Citation: Haojie Wang, Chun Chen, Haimin Zhang, Guozhong Wang, Huijun Zhao. An efficient and reusable bimetallic Ni₃Fe NPs@C catalyst for selective hydrogenation of biomass-derived levulinic acid to γ-valerolactone[J]. Chinese Journal of Catalysis, ;2018, 39(10): 1599-1607. doi: 10.1016/S1872-2067(18)63105-5 shu

An efficient and reusable bimetallic Ni₃Fe NPs@C catalyst for selective hydrogenation of biomass-derived levulinic acid to γ-valerolactone

a Key Laboratory of Materials Physics, Centre for Environmental and Energy Nanomaterials, Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, Anhui, China;
b University of Science and Technology of China, Hefei 230026, Anhui, China;
c Centre for Clean Environment and Energy, Griffith University, Queensland 4222, Australia

Received Date: 29 March 2018
Revised Date: 25 May 2018

Fund Project: This work was supported by the National Natural Science Foundation of China (51502297, 51372248, 51432009), and the Instrument Developing Project of the Chinese Academy of Sciences (yz201421).

Bimetallic nanostructures have attracted great interest as efficient catalyst to enhance activity, selectivity and stability in catalytical conversion. Herein, we report a facile one-pot carbothermal route to in-situ controllable synthesize heterogeneous bimetallic Ni₃Fe NPs@C nanocatalyst. The X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy and N₂ adsorption-description results reveal that the Ni₃Fe alloy nanoparticles are evenly embedded in carbon matrix. The as-prepared Ni₃Fe NPs@C catalyst shows excellent selective hydrogenation catalytic performance toward the conversion of levulinic acid (LA) to γ-valerolactone (GVL) via both direct hydrogenation (DH) and transfer hydrogenation (TH). In DH of LA, the bimetallic catalyst achieved a 93.8% LA conversion efficiency with a 95.5% GVL selectivity and 38.2 mmol g^-1 h^-1 GVL productivity (under 130℃, 2MPa H₂within 2 h), which are 6 and 40 times in comparison with monometallic Ni NPs@C and Fe NPs@C catalysts, respectively. In addition, the identical catalyst displayed a full conversion of LA with almost 100% GVL selectivity and 167.1 mmol g^-1 h^-1 GVL productivity at 180℃ within 0.5 h in TH of LA. Under optimal reaction conditions, the DH and TH catalytic performance of 500-Ni₃Fe NPs@C(3:1) catalyst for converting LA to GVL is comparable to the state-of-the-art noble-based catalysts. The demonstrated capability of bimetallic catalyst design approach to introduce dual-catalytic functionality for DH and TH reactions could be adoptable for other catalysis processes.
- Levulinic acid,
- γ-valerolactone,
- Bimetallic catalyst,
- Hydrogenation,
- Dual-catalytic functionality
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通讯作者: 陈斌, bchen63@163.com

An efficient and reusable bimetallic Ni₃Fe NPs@C catalyst for selective hydrogenation of biomass-derived levulinic acid to γ-valerolactone