Citation: Mingxuan Qi, Lanyu Jin, Honghe Yao, Zipeng Xu, Teng Cheng, Qi Chen, Cheng Zhu, Yang Bai. 钙钛矿太阳能电池在反向偏压下的电学失效及稳定性研究进展[J]. Acta Physico-Chimica Sinica, ;2025, 41(8): 100088. doi: 10.1016/j.actphy.2025.100088 shu

钙钛矿太阳能电池在反向偏压下的电学失效及稳定性研究进展

Experimental Centre for Advanced Materials, School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China

Received Date: 7 February 2025
Revised Date: 21 March 2025
Accepted Date: 3 April 2025

Fund Project: The project was supported by the National Natural Science Foundation of China (52473272).

卤化物钙钛矿凭借其优异的光电特性和独特的缺陷容忍特性，在光伏领域展现出巨大的应用潜力，其单结太阳能电池的认证效率已突破26.95%。然而，钙钛矿材料中的离子键键能较弱，使其在电场作用下易发生离子迁移，导致器件在反向电偏压加载下呈现显著的电学不稳定性，严重阻碍了其商业化进程。特别是在大面积组件应用中，局部遮光效应会使被遮挡的子电池成为电阻，在相邻子电池驱动下被迫承受反向偏压，进而引发材料的结构降解和器件性能的急剧衰减。本文系统综述了钙钛矿太阳能电池在反向偏压下的失效机制，全面梳理了反向偏压稳定性的最新研究进展，重点剖析了反向击穿电压阈值与其电学演化规律，深入探讨了器件老化行为的诱因及稳定性提升策略，并评述了相关原位表征技术的应用进展。最后，本文进一步提出了通过机器学习辅助逆向设计材料体系、构建动态载流子输运模型等创新性解决方案，为攻克反向偏压稳定性这一关键科学难题提供了新的研究思路。
- Halide perovskite,
- Reverse bias,
- Shadowing,
- Hot spot effect,
- Degradation mechanism,
- Stability
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