Citation: Caiyun Jin, Zexuan Wu, Guopeng Li, Zhan Luo, Nian-Wu Li. 用于金属锂电池的磷腈基阻燃人工界面层[J]. Acta Physico-Chimica Sinica, ;2025, 41(8): 100094. doi: 10.1016/j.actphy.2025.100094 shu

用于金属锂电池的磷腈基阻燃人工界面层

State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China

Received Date: 14 February 2025
Revised Date: 31 March 2025
Accepted Date: 11 April 2025

Fund Project: The project was supported by the National Natural Science Foundation of China (21975015).

金属锂负极(LMA)因具有高的比容量(3860 mAh·g^-1)和最低的氧化还原电位(-3.04 V vs.标准氢电极)，而被认为是下一代高能量密度可充电电池的理想负极材料。然而，金属锂电池存在着锂负极枝晶不可控生长和容易热失控等难题。为此，本论文通过傅克烷基化反应设计合成了一种新型的倍半硅氧烷功能化的六苯氧基环三磷腈基多孔聚合物(SHPP)人工界面层用于保护LMA。SHPP分子链扭曲堆叠可形成大量纳米孔，这些具备独特限域效应的纳米孔能够限制阴离子的通过，提高锂离子迁移数，进而抑制锂枝晶生长。SHPP可以在受热时释放PO·自由基，可用于湮灭酯类电解液受热分解产生的高活性HO·和O·自由基，以减少电池热失控风险。另外，SHPP使得LMA界面中产生Li₃P和LiF成分，有助于提高界面锂离子传导和化学稳定性。因此，SHPP-Li对称电池在酯类电解液中能够稳定循环1600 h，且SHPP-Li||LiNi_0.8Co_0.1Mn_0.1O₂全电池在500次循环后的容量保持率高达76.8%。这种阻燃型人工界面层为安全且无枝晶的锂金属负极提供新的设计思路。
- Hexaphenoxycyclotriphosphazene,
- Flame retardant,
- Lithium dendrite,
- Lithium-ion transport,
- Lithium metal battery
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沈阳化工大学材料科学与工程学院沈阳 110142

用于金属锂电池的磷腈基阻燃人工界面层

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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