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Citation: Weifeng Chu, Fucun Chen, Ce Guo, Xiujie Li, Xiangxue Zhu, Yang Gao, Sujuan Xie, Shenglin Liu, Nan Jiang, Longya Xu. Synthesis of FER zeolite with piperidine as structure-directing agent and its catalytic application[J]. Chinese Journal of Catalysis, ;2017, 38(11): 1880-1887. doi: 10.1016/S1872-2067(17)62906-1 shu

Synthesis of FER zeolite with piperidine as structure-directing agent and its catalytic application

Weifeng Chu ^a,b, ,
Fucun Chen ^a ,
Ce Guo ^a,b ,
Xiujie Li ^a ,
Xiangxue Zhu ^a ,
Yang Gao ^a ,
Sujuan Xie ^a ,
Shenglin Liu ^a ,
Nan Jiang ^c ,
Longya Xu ^a

a Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
b University of Chinese Academy of Sciences, Beijing 100049, China;
c Nanjing Rongxin Chemical Co., Ltd., Nanjing 210047, Jiangsu, China

Received Date: 23 July 2017
Revised Date: 24 August 2017

Fund Project: This work was supported by the National Natural Science Foundation of China (21376235) and Natural Science Foundation of Liaoning Province (201602740).

The synthesis of ferrierite (FER) zeolite using piperidine as an organic structure-directing agent was investigated. X-ray diffraction, X-ray fluorescence, N₂-adsorption, and scanning electron microscopy were used to characterize the crystal phases, textural properties, and particle morphologies of the zeolite samples. The crystallization behavior of the FER zeolite was found to be directly related to crystallization temperature. At 150 ℃, pure FER phase was observed throughout crystallization. At 160-170 ℃, MWW phase appeared first and gradually transformed into FER phase over time, indi-cating that the FER phase was thermodynamically favored. In the piperidine-Na₂O-H₂O synthetic system, alkalinity proved to be the crucial factor determining the size and textural properties of FER zeolite. Furthermore, the obtained FER samples exhibited good catalytic performance in the skeletal isomerization of 1-butene.
- FER zeolite,
- Piperidine,
- Crystallization process,
- MWW zeolite,
- Skeletal isomerization
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