Citation: Mengsi Zhao, Juanjuan Shi, Zhaoyin Hou. Selective hydrogenation of phenol to cyclohexanone in water over Pd catalysts supported on Amberlyst-45[J]. Chinese Journal of Catalysis, ;2016, 37(2): 234-239. doi: 10.1016/S1872-2067(15)60997-4 shu

Selective hydrogenation of phenol to cyclohexanone in water over Pd catalysts supported on Amberlyst-45

1.
Institute of Catalysis, Department of Chemistry, Zhejiang University, Hangzhou 310028, Zhejiang, China

Corresponding author: Zhaoyin Hou,
Received Date: 3 September 2015
Available Online: 29 September 2015
Fund Project: 国家自然科学基金(21473155, 21273198, 21073159) (21473155, 21273198, 21073159) 浙江省自然科学基金(LZ12B03001). (LZ12B03001)

A series of Pd catalysts were prepared on different supports (Fe₂O₃, SiO₂, ZnO, MgO, Al₂O₃, carbon, and Amberlyst-45) and used in the selective hydrogenation of phenol to cyclohexanone in water. The Amberlyst-45 supported Pd catalyst (Pd/A-45) was highly active and selective under mild conditions (40-100℃, 0.2-1 MPa), giving a selectivity of cyclohexanone higher than 89% even at complete conversion of phenol. Experiments with different Pd loadings (or different particle sizes) confirmed that the formation of cyclohexanone was a structure sensitive reaction, and Pd particles of 12-14 nm on Amberlyst-45 gave better selectivity and stability.
- Phenol,
- Hydrogenation,
- Cyclohexanone,
- Palladium,
- Amberlyst-45 resin,
- Supported catalyst
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沈阳化工大学材料科学与工程学院沈阳 110142