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Citation: Ruiben Jin, Xiaojia Jiang, Yangyuan Zhou, Jianfu Zhao. Microspheres of graphene oxide coupled to N-doped Bi2O2CO3 for visible light photocatalysis[J]. Chinese Journal of Catalysis, ;2016, 37(5): 760-768. doi: 10.1016/S1872-2067(15)61079-8 shu

Microspheres of graphene oxide coupled to N-doped Bi2O2CO3 for visible light photocatalysis

  • 1.

    College of Environmental Science and Engineering, State Key Laboratory of Pollution Control and Resources Reuse, Tongji University, Shanghai 200092, China

  • Corresponding author: Ruiben Jin, 
  • Received Date: 26 November 2015
    Available Online: 26 February 2016

    Fund Project: 国家自然科学基金(21277097) (21277097)“十二五”国家科技支撑计划重点项目(2012BAJ21B01). (2012BAJ21B01)

  • Hierarchical microspheres of a graphene oxide (GO) coupled to N-doped (BiO)2CO3 composite (N-BOC-GO) was synthesized by a simple hydrothermal approach. The N-BOC-GO composite gave enhancement in photocatalytic activity compared to the pure BOC and N-BOC samples. With 1.0 wt% GO, 62% NO removal was obtained with N-BOC-GO. The factors enhancing the photocatalytic performance were the high electron-withdrawing ability and high conductivity of GO and improved visible light-harvesting ability of N-BOC-GO with a 3D hierarchical architecture due to the surface scattering and reflecting (SSR) effect. An effective charge transfer from N-BOC to GO was demonstrated by the much weakened photoluminescene intensity of the N-BOC-GO composite. This work highlights the potential application of GO-based photocatalysts in air purification.
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