Citation: Fanpeng Meng, Fei Zhao, Jingkai Lin, Jinsheng Zhao, Huayang Zhang, Shaobin Wang. 优化氮化碳纳米片/球形共轭聚合物S型异质结界面电场以促进析氢反应[J]. Acta Physico-Chimica Sinica, ;2025, 41(8): 100095. doi: 10.1016/j.actphy.2025.100095 shu

优化氮化碳纳米片/球形共轭聚合物S型异质结界面电场以促进析氢反应

1.
Shandong Key Laboratory of Chemical Energy Storage and Novel Cell Technology, College of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, Shandong Province, China;
2.
College of Chemistry and Chemical Engineering, Taishan University, Taian 271000, Shandong Province, China;
3.
School of Chemical Engineering, The University of Adelaide, Adelaide SA 5005, Australia

Received Date: 18 March 2025
Revised Date: 2 April 2025
Accepted Date: 15 April 2025

Fund Project: This work was funded by the National Natural Science Foundation of China (22302085, 22172069), the Natural Science Foundation of Shandong Province (ZR2024QB046, ZR2021ME071) and the Research Projects of Liaocheng University (318052272). H. Zhang and S. Wang acknowledges the support from Discovery Project (DP230102406, DP240102787), and Australian Laureate Fellowships (FL230100178) from the Australian Research Council.

基于氮化碳设计异质结是提升光催化效率的有效途径。本研究通过简便高效的球磨技术，构建了由氮化碳纳米片(GCNNS)与供体-受体共轭聚合物(聚对氨基亚苄基异苯胺，PASO)组成的全有机S型无金属异质结。该异质结展现出优异的光催化产氢性能，优化后的GCNNS/PASO-10样品的产氢速率达到10.12 mmol·g^-1·h^-1，分别是GCNNS和PASO的5.9倍和19.5倍。这种提升源于独特的界面结合作用、增强的可见光吸收能力以及S型异质结强内建电场促进的高效电荷分离。理论计算与表征结果表明，该异质结的S型机制实现了能带最优匹配并推动了空间电荷的有效分离，从而显著提升了光催化活性。本工作揭示了全有机材料在异质结构建中的独特优势，为设计先进S型体系以实现可持续能源转化提供了新思路。
- All-organic heterojunction,
- Carbon nitride nanosheets,
- S-scheme heterojunction,
- H₂ evolution,
- D-A conjugated polymers
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