Citation: Xueqi Yang, Juntao Zhao, Jiawei Ye, Desen Zhou, Tingmin Di, Jun Zhang. 调节NNU-55(Fe)的d带中心以增强CO₂吸附和光催化活性[J]. Acta Physico-Chimica Sinica, ;2025, 41(7): 100074. doi: 10.1016/j.actphy.2025.100074 shu

调节NNU-55(Fe)的d带中心以增强CO₂吸附和光催化活性

Xueqi Yang ¹ ,
Juntao Zhao ¹ ,
Jiawei Ye ^1,, ,
Desen Zhou ¹ ,
Tingmin Di ^2,, ,
Jun Zhang ^1,,

1.
Key Laboratory of Green Chemical Process of Ministry of Education, Hubei Key Laboratory of Novel Reactor and Green Chemical Technology, School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology, Wuhan 430205, Hubei Province, China
2.
Hubei Key Laboratory of Plasma Chemistry and Advanced Materials, School of Materials Science and Engineering, Wuhan Institute of Technology, Wuhan 430205, Hubei Province, China

Corresponding author: Jiawei Ye, yejiawei@wit.edu.cn Tingmin Di, ditingmin19@wit.edu.cn Jun Zhang, junzhang@wit.edu.cn
Received Date: 26 January 2025
Revised Date: 26 February 2025
Accepted Date: 26 February 2025

Fund Project: the National Natural Science Foundation of China (NSFC) 22308341the National Natural Science Foundation of China (NSFC) 22005228the Scientific Research Foundation of Wuhan Institute of Technology K2024047

光催化二氧化碳(CO₂)还原已成为一种有效的技术用于将CO₂转化为高价值的化学品。金属有机框架(MOFs)材料因其结构可调、比表面积大、催化性能好和光响应性优异等特点而展现出巨大的潜力。本文采用MOF材料NNU-55(Fe)将CO₂光催化转化为一氧化碳(CO)。通过改变无机阴离子配体调节金属活性中心(Fe-N4)的电子性质，可以轻松调控NNU-55(Fe) MOFs的光催化性能。研究表明，相较于SO₄²⁻和Cl⁻配位的催化剂，NO₃⁻配位的NNU-55(Fe)展现出更优异的催化性能，在3 h内实现了124 μmol∙g⁻¹的CO产量。NO₃⁻更强的电子供给能力提升了Fe中心的电子密度，降低了Fe的d带中心，并增强了吸附系统成键轨道的占据，从而提高了CO₂的吸附能力和还原活性。本研究通过改变金属位点的无机配体来调节MOFs电子结构和催化活性的策略，为开发高效光催化材料提供了新的思路。
- MOFs,
- Coordination structure,
- d-band center,
- CO₂ adsorption,
- Photoreduction
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调节NNU-55(Fe)的d带中心以增强CO2吸附和光催化活性

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通讯作者: 陈斌, bchen63@163.com

调节NNU-55(Fe)的d带中心以增强CO₂吸附和光催化活性