Citation: Chengcheng Yan, Long Lin, Guoxiong Wang, Xinhe Bao. Transition metal-nitrogen sites for electrochemical carbon dioxide reduction reaction[J]. Chinese Journal of Catalysis, ;2019, 40(1): 23-37. doi: 10.1016/S1872-2067(18)63161-4 shu

Transition metal-nitrogen sites for electrochemical carbon dioxide reduction reaction

Chengcheng Yan ^a,b, ,
Long Lin ^a,b ,
Guoxiong Wang ^a,c ,
Xinhe Bao ^a,c

a State Key Laboratory of Catalysis, CAS Center for Excellence in Nanoscience, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
b University of Chinese Academy of Sciences, Beijing 100049, China;
c Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China

Received Date: 4 September 2018
Revised Date: 19 September 2018

Fund Project: This work was supported by the National Key R&D Program of China (2017YFA0700102), the National Natural Science Foundation of China (21573222 and 91545202), the Outstanding Youth Talent Project of Dalian (2017RJ03), the DMTO Project of Dalian Institute of Chemical Physics, CAS (DICP DMTO201702), the Strategic Priority Research Program of the Chinese Academy of Sciences (XDB17020200), and the Youth Innovation Promotion Association, CAS (2015145).

Electrochemical CO₂ reduction reaction (CO₂RR) powered by renewable electricity has emerged as the most promising technique for CO₂ conversion, making it possible to realize a carbon-neutral cycle. Highly efficient, robust, and cost-effective catalysts are highly demanded for the near-future practical applications of CO₂RR. Previous studies on atomically dispersed metal-nitrogen (M-N_x) sites constituted of earth abundant elements with maximum atom-utilization efficiency have demonstrated their performance towards CO₂RR. This review summarizes recent advances on a variety of M-N_x sites-containing transition metal-centered macrocyclic complexes, metal organic frameworks, and M-N_x-doped carbon materials for efficient CO₂RR, including both experimental and theoretical studies. The roles of metal centers, coordinated ligands, and conductive supports on the intrinsic activity and selectivity, together with the importance of reaction conditions for improved performance are discussed. The mechanisms of CO₂RR over these M-N_x-containing materials are presented to provide useful guidance for the rational design of efficient catalysts towards CO₂RR.
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