Citation: Bo Yuan, Bao Zhang, Zhiliang Wang, Shengmei Lu, Jun Li, Yan Liu, Can Li. Photocatalytic aerobic oxidation of toluene and its derivatives to aldehydes on Pd/Bi₂WO₆[J]. Chinese Journal of Catalysis, ;2017, 38(3): 440-446. doi: 10.1016/S1872-2067(17)62757-8 shu

Photocatalytic aerobic oxidation of toluene and its derivatives to aldehydes on Pd/Bi₂WO₆

Bo Yuan ^a,b, ,
Bao Zhang ^a,b ,
Zhiliang Wang ^a,b ,
Shengmei Lu ^a ,
Jun Li ^a ,
Yan Liu ^a ,
Can Li ^a

a State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
b University of Chinese Academy of Sciences, Beijing 100049, China

Received Date: 27 October 2016
Revised Date: 20 November 2016

Fund Project: This work was supported by the National Natural Science Foundation of China (21322202, 21472187) and the National Basic Research Program of China (2010CB833300).

The selective oxidation of toluene and its derivatives is extremely important in the chemical industry.The use of photocatalysis in organic synthesis has attracted considerable attention among synthetic chemists because of its “green” environmental characteristics. In this study, nanoscale Bi₂WO₆ with a flower-like morphology was found to be a highly efficient photocatalyst in the catalytic oxidation of toluene and its derivatives using O₂ as the oxidant. The loading of Pd nanoparticles as a cocatalyst onto the flower-like Bi₂WO₆ was found to produce a significant enhancement in the catalytic activity. Mechanistic investigation showed that the superior performance of Pd/Bi₂WO₆ could be attributed to the improvement of both the reductive and oxidative abilities of Bi₂WO₆by the loading of the cocatalyst.
- Flower-like Bi₂WO₆,
- Toluene oxidation,
- Benzaldehyde,
- Cocatalyst,
- Palladium nanoparticle
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Photocatalytic aerobic oxidation of toluene and its derivatives to aldehydes on Pd/Bi₂WO₆