Citation: Jie Li, Yuanhang Ren, Bin Yue, Heyong He. Ni/Al₂O₃ catalysts derived from spinel NiAl₂O₄ for low-temperature hydrogenation of maleic anhydride to succinic anhydride[J]. Chinese Journal of Catalysis, ;2017, 38(7): 1166-1173. doi: 10.1016/S1872-2067(17)62844-4 shu

Ni/Al₂O₃ catalysts derived from spinel NiAl₂O₄ for low-temperature hydrogenation of maleic anhydride to succinic anhydride

Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Collaborative Innovation Center of Chemistry for Energy Materials, Fudan University, Shanghai 200433, China

Received Date: 22 February 2017
Revised Date: 19 April 2017

Fund Project: This work was supported by the National Natural Science Foundation of China (21173050, 21371035) and SINOPEC (X514005).

Ni/Al₂O₃ catalysts were derived from spinel NiAl₂O₄ with different Ni content ((2.5, 5 and 7.5) wt%). The catalysts were obtained by H₂ reduction and were investigated for the low-temperature hydro-genation of maleic anhydride (MA) to produce succinic anhydride (SA). The characterization results showed that Ni⁰ active sites were mainly derived during the H₂ reduction from spinel NiAl₂O₄. Among the catalysts studied, employing the optimum preparation and reaction conditions with Ni(5%)/Al₂O₃ yielded the highest catalytic performance. A near-100% conversion of MA and~90% selectivity to SA were achieved at 120℃ and 0.5 MPa of H₂ with a weighted hourly space velocity (MA) of 2 h^-1.
- Maleic anhydride,
- Succinic anhydride,
- Hydrogenation,
- Nickel,
- Spinel
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
26. [26]
27. [27]
28. [28]
29. [29]
30. [30]
31. [31]
32. [32]
33. [33]
34. [34]
35. [35]
36. [36]
37. [37]
38. [38]
39. [39]
40. [40]
41. [41]
1. [1]
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通讯作者: 陈斌, bchen63@163.com

Ni/Al₂O₃ catalysts derived from spinel NiAl₂O₄ for low-temperature hydrogenation of maleic anhydride to succinic anhydride