082. doi: 10.11862/CJIC.20250048
5. [5]
  Sumiya Akter Dristy , Md Ahasan Habib , Shusen Lin , Mehedi Hasan Joni , Rutuja Mandavkar , Young-Uk Chung , Md Najibullah , Jihoon Lee . Exploring Zn doped NiBP microspheres as efficient and stable electrocatalyst for industrial-scale water splitting. Acta Physico-Chimica Sinica, 2025, 41(7): 100079-0. doi: 10.1016/j.actphy.2025.100079
6. [6]
  Jia Wang , Qing Qin , Zhe Wang , Xuhao Zhao , Yunfei Chen , Liqiang Hou , Shangguo Liu , Xien Liu . P-Doped Carbon-Supported Zn_xP_yO_z for Efficient Ammonia Electrosynthesis under Ambient Conditions. Acta Physico-Chimica Sinica, 2024, 40(3): 2304044-0. doi: 10.3866/PKU.WHXB202304044
7. [7]
  .
  CCS Chemistry 综述推荐│绿色氧化新思路：光/电催化助力有机物高效升级
  . CCS Chemistry, 2025, 7(10.31635/ccschem.024.202405369): -.
8. [8]
  Zelong LIANG , Shijia QIN , Pengfei GUO , Hang XU , Bin ZHAO . Synthesis and electrocatalytic CO₂ reduction performance of metal-organic framework catalysts loaded with silver particles. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 165-173. doi: 10.11862/CJIC.20240409
9. [9]
  Yixuan Wang , Canhui Zhang , Xingkun Wang , Jiarui Duan , Kecheng Tong , Shuixing Dai , Lei Chu , Minghua Huang . Engineering Carbon-Chainmail-Shell Coated Co₉Se₈ Nanoparticles as Efficient and Durable Catalysts in Seawater-Based Zn-Air Batteries. Acta Physico-Chimica Sinica, 2024, 40(6): 2305004-0. doi: 10.3866/PKU.WHXB202305004
10. [10]
  Shuang Cao , Bo Zhong , Chuanbiao Bie , Bei Cheng , Feiyan Xu . Insights into Photocatalytic Mechanism of H₂ Production Integrated with Organic Transformation over WO₃/Zn_0.5Cd_0.5S S-Scheme Heterojunction. Acta Physico-Chimica Sinica, 2024, 40(5): 2307016-0. doi: 10.3866/PKU.WHXB202307016
11. [11]
  Xuejie Wang , Guoqing Cui , Congkai Wang , Yang Yang , Guiyuan Jiang , Chunming Xu . Research Progress on Carbon-based Catalysts for Catalytic Dehydrogenation of Liquid Organic Hydrogen Carriers. Acta Physico-Chimica Sinica, 2025, 41(5): 100044-0. doi: 10.1016/j.actphy.2024.100044
12. [12]
  Xueting Feng , Ziang Shang , Rong Qin , Yunhu Han . Advances in Single-Atom Catalysts for Electrocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2305005-0. doi: 10.3866/PKU.WHXB202305005
13. [13]
  Ye Wang , Ruixiang Ge , Xiang Liu , Jing Li , Haohong Duan . An Anion Leaching Strategy towards Metal Oxyhydroxides Synthesis for Electrocatalytic Oxidation of Glycerol. Acta Physico-Chimica Sinica, 2024, 40(7): 2307019-0. doi: 10.3866/PKU.WHXB202307019
14. [14]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
15. [15]
  Yang WANG , Xiaoqin ZHENG , Yang LIU , Kai ZHANG , Jiahui KOU , Linbing SUN . Mn single-atom catalysts based on confined space: Fabrication and the electrocatalytic oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2175-2185. doi: 10.11862/CJIC.20240165
16. [16]
  Ying Chen , Ronghua Yan , Weiyan Yin . Research Progress on the Synthesis of Metal Single-Atom Catalysts and Their Applications in Electrocatalytic Hydrogen Evolution Reactions. University Chemistry, 2025, 40(9): 344-353. doi: 10.12461/PKU.DXHX202503066
17. [17]
  Jiajie Li , Xiaocong Ma , Jufang Zheng , Qiang Wan , Xiaoshun Zhou , Yahao Wang . Recent Advances in In-Situ Raman Spectroscopy for Investigating Electrocatalytic Organic Reaction Mechanisms. University Chemistry, 2025, 40(4): 261-276. doi: 10.12461/PKU.DXHX202406117
18. [18]
  Mian Wei , Chang Cheng , Bowen He , Bei Cheng , Kezhen Qi , Chuanbiao Bie . Inorganic-organic CdS/YBTPy S-scheme photocatalyst for efficient hydrogen production and its mechanism. Acta Physico-Chimica Sinica, 2025, 41(12): 100158-0. doi: 10.1016/j.actphy.2025.100158
19. [19]
  Yan Kong , Wei Wei , Lekai Xu , Chen Chen . Electrochemical Synthesis of Organonitrogen Compounds from N-integrated CO₂ Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(8): 2307049-0. doi: 10.3866/PKU.WHXB202307049
20. [20]
  Lutian Zhao , Yangge Guo , Liuxuan Luo , Xiaohui Yan , Shuiyun Shen , Junliang Zhang . Electrochemical Synthesis for Metallic Nanocrystal Electrocatalysts: Principle, Application and Challenge. Acta Physico-Chimica Sinica, 2024, 40(7): 2306029-0. doi: 10.3866/PKU.WHXB202306029

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(58)
HTML views(7)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142