Citation: Xiaofang Li, Xiaofeng Wu, Shengwei Liu, Yuhan Li, Jiajie Fan, Kangle Lv. Effects of fluorine on photocatalysis[J]. Chinese Journal of Catalysis, ;2020, 41(10): 1451-1467. doi: 10.1016/S1872-2067(20)63594-X shu

Effects of fluorine on photocatalysis

Xiaofang Li ^b, ,
Xiaofeng Wu ^a,f ,
Shengwei Liu ^c ,
Yuhan Li ^d ,
Jiajie Fan ^e ,
Kangle Lv ^a

a Key Laboratory of Catalysis and Energy Materials Chemistry of Ministry of Enducation, College of Resources and Environmental Science, South-Central University for Nationalities, Wuhan 430074, Hubei, China;
b College of Chemistry and Chemical Engineering, Wuhan University of Science and Technology, Wuhan 430081, Hubei, China;
c School of Environmental Science and Engineering, Guangdong Provincial Key Laboratory of Environmental Pollution Control and Remediation Technology, Sun Yat-sen University, Guangzhou 510006, Guangdong, China;
d Engineering Research Center for Waste Oil Recovery Technology and Equipment, Ministry of Education, Chongqing Key Laboratory of Catalysis and New Environmental Materials, Chongqing Technology and Business University, Chongqing 400067, China;
e School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, Henan, China;
f Laboratory of Inorganic Materials and Catalysis, Department of Chemical Engineering and Chemistry, Eindhoven University of Technology, P. O. Box 513, 5600 MB Eindhoven, The Netherlands

Received Date: 17 February 2020
Revised Date: 25 March 2020

Fund Project: This work was supported by the National Natural Science Foundation of China (51672312, 51808080, 21373275, 51872341, 51572209), the Fundamental Research Funds for the Central Universities, South-Central University for Nationalities (CZT20016), China "Post-Doctoral Innovative Talent Support Program" (BX20180056), the Natural Science Foundation Project of CQ CSTC (cstc2018jcyjA3794), China Postdoctoral Science Foundation (2018M643788XB), Science and Technology Research Project of Chongqing Education Commission Foundation (KJQN201800826, KJZDK201800801), Venture & Innovation Support Program for Chongqing Overseas Returnees (cx2018130), and Chongqing Technology and Business University Research Foundation Project (1856039).

Tailoring the microstructure of pristine TiO₂ is essential to narrow its band gap and prolong the charge lifetime. In particular, strategies involving fluorine have been used successfully to tune the surface chemistry, electronic structure, and morphology of TiO₂ photocatalysts to improve their photocatalytic activity based on the strong complexation between fluoride ions and TiO₂ and the high electronegativity of fluorine. In this review, we summarize the strategies involving fluorine to establish highly efficient TiO₂ photocatalytic systems or fabricate highly efficient TiO₂ photocatalysts. The main fluorine effects (i.e. the effects of fluorine on photocatalysis) include the following four aspects:(1) Surface effects of fluoride on TiO₂ photocatalysis, (2) effects of fluorine doping on TiO₂ photocatalysis, (3) fluoride-mediated tailoring of the morphology of TiO₂ photocatalysts, and (4) the effects of fluorine on non-TiO₂ photocatalysis. Additionally, the unique applications of these fluorine effects in photocatalysis, including selective degradation of pollutants, selective oxidation of chemicals, water-splitting to produce H₂, reduction of CO₂ to produce solar fuels, and improvement of the thermostability of TiO₂ photocatalysts, are reviewed.
- TiO₂,
- Fluorine,
- Photocatalysis,
- Doping,
- Surface modification
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