Citation: M. Y. Lee, J. S. Nam, J. H. Seo. Synthesis of Ni-CeO₂ catalyst for the partial oxidation of methane using RF thermal plasma[J]. Chinese Journal of Catalysis, ;2016, 37(5): 743-749. doi: 10.1016/S1872-2067(15)61071-3 shu

Synthesis of Ni-CeO₂ catalyst for the partial oxidation of methane using RF thermal plasma

M. Y. Lee ^a ,
J. S. Nam ^b ,
J. H. Seo ^a,b,,

1.
a Department of Applied Plasma Engineering, Chonbuk National University, Jeonbuk 54896, Korea;
2.
b Department of Quantum System Engineering, Chonbuk National University, Jeonbuk 54896, Korea

Corresponding author: J. H. Seo,
Received Date: 4 January 2016
Available Online: 23 February 2016

Ni-CeO₂ catalysts with a nickel content of 50 mol% were prepared using RF thermal plasma, and their catalytic activities for methane partial oxidation were characterized. For the synthesis of Ni-CeO₂ catalysts, a precursor containing Ni (~5-μm diameter) and CeO₂ (~200-nm diameter) powders were heated simultaneously using an RF plasma at a power level of ~52 kVA and a powder feeding rate of ~120 g/h. From the X-ray diffraction data and transmission electron microscopy images, the precursor formed into high crystalline CeO₂ supports with nanosized Ni particles (< 50-nm diameter) on their surfaces. The catalytic performance was evaluated under atmospheric pressure at > 500 ℃ and a CH₄:O₂ molar ratio of 2:1 with Ar diluent. Although the Ni content was high (~50 mol%), the experimental results reveal a methane conversion rate of > 70%, selectivities of CO and H₂ greater than 90% and slight carbon coking during an on-stream test at 550 ℃ for 24 h. However, at 750 ℃, the on-stream test revealed the formation of filament-like carbons with an increased methane conversion rate over 90%.
- RF thermal plasma,
- Methane,
- Partial oxidation,
- Nickel catalyst,
- Ceria,
- Carbon deposition
1. [1]
  [1] P. Proulx, J. Mostaghimi, M. I. Boulos, Plasma Chem. Plasma Process., 1987, 7, 29-52.
2. [2]
  [2] S. L. Girshick, C. P. Chiu, R. Muno, C. Y. Wu, L. Yang, S. K. Singh, P. H. McMurry, J. Aerosol. Sci., 1993, 24, 367-382.
3. [3]
  [3] D. Vollath, J. Nanopart. Res., 2008, 10(suppl. 1), 39-57.
4. [4]
  [4] M. Shigeta, A. B. Murphy, J. Phys. D, 2011, 44, 174025/1-174025/16.
5. [5]
  [5] J. H. Seo, B. G. Hong, Nucl. Eng.Technol., 2012, 44, 9-20.
6. [6]
  [6] P. Fauchais, A. Vardelle, IEEE Trans. Plasma Sci., 1997, 25, 1258-1280.
7. [7]
  [7] M. I. Boulos, P. Fauchais, E. Pfender, Thermal Plasmas: Fundamentals and Applications, Plenum Press, 1994.
8. [8]
  [8] P. Bushier, H. Schubert, J. Uhlenbusch, M. Weiss, J. Thermal Spray Technol., 2001, 10, 666-672.
9. [9]
  [9] H. Zea, C. K. Chen, K. Lester, A. Phillips, A. Datye, I. Fonseca, J. Phillips, Catal. Today, 2004, 89, 237-244.
10. [10]
  [10] G. P. Vissokov, Catal. Today, 2004, 89, 245-251.
11. [11]
  [11] V. Colombo, E. Ghedini, P. Sanibondi, Plasma Sources Sci. Technol., 2010, 19, 065024/1-065024/13.
12. [12]
  [12] D. Bernardi, V. Colombo, E. Ghedini, A. Mentrelli, T. Trombetti, Eur. Phys. J. D, 2004, 28, 423-433.
13. [13]
  [13] B. C. Enger, R. Lodeng, A. Holmen, Appl. Catal. A, 2008, 346, 1-27.
14. [14]
  [14] S. Tang, J. Lin, K. L. Tan, Catal. Lett., 1998, 51, 169-175.
15. [15]
  [15] E. Mamontov, T. Egami, R. Brezny, M. Koranne, S. Tyagi, J. Phys. Chem. B, 2000, 104, 11110-11116.
16. [16]
  [16] J. B. Hu, C. L. Yu, Y. D. Bi, L. F. Wei, J. C. Chen, X. R. Chen, Chin. J. Catal., 2014, 35, 8-20.
17. [17]
  [17] C. L. Yu, J. B. Hu, W. Q. Zhou, Q. Z. Fan, J. Energy Chem., 2014, 23, 235-243.
18. [18]
  [18] M. Binnewies, E. Milke, Thermochemical Data of Elements and Compounds, 2nd ed., Wiley-VCH, Weinheim, Germany, 2002, 308.
19. [19]
  [19] T. L. Zhu, M. Flytzani-Stephanopoulos, Appl. Catal. A, 2001, 208, 403-417.
20. [20]
  [20] N. Y. Mendoza-Gonzalez, M. El-Morsli, P. Proulx, J. Therm. Spray Technol., 2008, 17, 533-550.
21. [21]
  [21] S. Xu, X. L. Wang, Fuel, 2005, 84, 563-567.
22. [22]
  [22] S. Pengpanich, V. Meeyoo, T. Rirksomboon, Catal. Today, 2004, 93, 95-105.
23. [23]
  [23] J. K. Xu, W. Zhou, J. H. Wang, Z. J. Li, J. X. Ma, Chin. J. Catal., 2009, 30, 1076-1084.
1. [1]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
2. [2]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
3. [3]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
4. [4]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
5. [5]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
6. [6]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
7. [7]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
8. [8]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
9. [9]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
10. [10]
  Xuejie Wang , Guoqing Cui , Congkai Wang , Yang Yang , Guiyuan Jiang , Chunming Xu . 碳基催化剂催化有机液体氢载体脱氢研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100044-. doi: 10.1016/j.actphy.2024.100044
11. [11]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
12. [12]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Fei Liu . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-. doi: 10.3866/PKU.WHXB202408004
13. [13]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
14. [14]
  Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-. doi: 10.3866/PKU.WHXB202407020
15. [15]
  Xue Dong , Xiaofu Sun , Shuaiqiang Jia , Shitao Han , Dawei Zhou , Ting Yao , Min Wang , Minghui Fang , Haihong Wu , Buxing Han . 碳修饰的铜催化剂实现安培级电流电化学还原CO₂制C₂₊产物. Acta Physico-Chimica Sinica, 2025, 41(3): 2404012-. doi: 10.3866/PKU.WHXB202404012
16. [16]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
17. [17]
  Xiaomei Ning , Liang Zhan , Xiaosong Zhou , Jin Luo , Xunfu Zhou , Cuifen Luo . Preparation and Electro-Oxidation Performance of PtBi Supported on Carbon Cloth: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 217-224. doi: 10.3866/PKU.DXHX202401085
18. [18]
  Zhuoya WANG , Le HE , Zhiquan LIN , Yingxi WANG , Ling LI . Multifunctional nanozyme Prussian blue modified copper peroxide: Synthesis and photothermal enhanced catalytic therapy of self-provided hydrogen peroxide. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2445-2454. doi: 10.11862/CJIC.20240194
19. [19]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
20. [20]
  Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(433)
HTML views(72)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis of Ni-CeO2 catalyst for the partial oxidation of methane using RF thermal plasma

Metrics

通讯作者: 陈斌, bchen63@163.com

Synthesis of Ni-CeO₂ catalyst for the partial oxidation of methane using RF thermal plasma