Citation: Bin Yang, Wei Deng, Limin Guo, Tatsumi Ishihara. Copper-ceria solid solution with improved catalytic activity for hydrogenation of CO₂ to CH₃OH[J]. Chinese Journal of Catalysis, ;2020, 41(9): 1348-1359. doi: 10.1016/S1872-2067(20)63605-1 shu

Copper-ceria solid solution with improved catalytic activity for hydrogenation of CO₂ to CH₃OH

a School of Environmental Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, Hubei, China;
b International Institute for Carbon-Neutral Energy Research, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 8190395, Japan;
c Department of Applied Chemistry, Faculty of Engineering, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 8190395, Japan

Received Date: 15 January 2020
Revised Date: 26 February 2020

Fund Project: The work was financially supported by National Natural Science Foundation of China (21878116), Natural Science Foundation of Hubei Province (2019CFA070), National Key R&D program of China (2017YFE0127400) and Program for Huazhong University of Science and Technology (HUST) Academic Frontier Youth Team (2018QYTD03).

A copper-ceria solid solution and ceria-supported copper catalysts were prepared and used for the catalytic hydrogenation of CO₂ to CH₃OH. According to site-specific classification and quantitative analyses (X-ray diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy, H₂ temperature-programmed reduction, and CO adsorption), the interfaces of the prepared catalysts were classified as Cu incorporated into ceria (Cu-O_v-Ce_x), dispersed CuO (D-CuO-CeO₂), and bulk CuO (B-CuO-CeO₂) over the CeO₂ surface. These results, together with those of activity tests, showed that the Cu-O_v-Ce_x species was closely related to the CO₂ hydrogenation activity and resulted in a much higher turnover frequency of CH₃OH production than that observed with the D-CuO-CeO₂ and B-CuO-CeO₂ species. Thus, the copper-ceria solid solution exhibited improved activity due to the higher Cu-O_v-Ce_x fraction.
- Copper-ceria,
- Solid solution,
- CO₂ hydrogenation,
- Methanol,
- Active site
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
26. [26]
27. [27]
28. [28]
29. [29]
30. [30]
31. [31]
32. [32]
1. [1]
  Jianan Hong , Chenyu Xu , Yan Liu , Changqi Li , Menglin Wang , Yanwei Zhang . Decoding the interfacial competition between hydrogen evolution and CO₂ reduction via edge-active-site modulation in photothermal catalysis. Acta Physico-Chimica Sinica, 2025, 41(9): 100099-0. doi: 10.1016/j.actphy.2025.100099
2. [2]
  Feifei Yang , Wei Zhou , Chaoran Yang , Tianyu Zhang , Yanqiang Huang . Enhanced Methanol Selectivity in CO₂ Hydrogenation by Decoration of K on MoS₂ Catalyst. Acta Physico-Chimica Sinica, 2024, 40(7): 2308017-0. doi: 10.3866/PKU.WHXB202308017
3. [3]
  Xue Liu , Lipeng Wang , Luling Li , Kai Wang , Wenju Liu , Biao Hu , Daofan Cao , Fenghao Jiang , Junguo Li , Ke Liu . Research on Cu-Based and Pt-Based Catalysts for Hydrogen Production through Methanol Steam Reforming. Acta Physico-Chimica Sinica, 2025, 41(5): 100049-0. doi: 10.1016/j.actphy.2025.100049
4. [4]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-0. doi: 10.3866/PKU.WHXB202407005
5. [5]
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6. [6]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-Based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-0. doi: 10.3866/PKU.WHXB202406029
7. [7]
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8. [8]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
9. [9]
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10. [10]
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11. [11]
  Yanhui Guo , Li Wei , Zhonglin Wen , Chaorong Qi , Huanfeng Jiang . Recent Progress on Conversion of Carbon Dioxide into Carbamates. Acta Physico-Chimica Sinica, 2024, 40(4): 2307004-0. doi: 10.3866/PKU.WHXB202307004
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13. [13]
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14. [14]
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15. [15]
  Jie ZHAO , Huili ZHANG , Xiaoqing LU , Zhaojie WANG . Theoretical calculations of CO₂ capture and separation by functional groups modified 2D covalent organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 275-283. doi: 10.11862/CJIC.20240213
16. [16]
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17. [17]
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18. [18]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
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Copper-ceria solid solution with improved catalytic activity for hydrogenation of CO2 to CH3OH

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通讯作者: 陈斌, bchen63@163.com

Copper-ceria solid solution with improved catalytic activity for hydrogenation of CO₂ to CH₃OH