Citation: Liangliang Song, Haoyan Liang, Shunqing Li, Bao Qiu, Zhaoping Liu. 超高比能电池高锰富锂层状氧化物正极材料面临的挑战与解决策略[J]. Acta Physico-Chimica Sinica, ;2025, 41(8): 100085. doi: 10.1016/j.actphy.2025.100085 shu

超高比能电池高锰富锂层状氧化物正极材料面临的挑战与解决策略

Liangliang Song ^1,2 ,
Haoyan Liang ¹ ,
Shunqing Li ^1,2 ,
Bao Qiu ^1,2 ,
Zhaoping Liu ^1,2

1.
Ningbo Institute of Materials Technology & Engineering (NIMTE), Chinese Academy of Sciences, Ningbo 315201, Zhejiang Province, China;
2.
School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, China

Received Date: 17 February 2025
Revised Date: 17 March 2025
Accepted Date: 27 March 2025

Fund Project: The project was supported by the External Cooperation Program of Chinese Academy of Sciences (181GJHZ2024126MI), the Low Cost Cathode Material (TC220H06P), the Zhongke Hangzhou Bay Institute (Ningbo) New Materials Co. Ltd. (NIMTE-61-2024-2), the Natural Science Foundation of Ningbo (2024QL041) and the Youth Innovation Promotion Association of Chinese Academy of Sciences (2022299).

得益于过渡金属和晶格氧共同参与氧化还原反应，富锂层状氧化物(LLOs)具有大于250 mAh·g^-1的比容量，因而成为下一代商用锂离子电池的潜在候选正极材料。为进一步提高理论比容量并减少对环境和健康有害的钴、镍元素依赖，开发高锰富锂层状氧化物(HM-LLOs)成为一种可行的策略。通过引入更多的Li–O–Li构型，可以促进更多晶格氧参与氧化还原反应，从而提升理论比容量。然而，锰含量的增加也带来了如活化困难和不可逆氧释放等挑战，显著限制了HM-LLOs理论比容量的实际利用。基于此，本文首先探讨了HM-LLOs高理论比容量的来源，随后深入分析了高锰特性引发的结构变化及其对实际比容量利用的限制，最后系统总结了从合成到活性材料改性的多种优化策略，并展望了可能提升HM-LLOs实际比容量的未来方向。
- Lithium-ion battery,
- Cathode materials,
- Li-rich layered oxide,
- Synthesis optimization,
- Modification strategy
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