Citation: Xinhua Gao, Jianli Zhang, Ning Chen, Qingxiang Ma, Subing Fan, Tiansheng Zhao, Noritatsu Tsubaki. Effects of zinc on Fe-based catalysts during the synthesis of light olefins from the Fischer-Tropsch process[J]. Chinese Journal of Catalysis, ;2016, 37(4): 510-516. doi: 10.1016/S1872-2067(15)61051-8 shu

Effects of zinc on Fe-based catalysts during the synthesis of light olefins from the Fischer-Tropsch process

a.
a State Key Laboratory Cultivation Base of Natural Gas Conversion, College of Chemistry & Chemical Engineering, Ningxia University, Yinchuan 750021, Ningxia, China;
b.
b Department of Applied Chemistry, School of Engineering, University of Toyama, Toyama 930-8555, Japan

Corresponding author: Jianli Zhang, Tiansheng Zhao,
Received Date: 31 December 2015
Available Online: 15 February 2016
Fund Project: 宁夏自然科学基金重点项目(NZ13010) (NZ13010) 国家自然科学基金(21366025). (21366025)

Fe-based catalysts for the production of light olefins via the Fischer-Tropsch synthesis were modified by adding a Zn promoter using both microwave-hydrothermal and impregnation methods. The physicochemical properties of the resulting catalysts were determined by scanning electron microscopy, the Brunauer-Emmett-Teller method, X-ray diffraction, H₂ temperature-programed reduction and X-ray photoelectron spectroscopy. The results demonstrate that the addition of a Zn promoter improves both the light olefin selectivity over the catalyst and the catalyst stability. The catalysts prepared via the impregnation method, which contain greater quantities of surface ZnO, exhibit severe carbon deposition following activity trials. In contrast, those materials synthesized using the microwave-hydrothermal approach show improved dispersion of Zn and Fe phases and decreased carbon deposition, and so exhibit better CO conversion and stability.
- Zn promoter,
- Fe-based catalyst,
- Light olefin,
- Fischer-Tropsch synthesis,
- Microwave-hydrothermal method
1. [1]
  [1] H. M. Torres Galvis, K. P. de Jong, ACS Catal., 2013, 3, 2130-2149.
2. [2]
  [2] H. M. Torres Galvis, A. C. J. Koeken, J. H. Bitter, T. Davidian, M. Ruitenbeek, A. I. Dugulan, K. P. de Jong, Catal. Today, 2013, 215, 95-102.
3. [3]
  [3] O. O. James, B. Chowdhury, M. A. Mesubi, S. Maity, RSC Adv., 2012, 2, 7347-7366.
4. [4]
  [4] H. M. Torres Galvis, J. H. Bitter, C. B. Khare, M. Ruitenbeek, A. I. Dugulan, K. P. de Jong, Science, 2012, 335, 835-838.
5. [5]
  [5] H. Schulz, Appl. Catal. A, 1999,186, 3-12.
6. [6]
  [6] X. Q. Chen, D. H. Deng, X. L. Pan, X. H. Bao, Chin. J. Catal., 2015, 36, 1631-1637.
7. [7]
  [7] J. L. Zhang, L. H. Ma, S. B. Fan, T. S. Zhao, Y. H. Sun, Fuel, 2013, 109, 116-123.
8. [8]
  [8] Y. Cheng, J. Lin, K. Xu, H. Wang, X. Y. Yao, Y. Pei, S. R. Yan, M. H. Qiao, B. N. Zong, ACS Catal., 2016, 6, 389-399.
9. [9]
  [9] W. S. Ning, S. B. Yang, H. X. Chen, M. Yamada, Catal. Commun., 2013, 39, 74-77.
10. [10]
  [10] O. O. James, B. Chowdhury, S. Maity, J. Chem. Sci., 2013, 125, 679-686.
11. [11]
  [11] G. C.Wang, K. Zhang, P. Liu, H. T. Hui, Y. S. Tan, J. Ind. Eng. Chem., 2013, 19, 961-965.
12. [12]
  [12] H. L. Wang, Y. Yang, J. Xu, H. Wang, M. Y. Ding, Y. W. Li, J. Mol. Catal., 2010, 326, 29-40.
13. [13]
  [13] S. L. Soled, E. Iglesia, S. Miseo, B. A. DeRites, R. A. Fiato, Top. Catal., 1995, 2, 193-205.
14. [14]
  [14] S. Z. Li, A. W. Li, S. Krishnamoorthy, E. Iglesia, Catal. Lett., 2001, 77, 197-205.
15. [15]
  [15] X. H. Gao, Y. L. Wang, S. P. Lu, J. L. Zhang, S. B. Fan, T. S. Zhao. J. Fuel Chem. Technol., 2014, 42, 219-224.
16. [16]
  [16] F. Bondioli, A. M. Ferrari, C. Leonelli, C. Siligardi, G. C. Pellacani, J. Am. Ceram. Soc., 2001, 84, 2728-2730.
17. [17]
  [17] O. W. Perez-Lopez, A. C. Farias, N. R. Marcilio, J. M. C. Bueno, Mater. Res. Bull., 2005, 40, 2089-2099.
18. [18]
  [18] X. M. Liu, G. Q. Lu, Z. F. Yan, J. Beltramini, Ind. Eng. Chem. Res., 2003, 42, 6518-6530.
1. [1]
  Xuejie Wang , Guoqing Cui , Congkai Wang , Yang Yang , Guiyuan Jiang , Chunming Xu . 碳基催化剂催化有机液体氢载体脱氢研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100044-. doi: 10.1016/j.actphy.2024.100044
2. [2]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081
3. [3]
  Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni₃N supported Al-doped SrTiO₃: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371
4. [4]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
5. [5]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
6. [6]
  Xue Dong , Xiaofu Sun , Shuaiqiang Jia , Shitao Han , Dawei Zhou , Ting Yao , Min Wang , Minghui Fang , Haihong Wu , Buxing Han . 碳修饰的铜催化剂实现安培级电流电化学还原CO₂制C₂₊产物. Acta Physico-Chimica Sinica, 2025, 41(3): 2404012-. doi: 10.3866/PKU.WHXB202404012
7. [7]
  Zelong LIANG , Shijia QIN , Pengfei GUO , Hang XU , Bin ZHAO . Synthesis and electrocatalytic CO₂ reduction performance of metal-organic framework catalysts loaded with silver particles. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 165-173. doi: 10.11862/CJIC.20240409
8. [8]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
9. [9]
  Dan Li , Hui Xin , Xiaofeng Yi . Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production. University Chemistry, 2024, 39(8): 204-211. doi: 10.3866/PKU.DXHX202312046
10. [10]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
11. [11]
  Xue Liu , Lipeng Wang , Luling Li , Kai Wang , Wenju Liu , Biao Hu , Daofan Cao , Fenghao Jiang , Junguo Li , Ke Liu . Cu基和Pt基甲醇水蒸气重整制氢催化剂研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100049-. doi: 10.1016/j.actphy.2025.100049
12. [12]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . K原子掺杂高度面间结晶的g-C₃N₄光催化剂及其高效H₂O₂光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005
13. [13]
  Zhuo Wang , Xue Bai , Kexin Zhang , Hongzhi Wang , Jiabao Dong , Yuan Gao , Bin Zhao . MOF模板法合成氮掺杂碳材料用于增强电化学钠离子储存和去除. Acta Physico-Chimica Sinica, 2025, 41(3): 2405002-. doi: 10.3866/PKU.WHXB202405002
14. [14]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
15. [15]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
16. [16]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
17. [17]
  Li'na ZHONG , Jingling CHEN , Qinghua ZHAO . Synthesis of multi-responsive carbon quantum dots from green carbon sources for detection of iron ions and L-ascorbic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 709-718. doi: 10.11862/CJIC.20240280
18. [18]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
19. [19]
  Yanan Liu , Yufei He , Dianqing Li . Preparation of Highly Dispersed LDHs-based Catalysts and Testing of Nitro Compound Reduction Performance: A Comprehensive Chemical Experiment for Research Transformation. University Chemistry, 2024, 39(8): 306-313. doi: 10.3866/PKU.DXHX202401081
20. [20]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(412)
HTML views(38)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142