Citation: Jia Wang, Man Yang, Aiqin Wang. Selective hydrogenolysis of glycerol to 1,3-propanediol over Pt-W based catalysts[J]. Chinese Journal of Catalysis, ;2020, 41(9): 1311-1319. doi: 10.1016/S1872-2067(20)63586-0 shu

Selective hydrogenolysis of glycerol to 1,3-propanediol over Pt-W based catalysts

Jia Wang ^a, ,
Man Yang ^b,d ,
Aiqin Wang ^b,c

a College of Forestry, Northwest A&F University, Yangling 712100, Shaanxi, China;
b CAS Key Laboratory of Science and Technology on Applied Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
c State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
d University of Chinese Academy of Sciences, Beijing 100049, China

Received Date: 21 February 2020
Revised Date: 16 March 2020

Fund Project: This work was supported by the National Natural Science Foundation of China (21706215, 21690084, 21673228), Natural Science Basic Project of Shaanxi Province (2018JQ2034), and the Fundamental Research Funds for the Central Universities (Z109021701).

The selective hydrogenolysis of glycerol to 1,3-propanediol (1,3-PDO) is an attractive reaction due to the high demand for valorization of huge excess amounts of glycerol supply as well as the important application of 1,3-PDO in polyester industry. Nevertheless, the formation of 1,3-PDO is thermodynamically less favorable than 1,2-PDO, which necessitates the development of efficient catalysts to manipulate the reaction kinetics towards the 1,3-PDO formation. Among others, Pt-W based catalysts have shown promising activities and selectivities of 1,3-PDO although the reaction mechanism is not well addressed at the molecular level. In this short review, we have compared the performances of different Pt-W based catalysts and discussed the key factors influencing the activity and selectivity. Three possible reaction mechanisms have been discussed in terms of the synergy between Pt and WO_x and the origin of acid sites. Finally, the long-term stability of the Pt-W catalysts has been discussed. We hope this review will provide useful information for the development of more efficient catalysts for this important reaction.
- Glycerol,
- Hydrogenolysis,
- 1,3-propanediol,
- Pt-W based catalysts
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