Citation: Huiru Zhao, Shumei Shi, Jinxiong Wu, Yue Ding, Niu Li. Charge compensation dominates the distribution of silica in SAPO-34[J]. Chinese Journal of Catalysis, ;2016, 37(2): 227-233. doi: 10.1016/S1872-2067(15)61025-7 shu

Charge compensation dominates the distribution of silica in SAPO-34

Huiru Zhao ^a ,
Shumei Shi ^a,b ,
Jinxiong Wu ^a ,
Yue Ding ^a ,
Niu Li ^a,b,,

1.
a Institute of New Catalytic Material Science, School of Materials Science and Engineering, Nankai University, Tianjin 300071, China;
2.
b National Institute for Advanced Materials, Nankai University, Tianjin 300071, China

Corresponding author: Niu Li,
Received Date: 13 November 2015
Available Online: 23 November 2015
Fund Project: 天津市自然科学基金(12JCYBJC 12700). (12JCYBJC 12700)

The distribution of Si atoms in the SAPO-34 framework determines its acidity and catalytic effects. This was investigated using the charge balance between the inorganic framework and trapped template ions. Three types of templates, which yielded R⁺, 2R⁺ and 2R²⁺ positive charges in the cages of SAPO-34, were obtained from single crystal data and they were used to direct the synthesis of SAPO-34 with different Si contents and formation of isolated Si atoms and Si islands in the lattice. The concentration limits of SiO₂ in the gel for constituting isolated Si atoms were calculated and verified experimentally. Si islands, including 5-Si, 8-Si, 11-Si, 14-Si island were described on the basis of host-guest charge compensation. An overall view of the distribution of Si atoms in SAPO-34 was given and a criterion for the strength and density of acid sites in SAPO-34 for it to be an efficient catalyst for MTO was made available.
- SAPO-34,
- Si distribution,
- Synthesis,
- Silicon island,
- Methanol to olefins
1. [1]
  [1] U. Olsbye, S. Svelle, M. Bjøgen, P. Beato, T. V. W. Janssens, F. Joensen, S. Bordiga, K. P. Lillerud, Angew. Chem. Int. Ed., 2012, 51, 5810.
2. [2]
  [2] J. Lefevere, S. Mullens, V. Meynen, J. Van Noyen, Chem. Papers, 2014, 68, 1143.
3. [3]
  [3] M. Charghand, M. Haghighi, S. Aghamohammadi, Ultrasonics. Sonochem., 2014, 21, 1827.
4. [4]
  [4] G. Y. Liu, P. Tian, Z. M. Liu, Chin. J. Catal., 2012, 33, 174.
5. [5]
  [5] M. Guisnet, L. Costa, F. R. Ribeiro, J. Mol. Catal. A, 2009, 305, 69.
6. [6]
  [6] W. L. Dai, G. J. Wu, N. D. Li, N. J. Guan, M. Hunger, ACS Catal., 2013, 3, 588.
7. [7]
  [7] T. Álvaro-Muñoz, C. Márquez-Álvarez, E. Sastre, Catal. Today, 2012, 179, 27.
8. [8]
  [8] J. Z. Li, Y. X. Wei, J. R. Chen, P. Tian, X. Su, S. T. Xu, Y. Qi, Q. Y. Wang, Y. Zhou, Y. L. He, Z. M. Liu, J. Am. Chem. Soc., 2012, 133, 836.
9. [9]
  [9] S. Askari, R. Halladj, M. Sohrabi, Rev. Adv. Mater. Sci., 2012, 32, 83.
10. [10]
  [10] B. P. C. Hereijgers, F. Bleken, M. H. Nilsen, S. Svelle, K. P. Lillerud, M. Bjøgen, B. M. Weckhuysen, U. Olsbye, J. Catal., 2009, 264, 77.
11. [11]
  [11] T. Álvaro-Muñoz, C. Álvarez, E. Sastre, Appl. Catal. A, 2014, 472, 72.
12. [12]
  [12] D. Chen, K. Moljord, A. Holmen, Microporous Mesoporous Mater., 2012, 164, 239.
13. [13]
  [13] S. Bordiga, L. Regli, C. Lamberti, A. Zeccina, M. Bjorgen, K. P. Lillerud, J. Phys. Chem. B, 2005, 109, 7724.
14. [14]
  [14] Z. B. Li, J. Martinez-Triguero, P. Concepción, J. Yu, A. Corma, Phys. Chem. Chem. Phys., 2013, 15, 14670.
15. [15]
  [15] G. J. Yang, Y. X. Wei, S. T. Xu, J. R. Chen, J. Z. Li, Z. M. Liu, J. H. Yu, R. R. Xu, J. Phys. Chem. C, 2013, 117, 8214.
16. [16]
  [16] E. Kang, T. Kim, H. Chae, M. Kim, K. Jeong, J. Kim, C. Kim, S. Jeong, J. Nanosci. Nanotechnol., 2013, 13, 7498.
17. [17]
  [17] L. Wu, Z. Y. Liu, M. H. Qiu, C. G. Yang, L. Xia, X. Liu, Y. H. Sun, React. Kinet. Mech. Catal., 2014, 111, 319.
18. [18]
  [18] Q. M. Sun, N. Wang, D. Y. Xi, M. Yang, J. H. Yu, Chem. Commun., 2014, 50, 6502.
19. [19]
  [19] H. Hajfarajollah, S. Askari, R. Halladj, React. Kinet. Mech. Catal., 2014, 111, 723.
20. [20]
  [20] Q. Y. Qian, J. Ruiz-Martínez, M. Mokhtar, A. M. Asiri, S. A. Al-Thabaiti, S. N. Basahel, B. M. Weckhuyse, ChemCatChem, 2014, 6, 772.
21. [21]
  [21] N. Nishiyama, M. Kawaguchi, Y. Hirota, D. Van Vu, Y. Egashira, K. Ueyama, Appl. Catal. A, 2009, 362, 193.
22. [22]
  [22] Y. J. Lee, S. C. Baek, K. W. Jun, Appl. Catal. A, 2007, 329, 130.
23. [23]
  [23] Q. Y. Qian, J. Ruiz Martínez, M. Mokhtar, A. M. Asiri, S. A. Al-Thabaiti, S. N. Basahel, H. E. Van der Bij, J. Kornatowski, B. M. Weckhuysen, Chem. Eur. J., 2013, 19, 11204.
24. [24]
  [24] W. L. Dai, N. Li, L. D. Li, N. J. Guan, M. Hunger, Catal. Commun., 2011, 16, 124.
25. [25]
  [25] W. L. Dai, X. Wang, G. J. Wu, L. D. Li, N. J. Guan, M. Hunger, ChemCatChem, 2012, 4, 1428.
26. [26]
  [26] G. Y. Liu, P. Tian, Y. Zhang, J. Z. Li, L. Xu, S. H. Meng, Z. M. Liu, Microporous Mesoporous Mater., 2008, 114, 416.
27. [27]
  [27] H. O. Pastore, S. Coluccia, L. Marchese, Annu. Rev. Mater. Res., 2005, 35, 351.
28. [28]
  [28] G. V. A. Martins, G. Berlier, C. Bisio, S. Coluccia, H. O. Pastore, L. Marchese, J. Phys. Chem. C, 2008, 112, 7193.
29. [29]
  [29] E. M. Flanigen, R. L. Patton, S. T. Wilson, Stud. Surf. Sci. Catal., 1988, 37, 13.
30. [30]
  [30] R. Vomscheid, M. Briend, M. J. Peltre, P. P. Man, D. Barthomeu, J. Phys. Chem., 1994, 98, 9614.
31. [31]
  [31] M. Salmasi, S. Fatemi, A. T. Najafabadi, J. Ind. Eng. Chem., 2011, 17, 755.
32. [32]
  [32] G. Sankar, J. K. Wyles, C. R. A. Catlow, Top. Catal., 2003, 24, 1.
33. [33]
  [33] R. Alexander, N. Khanh, D. Hong, Petrovietnam, 2014, 6, 34.
34. [34]
  [34] D. Fan, P. Tian, X. Su, Y. Y. Yuan, D. H. Wang, C. Wang, M. Yang, L. Y. Wang, S. T. Xu, Z. M. Liu, J. Mater. Chem. A, 2013, 1, 14206.
35. [35]
  [35] N. Li, Y. F. Ma, W. B. Kong, N. J. Guan, S. H. Xiang, Microporous Mesoporous Mater., 2008, 115, 356.
36. [36]
  [36] S. T. Wilson, Stud. Surf. Sci. Catal., 2001, 137, 229.
37. [37]
  [37] A. Meden, N. Novak, V. Kaučič, Mater. Sci. Forum., 1994, 166-169, 613.
38. [38]
  [38] Y. Iwase, K. Motokura, T. Koyama, A. Miyaji, T. Baba, Phys. Chem. Chem. Phys., 2009, 11, 9268.
39. [39]
  [39] H. Van Heyden, S. Mintova, T. Bein, Chem. Mater., 2008, 20, 2956.
40. [40]
  [40] Y. Ding, N. Li, N. J. Guan, H. G. Wang, H. B. Song, S. H. Xiang, Microporous Mesoporous Mater., 2012, 147, 68.
41. [41]
  [41] Y. Ding, N. Li, N. J. Guan, S. H. Xiang, Acta Sci. Natura. Univer. Nankai, 2011, 44, 57.
42. [42]
  [42] H. Zhao, PhD Dissertation, Synthesizing SAPO-34 with the Si Distribution in the Framework Controlled, Nankai University, 2014.
43. [43]
  [43] D. H. Wang, P. Tian, M. Yang, S. T. Xu, D. Fan, X. Su, Y. Yang, C. Wang, Z. M. Liu, Microporous Mesoporous Mater., 2014, 194, 8.
44. [44]
  [44] H. J. Chae, I. J. Park, Y. H. Song, K. E. Jeong, C. U. Kim, C. H. Shin, S. Y. Jeong, J. Nanosci. Nanotechnol., 2010, 10, 195.
45. [45]
  [45] T. Álvaro-Muñoz, C. Márquez-Álvarez, E. Sastre, Catal. Today, 2013, 215, 208.
46. [46]
  [46] L. P. Ye, F. H. Cao, W. Y. Ying, D. Y. Fang, Q. W. Sun, J. Porous Mater., 2011, 18, 225.
47. [47]
  [47] M. Salmasi, S. Fatemi, A. Najafabadi, J. Ind. Eng. Chem., 2011, 17, 755.
48. [48]
  [48] F. M. Shalmani, R. Halladj, S. Askari, Powder Technol., 2012, 221, 395.
49. [49]
  [49] F. C. Sena, B. F. de Souza, N. C. de Almeida, J. S. Cardoso, L. D. Fernandes, Appl. Catal. A, 2011, 406, 59.
50. [50]
  [50] S. Aghamohammadi, M. Haghighi, M. Charghand, Mater. Res. Bull, 2014, 50, 462.
51. [51]
  [51] M. Strauss, G. A. V. Martins, G. Berlier, S. Coluccia, L. O. Marchese, H. O. Pastore, Microporous Mesoporous Mater., 2014, 187, 135.
52. [52]
  [52] A. H. Zhang, S. L. Sun, Z. J. A. Komon, N. Osterwalder, S. Gadewar, P. Stoimenov, D. J. Auerbach, G. D. Stucky, E. W. McFarland, Phys. Chem. Chem. Phys., 2011, 13, 2550.
53. [53]
  [53] A. Buchholz, W. Wang, M. Xu, A. Arnold, M. Hunger, Microporous Mesoporous Mater., 2002, 56, 267.
54. [54]
  [54] M. Derewinski, M. J. Peltre, M. Briend, D. Barthomeuf, P. P. Man, J. Chem. Soc., Faraday Trans., 1993, 89, 1823.
55. [55]
  [55] M. Zokaie, U. Olsbye, K. P. Lillerud, O. Swang, J. Phys. Chem. C, 2012, 116, 7255.
56. [56]
  [56] M. G. O'Brien, A. M. Beale, C. R. A. Catlow, B. M. Weckhuysen, J. Am. Chem. Soc., 2006, 128, 11744.
57. [57]
  [57] L. Xu, A. P. Du, Y. X. Wei, Y. L. Wang, Z. X. Yu, Y. L. He, X. Z. Zhang, Z. M. Liu, Microporous Mesoporous Mater., 2008, 115, 332.
58. [58]
  [58] A. Izadbakhsh, F. Farhadi, F. Khorasheh, S. Sahebdelfar, M. Asadi, Z. F. Yan, Microporous Mesoporous Mater., 2009, 126, 1.
59. [59]
  [59] A. M. Prakash, S. Unnikrirhnan, J. Chem. Soc., Faraday Trans., 1994, 90, 2291.
60. [60]
  [60] H. Kessler, J. Patarin, C. Schott-Darie, Stud. Surf. Sci. Catal., 1994, 85, 75.
61. [61]
  [61] R. Y. Pei, Z. J. Tian, Y. Wei, K. D. Li, Y. P. Xu, L. Wang, H. J. Ma, Mater. Lett., 2010, 64, 2384.
62. [62]
  [62] S. Girard, J. D. Gale, C. Mellot-Draznieks, G. Férey, J. Am. Chem. Soc., 2002, 124, 1040.
63. [63]
  [63] C. G. Wang, J. X. Wu, M. C. Hu, N. Li, N. J. Guan, S. H. Xiang, J. Porous Mater., 2012, 19, 751.
64. [64]
  [64] J. X. Wu, H. R. Zhao, N. Li, Q. Q. Luo, C. Q. He, N. J. Guan, S. H. Xiang, CrystEngComm, 2012, 14, 8671.
1. [1]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
2. [2]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
3. [3]
  Jiaming Xu , Yu Xiang , Weisheng Lin , Zhiwei Miao . Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies. University Chemistry, 2024, 39(3): 239-257. doi: 10.3866/PKU.DXHX202309093
4. [4]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
5. [5]
  Jiaqi AN , Yunle LIU , Jianxuan SHANG , Yan GUO , Ce LIU , Fanlong ZENG , Anyang LI , Wenyuan WANG . Reactivity of extremely bulky silylaminogermylene chloride and bonding analysis of a cubic tetragermylene. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1511-1518. doi: 10.11862/CJIC.20240072
6. [6]
  Linhui Liu , Wuwan Xiong , Mingli Fu , Junliang Wu , Zhenguo Li , Daiqi Ye , Peirong Chen . Efficient NO_x abatement by passive adsorption over a Pd-SAPO-34 catalyst prepared by solid-state ion exchange. Chinese Chemical Letters, 2024, 35(4): 108870-. doi: 10.1016/j.cclet.2023.108870
7. [7]
  Ling Liu , Haibin Wang , Genrong Qiang . Curriculum Ideological and Political Design for the Comprehensive Preparation Experiment of Ethyl Benzoate Synthesized from Benzyl Alcohol. University Chemistry, 2024, 39(2): 94-98. doi: 10.3866/PKU.DXHX202304080
8. [8]
  Wanmin Cheng , Juan Du , Peiwen Liu , Yiyun Jiang , Hong Jiang . Photoinitiated Grignard Reagent Synthesis and Experimental Improvement in Triphenylmethanol Preparation. University Chemistry, 2024, 39(5): 238-242. doi: 10.3866/PKU.DXHX202311066
9. [9]
  Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020
10. [10]
  Jian Jin , Jing Cheng , Xueping Yang . Integration Practice of Organic Chemistry Experiment and Safety Education: Taking the Synthesis of Triphenylmethanol as an Example. University Chemistry, 2024, 39(3): 345-350. doi: 10.3866/PKU.DXHX202309010
11. [11]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
12. [12]
  Xue Liu , Lipeng Wang , Luling Li , Kai Wang , Wenju Liu , Biao Hu , Daofan Cao , Fenghao Jiang , Junguo Li , Ke Liu . Cu基和Pt基甲醇水蒸气重整制氢催化剂研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100049-. doi: 10.1016/j.actphy.2025.100049
13. [13]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
14. [14]
  Qingying Gao , Tao Luo , Jianyuan Su , Chaofan Yu , Jiazhu Li , Bingfei Yan , Wenzuo Li , Zhen Zhang , Yi Liu . Refinement and Expansion of the Classic Cinnamic Acid Synthesis Experiment. University Chemistry, 2024, 39(5): 243-250. doi: 10.3866/PKU.DXHX202311074
15. [15]
  Wenjun Zheng . Application in Inorganic Synthesis of Ionic Liquids. University Chemistry, 2024, 39(8): 163-168. doi: 10.3866/PKU.DXHX202401020
16. [16]
  Hongyan Chen , Yajun Hou , Shui Hu , Zhuoxun Wei , Fang Zhu , Chengyong Su . Construction of Synthetic Chemistry Experiment of the Chemistry “101 Plan”. University Chemistry, 2024, 39(10): 58-63. doi: 10.12461/PKU.DXHX202409109
17. [17]
  Cunming Yu , Dongliang Tian , Jing Chen , Qinglin Yang , Kesong Liu , Lei Jiang . Chemistry “101 Program” Synthetic Chemistry Experiment Course Construction: Synthesis and Properties of Bioinspired Superhydrophobic Functional Materials. University Chemistry, 2024, 39(10): 101-106. doi: 10.12461/PKU.DXHX202408008
18. [18]
  Jiaojiao Yu , Bo Sun , Na Li , Cong Wen , Wei Li . Improvement of Classical Organic Experiment Based on the “Reverse-Step Optimization Method”: Taking Synthesis of Ethyl Acetate as an Example. University Chemistry, 2025, 40(3): 333-341. doi: 10.12461/PKU.DXHX202405177
19. [19]
  Yuan Zheng , Quan Lan , Zhenggen Zha , Lingling Li , Jun Jiang , Pingping Zhu . Teaching Reform of Organic Synthesis Experiments by Introducing Reverse Thinking and Design Concepts: Taking the Synthesis of Cinnamic Acid Based on Retrosynthetic Analysis as an Example. University Chemistry, 2024, 39(6): 207-213. doi: 10.3866/PKU.DXHX202310065
20. [20]
  Li Jiang , Changzheng Chen , Yang Su , Hao Song , Yanmao Dong , Yan Yuan , Li Li . Electrochemical Synthesis of Polyaniline and Its Anticorrosive Application: Improvement and Innovative Design of the “Chemical Synthesis of Polyaniline” Experiment. University Chemistry, 2024, 39(3): 336-344. doi: 10.3866/PKU.DXHX202309002

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(862)
HTML views(145)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142