Citation: Lingyan Wang, Linhai Zhuo, Fengyu Zhao. Carbon dioxide-expanded ethanol-assisted synthesis of carbon-based metal composites and their catalytic and electrochemical performance in lithium-ion batteries[J]. Chinese Journal of Catalysis, ;2016, 37(2): 218-226. doi: 10.1016/S1872-2067(15)61024-5 shu

Carbon dioxide-expanded ethanol-assisted synthesis of carbon-based metal composites and their catalytic and electrochemical performance in lithium-ion batteries

1.
a School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273165, Shandong, China;
2.
b College of Chemistry and Chemical Engineering, Taishan University, Tai'an 271021, Shandong, China;
3.
c State Key Laboratory of Electroanalytical Chemistry, and Laboratory of Green Chemistry and Process, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, Jilin, China

Corresponding author: Linhai Zhuo, Fengyu Zhao,
Received Date: 5 November 2015
Available Online: 2 December 2015
Fund Project: 国家自然科学基金会与日本学术振兴会国际合作项目(21311140166) (21311140166) 国家自然科学基金(21273222) (21273222) 山东省科技计划项目(2014GGX102020) (2014GGX102020) 山东省高校科技计划项目(J14LC08) (J14LC08) 曲阜师范大学科技计划项目(xkj201508). (xkj201508)

Highly dispersed metals, metal oxides and their composites on substrates have received considerable interest in catalysis and lithium-ion batteries, because of their superior properties compared with their single-component counterparts. In this review, we introduce the properties of supercritical carbon dioxide (scCO₂) expanded ethanol, such as low viscosity, near-zero surface tension and high diffusivity. We discuss the deposition procedure and formation mechanism of carbon-based composites in scCO₂-expanded ethanol. This method has been used to fabricate several carbon-based composites, such as metal and metal oxide composites deposited on zero-dimensional colloidal carbon, one-dimensional carbon nanotubes, two-dimensional graphene, and three-dimensional hierarchical porous carbon. These materials and their performance as anodic materials for lithium-ion batteries will also be reviewed.
- CO₂-expanded ethanol,
- Carbon,
- Metal oxide,
- Catalysis,
- Electrochemistry
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