Citation: Jiangyong Liu, Jinxing Li, Rongfei Ye, Xiaodong Yan, Lixia Wang, Panming Jian. Versatile bifunctional nitrogen-doped porous carbon derived from biomass in catalytic reduction of 4-nitrophenol and oxidation of styrene[J]. Chinese Journal of Catalysis, ;2020, 41(8): 1217-1229. doi: 10.1016/S1872-2067(20)63534-3 shu

Versatile bifunctional nitrogen-doped porous carbon derived from biomass in catalytic reduction of 4-nitrophenol and oxidation of styrene

a School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, Jiangsu, China;
b School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, Jiangsu, China

Received Date: 20 November 2019
Revised Date: 28 December 2019

Fund Project: This work was supported by the Natural Science Foundation of the Jiangsu Higher Education Institutions of China (17KJB530011), the Jiangsu Planned Projects for Postdoctoral Research Funds (2019K093), and the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).

The scarcity and weak durability of metal, especially precious metal catalysts are big obstacles for their large-scale application in many reactions. The state-of-the-art of the catalytic science prefers such type of catalysts, which can replace metal-based catalysts to alleviate energy and environmental crises and exhibit catalytic performance comparable to or even exceeding these metal catalysts. Herein, we report that N-doped porous carbon (NKC) derived from cheap and abundant radish can be employed as versatile and efficient bifunctional catalysts in both the catalytic reduction of 4-nitrophenol (NRR) and oxidation of styrene (SOR). The series of NKC catalysts were prepared with a simple and facile one-pot strategy by coupling the N-doping, carbonization and KOH activation processes. These catalysts show hierarchical porosity, with the specific surface area, total pore volume and N-doping content ranging from 918.9-3062.7 m² g^-1, 1.01-2.04 cm³ g^-1 and 1.29-15.3 at%, respectively. Interestingly, our finding suggests that the catalytic performance is not directly related to these parameters but correlates positively with the content of graphitic N dopants, which is the dominant contributor for impelling both the NRR and SOR. Another intriguing finding is that for both reactions, the optimal catalyst was found to be the NKC-3-800 which possesses the highest graphitic N content of 3.13 at%. In addition, to gain insight into the catalytic behavior, analyses of kinetics and thermodynamics were performed, and the catalytic mechanisms were postulated. This work paves the way for the construction of biomass-derived N-doped carbon catalysts for bi-or even multi-functional applications in various organic reactions.
- Nitrogen-doping,
- Carbon,
- Biomass,
- 4-Nitrophenol,
- Styrene
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