Citation: Jixing Liu, Jian Liu, Zhen Zhao, Weiyu Song, Yuechang Wei, Aijun Duan, Guiyuan Jiang. Synthesis of a chabazite-supported copper catalyst with full mesopores for selective catalytic reduction of nitrogen oxides at low temperature[J]. Chinese Journal of Catalysis, ;2016, 37(5): 750-759. doi: 10.1016/S1872-2067(15)61072-5 shu

Synthesis of a chabazite-supported copper catalyst with full mesopores for selective catalytic reduction of nitrogen oxides at low temperature

1.
State Key Laboratory of Heavy Oil and Beijing Key Lab of Oil & Gas Pollution Control, China University of Petroleum, Beijing 102249, China

Corresponding author: Jian Liu,
Received Date: 10 January 2016
Available Online: 22 February 2016
Fund Project: 国家自然科学基金(21376261,21173270) (21376261,21173270)国家高技术研究发展计划(863计划,2015AA034603) (863计划,2015AA034603)北京市自然科学基金(2142027) (2142027)中国石油大学(北京)基金(20130007110007,2462015QZDX04). (北京)基金(20130007110007,2462015QZDX04)

A series of meso-microporous copper-supporting chabazite molecular sieve (Cu-SAPO-34) catalysts with excellent performance in low-temperature ammonia selective catalytic reduction (NH₃-SCR) have been synthesized via a one-pot hydrothermal crystallization method. The physicochemical properties of the catalysts were characterized by scanning electron microscopy, transmission electron microscopy, N₂ adsorption-desorption measurements, X-ray diffraction, ²⁷Al magic angle spinning nuclear magnetic resonance, diffuse reflectance ultraviolet-visible spectroscopy, inductively coupled plasma-atomic emission spectroscopy, X-ray photoelectron spectroscopy, temperature-programmed reduction measurements, and electron paramagnetic resonance analysis. The formation of micro-mesopores in the Cu-SAPO-34 catalysts decreases diffusion resistance and greatly improves the accessibility of reactants to catalytic active sites. The main active sites for NH₃-SCR reaction are the isolated Cu²⁺ species displaced into the ellipsoidal cavity of the Cu-SAPO-34 catalysts.
- One-pot synthesis,
- Meso-microporous Cu-SAPO-34,
- Low temperature,
- Selective catalytic reduction,
- Nitrogen oxides
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