Citation: Ming Ge, Zhenlu Li. Recent progress in Ag₃PO₄-based all-solid-state Z-scheme photocatalytic systems[J]. Chinese Journal of Catalysis, ;2017, 38(11): 1794-1803. doi: 10.1016/S1872-2067(17)62905-X shu

Recent progress in Ag₃PO₄-based all-solid-state Z-scheme photocatalytic systems

Ming Ge ^a,b, ,
Zhenlu Li ^a

a College of Chemical Engineering, North China University of Science and Technology, Tangshan 063210, Hebei, China;
b Hebei Key Laboratory of Photocatalytic and Electrocatalytic Materials for Environment, Tangshan 063210, Hebei, China

Received Date: 30 June 2017
Revised Date: 18 August 2017

Fund Project: This work was supported by the Youth Foundation of Hebei Education Department (QN2017115), and the National Natural Science Foundation of China (51504079).

Heterogeneous semiconductor photocatalysis is a promising green technology solution to energy and environmental problems. Traditional photocatalyst TiO₂, with a wide band gap of 3.2 eV, can only be excited by UV light and utilizes less than 4% of solar energy. Silver phosphate (Ag₃PO₄) is among the most active visible-light-driven photocatalysts reported. Unfortunately, unwanted pho-tocorrosion is the main obstacle to the practical application of Ag₃PO₄. Much effort has been made in recent years to address this issue and further enhance the photocatalytic performance of Ag₃PO₄. The construction of Z-scheme photocatalytic systems that mimic natural photosynthesis is a prom-ising strategy to improve the photocatalytic activity and stability of Ag₃PO₄. This brief review con-cisely summarizes and highlights recent research progress in Ag₃PO₄-based all-solid-state Z-scheme photocatalytic systems with or without a solid-state electron mediator, focusing on their construc-tion, application, and reaction mechanism. Furthermore, the challenges and future prospects of Ag₃PO₄-based Z-scheme photocatalytic systems are discussed.
- Silver phosphate,
- Photocatalysis,
- Z-scheme system,
- Application,
- Mechanism
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Recent progress in Ag₃PO₄-based all-solid-state Z-scheme photocatalytic systems