Citation: Peng Li, Yuanying Cui, Zhongliao Wang, Graham Dawson, Chunfeng Shao, Kai Dai. Efficient interfacial charge transfer of CeO₂/Bi₁₉Br₃S₂₇ S-scheme heterojunction for boosted photocatalytic CO₂ reduction[J]. Acta Physico-Chimica Sinica, ;2025, 41(6): 100065. doi: 10.1016/j.actphy.2025.100065 shu

Efficient interfacial charge transfer of CeO₂/Bi₁₉Br₃S₂₇ S-scheme heterojunction for boosted photocatalytic CO₂ reduction

Peng Li ¹ ,
Yuanying Cui ^{1, 2} ,
Zhongliao Wang ¹ ,
Graham Dawson ³ ,
Chunfeng Shao ^1,, ,
Kai Dai ^1,,

1.
Anhui Province Key Laboratory of Pollutant Sensitive Materials and Environmental Remediation, School of Physics and Electronic Information, Huaibei Normal University, Huaibei 235000, Anhui Province, China
2.
Guangxi Key Laboratory of Information Materials, Guilin University of Electronic Technology, Guilin 541004, Guangxi Zhuang Autonomous Region, China
3.
Department of Chemistry, Xi'an Jiaotong Liverpool University, Suzhou 215123, Jiangsu Province, China

Corresponding author: Chunfeng Shao, shaocf@chnu.edu.cn Kai Dai, daikai940@chnu.edu.cn
Received Date: 14 January 2025
Revised Date: 13 February 2025
Accepted Date: 13 February 2025

Fund Project: the National Natural Science Foundation of China 22278169the Excellent Scientific Research and Innovation Team of Education Department of Anhui Province 2022AH010028Anhui Provincial Quality Engineering Project 2022sx134

Improving the separation efficiency of photogenerated charge carriers to significantly enhance the redox capability of photocatalysts remains a major challenge in the field of photocatalysis. To address this issue, this study successfully synthesized a CeO₂/Bi₁₉Br₃S₂₇ S-scheme heterojunction catalyst using a hydrothermal method, aiming to enhance the photocatalytic performance of the catalyst. The synthesis of the CeO₂/Bi₁₉Br₃S₂₇ composite not only improved the separation efficiency of photogenerated charge carriers but also endowed the catalyst with stronger redox capabilities and greater driving force, significantly boosting its photocatalytic performance. Experimental results showed that the CO production rate of the CeO₂/Bi₁₉Br₃S₂₇ composite catalyst reached 13.5 μmol g⁻¹ h⁻¹, which is 5.19 times higher than that of the pure Bi₁₉Br₃S₂₇ catalyst and 2.81 times higher than that of the pure CeO₂ catalyst. This significant enhancement indicates that the CeO₂/Bi₁₉Br₃S₂₇ composite catalyst exhibited stronger catalytic performance in CO generation reactions. Furthermore, CeO₂/Bi₁₉Br₃S₂₇ catalyst achieved a CH₄ production rate of 4.3 μmol g⁻¹ h⁻¹, which is 3.1 times higher than that of the CeO₂ catalyst and 2.7 times higher than that of the Bi₁₉Br₃S₂₇ catalyst, further confirming its superior performance in CH₄ generation reactions. These results demonstrate that the CeO₂/Bi₁₉Br₃S₂₇ composite catalyst not only shows significant improvements in CO and CH₄ production rates but also exhibits excellent photocatalytic performance, highlighting its potential application in the field of photocatalysis. This study provides new insights into improving the separation efficiency of photogenerated charges and offers valuable references for the future development of highly efficient photocatalytic materials. By constructing the S-scheme heterojunction structure, the recombination of photogenerated charge carriers can be effectively suppressed, thereby enhancing the efficiency of photocatalytic reactions and providing a new solution for sustainable energy utilization.
- Photocatalytic carbon dioxide reduction,
- S-scheme heterojunction,
- CeO₂,
- Bi₁₉Br₃S₂₇,
- Built-in electric field
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Efficient interfacial charge transfer of CeO2/Bi19Br3S27 S-scheme heterojunction for boosted photocatalytic CO2 reduction

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通讯作者: 陈斌, bchen63@163.com

Efficient interfacial charge transfer of CeO₂/Bi₁₉Br₃S₂₇ S-scheme heterojunction for boosted photocatalytic CO₂ reduction