Citation: Květa Jirátová, Alla Spojakina, Luděk Kaluža, Radostina Palcheva, Jana Balabánová, Georgi Tyuliev. Hydrodesulfurization activities of NiMo catalysts supported on mechanochemically prepared Al-Ce mixed oxides[J]. Chinese Journal of Catalysis, ;2016, 37(2): 258-267. doi: 10.1016/S1872-2067(15)61016-6 shu

Hydrodesulfurization activities of NiMo catalysts supported on mechanochemically prepared Al-Ce mixed oxides

1.
a Institute of Chemical Process Fundamentals of the Academy of Sciences of the Czech Republic, v.v.i., 165 02 Prague 6, Czech Republic;
2.
b Institute of Catalysis, Bulgarian Academy of Sciences, G. Bonchev str., bldg. 11, 1113 Sofia, Bulgaria

Corresponding author: Květa Jirátová,
Received Date: 9 September 2015
Available Online: 11 November 2015

Al₂O₃-CeO₂ supports containing 1-10 wt% Ce were prepared mechanochemically by milling aluminum and/or cerium nitrates with NH₄HCO₃. Heteropolymolybdate, (NH₄)₄NiMo₆O₂₄, was used as the precursor of the Ni and Mo to prepare NiMo₆/Al₂O₃-CeO₂ components in catalysts by impregnation method. The physicochemical properties of the catalysts were determined using chemical analysis, X-ray diffraction, temperature-programmed H₂ reduction, temperature-programmed NH₃ desorption, X-ray photoelectron spectroscopy (XPS), and the Brunauer-Emmett-Teller method. The catalyst acidity decreased with increasing Ce concentration in the support. XPS showed that the NiS/MoS ratio decreased two-fold for the Ce-modified alumina support. NiMo₆/Al₂O₃, which had the highest acidity, showed the highest activity in hydrodesulfurization of 1-benzothiophene (normalized per weight of catalyst). The concentration of surface MoO_xS_y species (which is equal to the concentration of Mo⁵⁺) gradually decreased to zero for catalysts with Ce concentrations ≥ 10 wt%. However, the activities of all the catalysts prepared mechanochemically from Al₂O₃ and Al₂O₃-CeO₂ supports significantly exceeded that of a reference NiMo₆/Al₂O₃ catalyst prepared by impregnation method using the same precursor and with the same composition.
- Nickel,
- Molybdenum,
- Alumina,
- Ceria,
- Anderson heteropolymolybdate,
- 1-Benzothiophene,
- Hydrodesulfurization,
- Mechanochemical method
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