Citation: Tongmei Ding, Hengshui Tian, Jichang Liu, Wenbin Wu, Jintao Yu. Highly active Cu/SiO₂ catalysts for hydrogenation of diethyl malonate to 1,3-propanediol[J]. Chinese Journal of Catalysis, ;2016, 37(4): 484-493. doi: 10.1016/S1872-2067(15)61053-1 shu

Highly active Cu/SiO₂ catalysts for hydrogenation of diethyl malonate to 1,3-propanediol

1.
School of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China

Corresponding author: Hengshui Tian,
Received Date: 3 December 2015
Available Online: 13 February 2016

Cu/SiO₂ catalysts prepared by the ammonia evaporation method were applied to hydrogenation of diethyl malonate to 1,3-propanediol. The calcination temperature played an important role in the structural evolution and catalytic performance of the Cu/SiO₂ catalysts, which were systematically characterized by N₂ adsorption-desorption, inductively coupled plasma-atomic emission spectroscopy, N₂O chemisorption, X-ray diffraction, Fourier transform infrared spectroscopy, H₂ temperature-programmed reduction, transmission electron microscopy, and X-ray photoelectron spectroscopy. When the Cu/SiO₂ catalyst was calcined at 723 K, 90.7% conversion of diethyl malonate and 32.3% selectivity of 1,3-propanediol were achieved. Compared with Cu/SiO₂ catalysts calcined at other temperatures, the enhanced catalytic performance of the Cu/SiO₂ catalyst calcined at 723 K can be attributed to better dispersion of copper species, larger cupreous surface area and greater amount of copper phyllosilicate, which results in a higher ratio of Cu⁺/Cu⁰. The synergetic effect of Cu⁰ and Cu⁺ is suggested to be responsible for the optimum activity.
- Copper,
- Silica,
- Diethyl malonate,
- Hydrogenation,
- 1,3-Propanediol,
- Calcination temperature
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沈阳化工大学材料科学与工程学院沈阳 110142

Highly active Cu/SiO2 catalysts for hydrogenation of diethyl malonate to 1,3-propanediol

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通讯作者: 陈斌, bchen63@163.com

Highly active Cu/SiO₂ catalysts for hydrogenation of diethyl malonate to 1,3-propanediol