Citation: Wenting Luo, Yuan Lyu, Leifeng Gong, Hong Du, Miao Jiang, Yunjie Ding. Alcohol-treated SiO₂ as the support of Ir-Re/SiO₂ catalysts for glycerol hydrogenolysis[J]. Chinese Journal of Catalysis, ;2016, 37(11): 2009-2017. doi: 10.1016/S1872-2067(16)62517-2 shu

Alcohol-treated SiO₂ as the support of Ir-Re/SiO₂ catalysts for glycerol hydrogenolysis

Wenting Luo ^a,c, ,
Yuan Lyu ^a ,
Leifeng Gong ^a ,
Hong Du ^a,c ,
Miao Jiang ^a,c ,
Yunjie Ding ^a,b

a Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
b State Key Laboratory for Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
c University of Chinese Academy of Sciences, Beijing 100049, China

Received Date: 25 July 2016
Revised Date: 30 August 2016

Fund Project: This work was supported by the National Natural Science Foundation of China (21403217).

The surface of SiO₂ support was pretreated by C1-C4 normal alcohols before the impregnation of iridium and rhenium precursors. These catalysts were applied in high concentration glycerol aque-ous solution hydrogenolysis. The catalysts prepared from the pretreated supports exhibited high catalytic activity because of the formation of more active sites from a high dispersion of iridium oxide and rhenium oxide. The catalysts with the support pretreated by 1-propanol showed the highest glycerol conversion of 59.5%. The supports and catalysts were characterized by FT-IR, ni-trogen adsorption, TPR, XRD, TEM, H₂-chemisorption and NH₃-TPD.
- Glycerol hydrolysis,
- 1,3-Propanediol,
- Iridium,
- Rhenium,
- Alcohol pretreatment
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
26. [26]
27. [27]
28. [28]
29. [29]
30. [30]
31. [31]
32. [32]
33. [33]
34. [34]
35. [35]
36. [36]
37. [37]
38. [38]
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Alcohol-treated SiO2 as the support of Ir-Re/SiO2 catalysts for glycerol hydrogenolysis

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通讯作者: 陈斌, bchen63@163.com

Alcohol-treated SiO₂ as the support of Ir-Re/SiO₂ catalysts for glycerol hydrogenolysis