Citation: C. Ramakrishna, R. Krishna, T. Gopi, G. Swetha, Bijendra Saini, S. Chandra Shekar, Anchal Srivastava. Complete oxidation of 1,4-dioxane over zeolite-13X-supported Fe catalysts in the presence of air[J]. Chinese Journal of Catalysis, ;2016, 37(2): 240-249. doi: 10.1016/S1872-2067(15)61030-0 shu

Complete oxidation of 1,4-dioxane over zeolite-13X-supported Fe catalysts in the presence of air

1.
Evaluation Facility, Chemical Defence Equipments Evaluation Facility (CDEF), Defence R&D Establishment, Jhansi Road, Gwalior-474002, India

Corresponding author: C. Ramakrishna,
Received Date: 30 September 2015
Available Online: 9 December 2015
Fund Project:

Zeolite-13X-supported Fe (Fe/zeolite-13X) catalysts with various Fe contents were prepared by the wet impregnation method. The catalysts were characterized by N₂ adsorption-desorption isotherms to estimate the Brunauer-Emmett-Teller surface areas and Barrett-Joyner-Hanlenda pore size distributions. X-ray diffraction, scanning electron microscopy, temperature-programmed reduction, and temperature-programmed desorption of NH₃ were used to investigate the textural properties of the Fe/zeolite-13X catalysts. Their catalytic activities were determined for the complete oxidation of 1,4-dioxane using air as the oxidant in a fixed‐bed flow reactor in the temperature range 100-400℃. The influences of various process parameters, such as reaction temperature, metal loading, and gas hourly space velocity (GHSV), on the dioxane removal efficiency by catalytic oxidation were investigated. The stability of the catalyst was tested at 400℃ by performing time-on-stream analysis for 50 h. The Fe/zeolite-13X catalyst with 6 wt% Fe exhibited the best catalytic activity among the Fe/zeolite-13X catalysts at 400℃ and a GHSV of 24000 h^-1, with 97% dioxane conversion and 95% selectivity for the formation of carbon oxides (CO and CO₂). Trace amounts (< 3%) of acetaldehyde, ethylene glycol monoformate, ethylene glycol diformate, 1,4-dioxane-2-ol, 1,4-dioxane-2-one, and 2-methoxy-1,3-dioxalane were also formed as degradation products. A plausible degradation mechanism is proposed based on the products identified by GC-MS analysis.
- Iron,
- Zeolite-13X,
- 1,4-Dioxane,
- Catalytic degradation,
- Complete oxidation,
- Degradation mechanism
1. [1]
  [1] National Priorities List sites identified by the EPA, 821, 1518.
2. [2]
  [2] K. R. Smith, Proceedings of the National Academy of Sciences of the United States of America, 2000, 97, 13286-13293.
3. [3]
  [3] S. Budavari, M. J. Neil, A. Smith, P. E. Heckelman, J. F. Kinneary, The Merck Index, 12th ed., Merck & Co., Inc. Whitehouse Station, NJ, 1996.
4. [4]
  [4] National Industrial Chemicals Notification and Assessment Scheme (NICNAS), 1,4-Dioxane Priority Existing Chemical No-7, Full Public Report, Common Wealth of Australia, 1998.
5. [5]
  [5] T. Sandy, C. P. Grady Jr., S. Meininger, R. Boe, Annual Industrial Wastes Technical and Regulatory Conference, Conference Proceeding 7th, Charleston, SC, USA, 2001, 88-117.
6. [6]
  [6] R. Alnaizy, A. Akgerman, Adv. Environ. Res., 2000, 4, 233-244.
7. [7]
  [7] M. J. Zenker, R. C. Borden, M. A. Barlaz, Environ. Eng. Sci., 2003, 20, 423-432.
8. [8]
  [8] U.S. Department of Health and Human Services, Seventh Annual Report on Carcinogens, 1994, PB95-109781, 186.
9. [9]
  [9] S. Mahendra, C. J. Petzold, E. E. Baidoo, J. D. Keasling, L. Alvarez-Cohen, Environ. Sci. Technol., 2007, 41, 7330-7336.
10. [10]
  [10] S. L. Kelley, E. W. Aitchison, M. Deshpande, J. L. Schnoor, P. J. J. Alvarez, Water Res., 2001, 35, 3791-3800.
11. [11]
  [11] S. Hand, B. X. Wang, K. H. Chu, Sci. Total Environ., 2015, 520, 154-159.
12. [12]
  [12] C. D. Adams, P. A. Scanlan, N. D. Secrist, Environ. Sci. Technol., 1994, 28, 1812-1818.
13. [13]
  [13] S. C. Kwon, J. Y. Kim, S. M. Yoon, W. Bae, K. S. Kang, Y. W. Rhee, J. Ind. Eng. Chem., 2012, 18, 1951-1955.
14. [14]
  [14] M. A. Beckett, I. Hua, Water Res., 2003, 37, 2372-2376.
15. [15]
  [15] V. Maurino, P. Calza, C. Minero, E. Pelizzetti, M. Vincenti, Chemosphere, 1997, 35, 2675-2688.
16. [16]
  [16] R. R. Hill, G. E. Jeffs, D. R. Roberts, J. Photochem. Photobiol. A, 1997, 108, 55-58.
17. [17]
  [17] H. M. Coleman, V. Vimonses, G. Leslie, R. Amal, J. Hazard. Mater., 2007, 146, 496-501.
18. [18]
  [18] B. K. Min, J. E. Heo, N. K. Youn, O. S. Joo, H. Lee, J. H. Kim, H. S. Kim, Catal. Commun., 2009, 10, 712-715.
19. [19]
  [19] K. C. Lee, H. J. Beak, K. H. Choo, Water Res., 2015, 86, 58-65.
20. [20]
  [20] H. C. Wang, H. S. Liang, M. B. Chang, J. Hazard. Mater., 2011, 186, 1781-1787.
21. [21]
  [21] C. B. Almquist, E. Sahle-Demessie, S. C. Shekar, J. Sowash, Environ. Sci. Technol., 2007, 41, 4754-4760.
22. [22]
  [22] H. Finaga, S. Futamura, J. Catal., 2004, 227, 304-312.
23. [23]
  [23] M. Iwasaki, M. Hara, S. Ito, J. Mater. Sci. Lett., 1998, 17, 1769-1771.
24. [24]
  [24] P. V. Kumar, D. Meisel, Curr. Opin. Colloid. Inerface Sci., 2006, 7, 13920-13925.
25. [25]
  [25] D. M. Huang, D. B. Cao, Y. W. Li, H. J. Jiao, J. Phys. Chem. B, 2006, 110, 13920-13925.
26. [26]
  [26] O. Shekhah, W. Ranke, A. Schule, G. Kolios, R. Schlogl, Angew. Chem. Int. Ed., 2003, 42, 5760-5763.
27. [27]
  [27] A. N. Pour, S. Taghipoor, M. Shekarriz, S. M. K. Shahri, Y. Zamani, J. Nanosci. Nanotechnol., 2009, 9, 4425-4429.
28. [28]
  [28] A. N. Pour, M. R. Housaindokht, S. F. Tayyari, J. Zarkesh, J. Nat. Gas. Chem., 2010, 19, 284-292.
29. [29]
  [29] S. Eriksson, U. Nylen, S. Rojas, M. Boutonnet, Appl. Catal. A, 2004, 265, 207-219.
30. [30]
  [30] L. F. Chen, K. K. Zhu, L. H. Bi, A. Suchopar, M. Reicke, G. Mathys, H. Jaensch, U. Kortz, R. M. Richards, Inorg. Chem., 2007, 46, 8457-8459.
31. [31]
  [31] D. Habibi, A. R. Faraji, M. Arshadi, J. L. G. Fierro, J. Mol. Catal. A, 2013, 372, 90-99.
32. [32]
  [32] F. Battin, G. Scacchi, F. Baronnet, Int. J. Chem. Kinet., 1991, 23, 861-879.
33. [33]
  [33] M. M. J. Treacy, J. B. Higgins, Collection of Simulated XRD Powder Patterns for Zeolites, 4th ed., 2001, 152-153.
34. [34]
  [34] S. Lowell, J. E. Shields, M. A. Thomas, M. Thommes, Characterization of Porous Solids and Powders: Surface Area, Pore Size and Density, Springer, 2004, ISBN 1402023022.
35. [35]
  [35] J. Okal, M. Zawadzki, L. Kepinski, L. Krajczyki, W. Tylus, Appl. Catal. A, 2007, 319, 202-209.
36. [36]
  [36] W. Q. Yu, B. S. Wu, J. Xu, Z. C. Tao, H. W. Xiang, Y. W. Li, Catal. Lett., 2008, 125, 116-122.
37. [37]
  [37] J. H. Ma, B. B. Fan, R. F. Li, J. H. Cao, Catal. Lett., 1994, 23, 189-194.
38. [38]
  [38] G. Munteanu, L. Ilieva, D. Andreeva, Thermochim. Acta, 1997, 291, 171-177.
39. [39]
  [39] K. C. Wu, Y. L. Tung, Y. L. Chen, Y. W. Chen, Appl. Catal. B, 2004, 53, 111-116.
40. [40]
  [40] G. W. Chen, S. L. Li, F. J. Jiao, Q. Yuan, Catal. Today, 2007, 125, 111-119.
41. [41]
  [41] S. C. Shekar, K. Soni, R. Bunkar, M. Sharma, B. Singh, A. Nigam, T. Mahato, R. Vijayaraghavan, Catal. Commun., 2009, 11, 77-81.
42. [42]
  [42] V. G. Devulapelli, E. Sahle-Demessie, Appl. Catal. A, 2008, 348, 86-93.
43. [43]
  [43] H. Barndõk, D. Hermosilla, C. Han, D. D. Dionysiou, C. Negroa, A. Blanco, Appl. Catal. B, 2016, 180, 44-52.
44. [44]
  [44] N. Merayo, D. Hermosilla, L. Cortijo, A. Blanco, J. Hazard. Mater., 2014, 268, 102-109.
45. [45]
  [45] K. C. Soni, S. C. Shekar, B. Singh, T. Gopi, J. Colloid Interface Sci., 2015, 446, 226-236.
46. [46]
  [46] M. I. Stefan, J. R. Bolton, Environ. Sci. Technol., 1998, 32, 1588-1595.
47. [47]
  [47] H. J. Wang, B. Bakheet, S. Yuan, X. Li, G. Yu, S. Murayama, Y. J. Wang, J. Hazard. Mater., 2015, 294, 90-98.
48. [48]
  [48] V. Maurino, P. Calza, C. Minero, E. Pelizzetti, M. Vincenti, Chemosphere, 1997, 35, 2675-2688.
49. [49]
  [49] H. Barndõk, L. Cortijo, D. Hermosilla, C. Negro, A. Blanco, J. Hazard. Mater., 2014, 280, 340-347.
50. [50]
  [50] H. S. Kim, B. H. Kwon, S. J. Yoa, I. K. Kim, J. Chem. Eng. Jpn., 2008, 41, 829-835.
1. [1]
  Lijuan Liu , Xionglei Wang . Preparation of Hydrogels from Waste Thermosetting Unsaturated Polyester Resin by Controllable Catalytic Degradation: A Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 313-318. doi: 10.12461/PKU.DXHX202403060
2. [2]
  Jiahui YU , Jixian DONG , Yutong ZHAO , Fuping ZHAO , Bo GE , Xipeng PU , Dafeng ZHANG . The morphology control and full-spectrum photodegradation tetracycline performance of microwave-hydrothermal synthesized BiVO₄:Yb³⁺,Er³⁺ photocatalyst. Journal of Fuel Chemistry and Technology, 2025, 53(3): 348-359. doi: 10.1016/S1872-5813(24)60514-1
3. [3]
  Jinwang Wu , Qijing Xie , Chengliang Zhang , Haifeng Shi . 自旋极化增强ZnFe_1.2Co_0.8O₄/BiVO₄ S型异质结光催化性能降解四环素. Acta Physico-Chimica Sinica, 2025, 41(5): 100050-. doi: 10.1016/j.actphy.2025.100050
4. [4]
  Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi₂O₃ pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256
5. [5]
  Pei Li , Yuenan Zheng , Zhankai Liu , An-Hui Lu . Boron-Containing MFI Zeolite: Microstructure Control and Its Performance of Propane Oxidative Dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(4): 100034-. doi: 10.3866/PKU.WHXB202406012
6. [6]
  Qingwang LIU . MoS₂/Ag/g-C₃N₄ Z-scheme heterojunction: Preparation and photocatalytic performance. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 821-832. doi: 10.11862/CJIC.20240148
7. [7]
  Qiang ZHAO , Zhinan GUO , Shuying LI , Junli WANG , Zuopeng LI , Zhifang JIA , Kewei WANG , Yong GUO . Cu₂O/Bi₂MoO₆ Z-type heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 885-894. doi: 10.11862/CJIC.20230435
8. [8]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
9. [9]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
10. [10]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-Scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-. doi: 10.3866/PKU.WHXB202403005
11. [11]
  Hongbo Zhang , Yihong Tang , Suxia Zhang , Yuanting Li . Electrochemical Monitoring of Photocatalytic Degradation of Phenol Pollutants: A Recommended Comprehensive Analytical Chemistry Experiment. University Chemistry, 2024, 39(6): 326-333. doi: 10.3866/PKU.DXHX202310013
12. [12]
  Yingqi BAI , Hua ZHAO , Huipeng LI , Xinran REN , Jun LI . Perovskite LaCoO₃/g-C₃N₄ heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 480-490. doi: 10.11862/CJIC.20240259
13. [13]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
14. [14]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
15. [15]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
16. [16]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
17. [17]
  Jianjun LI , Mingjie REN , Lili ZHANG , Lingling ZENG , Huiling WANG , Xiangwu MENG . UV-assisted degradation of tetracycline hydrochloride by MnFe₂O₄@activated carbon activated persulfate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1869-1880. doi: 10.11862/CJIC.20240187
18. [18]
  Changjun You , Chunchun Wang , Mingjie Cai , Yanping Liu , Baikang Zhu , Shijie Li . 引入内建电场强化BiOBr/C₃N₅ S型异质结中光载流子分离以实现高效催化降解微污染物. Acta Physico-Chimica Sinica, 2024, 40(11): 2407014-. doi: 10.3866/PKU.WHXB202407014
19. [19]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
20. [20]
  Xiuyun Wang , Jiashuo Cheng , Yiming Wang , Haoyu Wu , Yan Su , Yuzhuo Gao , Xiaoyu Liu , Mingyu Zhao , Chunyan Wang , Miao Cui , Wenfeng Jiang . Improvement of Sodium Ferric Ethylenediaminetetraacetate (NaFeEDTA) Iron Supplement Preparation Experiment. University Chemistry, 2024, 39(2): 340-346. doi: 10.3866/PKU.DXHX202308067

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(525)
HTML views(62)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142