Citation: Zai-Fang Han, Xu-Liang Xue, Jian-Min Wu, Wan-Zhong Lang, Ya-Jun Guo. Preparation and catalytic properties of mesoporous nV-MCM-41 for propane oxidative dehydrogenation in the presence of CO₂[J]. Chinese Journal of Catalysis, ;2018, 39(6): 1099-1109. doi: 10.1016/S1872-2067(18)63048-7 shu

Preparation and catalytic properties of mesoporous nV-MCM-41 for propane oxidative dehydrogenation in the presence of CO₂

The Education Ministry Key Laboratory of Resource Chemistry and Shanghai Key Laboratory of Rare Earth Functional Materials, Department of Chemistry and Chemical Engineering, Shanghai Normal University, Shanghai 200234, China

Received Date: 31 December 2017
Revised Date: 9 February 2018

Fund Project: This work was supported by the Ministry of Education of China (PCSIRT_IRT_16R49) and the International Joint Laboratory on Resource Chemistry (IJLRC).

The nV-MCM-41 catalysts were prepared by one-step hydrothermal synthesis and applied to the oxidative dehydrogenation of propane (ODHP) in the presence of CO₂. Several state-of-the-art characterization methods were performed to explore the correlation between catalytic performance and the physicochemical characterizations of the catalysts. Because moderate amounts of V species were introduced into the framework of MCM-41, the catalyst maintained a large specific surface area, a highly ordered mesoporous structure, and highly dispersed V active sites (monomeric and dimeric V oxide species), while the high-vanadium-doping catalysts caused an enhancement in the number of acidic sites and V₂O₅ crystallites. The ODHP reaction showed that the 6.8V-MCM-41 (V content 6.8 wt%) catalyst exhibits high activity and stability, and the C₃H₈/CO₂ molar ratio (1:4) was suitable. The promoting effect of CO₂on the oxidative dehydrogenation of ODHP was demonstrated as the reaction coupling mechanism and "lattice oxygen" mechanism.
- Propane dehydrogenation,
- Vanadium oxide,
- MCM-41,
- Mesoporous support,
- Heterogeneous catalysis
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Preparation and catalytic properties of mesoporous nV-MCM-41 for propane oxidative dehydrogenation in the presence of CO2

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Preparation and catalytic properties of mesoporous nV-MCM-41 for propane oxidative dehydrogenation in the presence of CO₂