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Citation: Shuang-Hong Hao, Li-Xia Li, Dao-Qing Dong, Zu-Li Wang. Direct construction of sulfenylated pyrazoles catalyzed by I₂ at room temperature[J]. Chinese Journal of Catalysis, ;2017, 38(10): 1664-1667. doi: 10.1016/S1872-2067(17)62901-2 shu

Direct construction of sulfenylated pyrazoles catalyzed by I₂ at room temperature

College of Chemistry and Pharmaceutical Sciences, Qingdao Agricultural University, Qingdao 266109, Shangdong, China

Received Date: 6 July 2017
Revised Date: 14 August 2017

Fund Project: This work was supported by the National Natural Science Foundation of China (21402103, 21772107, 31471808), the China Postdoctoral Science Foundation (150030), and the Research Fund of Qingdao Agricultural University's Highlevel Person (631303).

An iodine-catalyzed sulfenylation of pyrazoles at room temperature is described, in which a variety of pyrazoles were well tolerated and the desired products were obtained in good to excellent yields.
- C-S bond,
- Iodine,
- Room temperature,
- Disulfides,
- Sulfenylation
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
26. [26]
27. [27]
28. [28]
29. [29]
30. [30]
31. [31]
32. [32]
33. [33]
34. [34]
35. [35]
36. [36]
37. [37]
38. [38]
39. [39]
40. [40]
41. [41]
42. [42]
43. [43]
44. [44]
45. [45]
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Direct construction of sulfenylated pyrazoles catalyzed by I2 at room temperature

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Direct construction of sulfenylated pyrazoles catalyzed by I₂ at room temperature